Synthesis of Functionalized Cyclic Carbonates by One-Pot Reactions of Carbon Dioxide, Epibromohydrin, and Phenols, Thiophenols, or Carboxylic Acids Catalyzed by Ionic Liquids

2017 ◽  
Vol 2017 (3) ◽  
pp. 753-759 ◽  
Author(s):  
Shi Wu ◽  
Yongya Zhang ◽  
Binshen Wang ◽  
Elnazeer H. M. Elageed ◽  
Liangzheng Ji ◽  
...  
2021 ◽  
Author(s):  
Yujiao zhou ◽  
Jocasta Avila ◽  
Nicolas Berthet ◽  
Solene Legrand ◽  
Catherine Santini ◽  
...  

Porous ionic liquids combining alkylphosphonium halides with ZIF–8 absorb large amounts of carbon dioxide that can be catalytically coupled with epoxides to form cyclic carbonates. High activity and selectivity under...


ChemCatChem ◽  
2013 ◽  
Vol 6 (1) ◽  
pp. 278-283 ◽  
Author(s):  
Binshen Wang ◽  
Elnazeer H. M. Elageed ◽  
Dawei Zhang ◽  
Sijuan Yang ◽  
Shi Wu ◽  
...  

2016 ◽  
Vol 16 (3) ◽  
pp. 6-16
Author(s):  
A. V. Sulimov ◽  
A. V. Ovcharova ◽  
A. A. Ovcharov ◽  
T. A. Ryabova ◽  
G. M. Kravchenko ◽  
...  

2013 ◽  
Vol 30 (11) ◽  
pp. 1973-1984 ◽  
Author(s):  
Dong-Woo Kim ◽  
Roshith Roshan ◽  
Jose Tharun ◽  
Amal Cherian ◽  
Dae-Won Park

2016 ◽  
Vol 18 (14) ◽  
pp. 4012-4021 ◽  
Author(s):  
Michael J. Liszka ◽  
Aram Kang ◽  
N. V. S. N. Murthy Konda ◽  
Kim Tran ◽  
John M. Gladden ◽  
...  

We describe a novel class of ionic liquids based on di-carboxylic acids that have high pretreatment efficiency and are compatible with both commercial enzyme mixtures and microbial fermentation host organisms.


2017 ◽  
Vol 41 (14) ◽  
pp. 6219-6225 ◽  
Author(s):  
Sara Sobhani ◽  
Farzaneh Zarifi ◽  
Jørgen Skibsted

The synergistic effect of ionic liquids and carboxylic acids in the reaction mechanism improved the catalytic activity of supported ILs.


2016 ◽  
Vol 8 (4) ◽  
pp. 300-309 ◽  
Author(s):  
A. V. Sulimov ◽  
A. V. Ovcharova ◽  
A. A. Ovcharov ◽  
T. A. Ryabova ◽  
G. M. Kravchenko ◽  
...  

2018 ◽  
Vol 71 (6) ◽  
pp. 407
Author(s):  
Shuang Yue ◽  
Qian Song ◽  
Shuliang Zang ◽  
Guichun Deng ◽  
Jun Li

Various amino-functional ionic liquids were developed as homogeneous catalysts for the cycloaddition of carbon dioxide to different epoxides yielding the corresponding cyclic carbonates under metal- and solvent-free conditions. The effects of reaction temperature, reaction time, CO2 pressure, and the amount of catalyst on the cycloaddition reaction were investigated. The catalysts could be easily recovered after the reaction and then reused at least eight times without noticeable loss of activity and selectivity. Reaction kinetic studies were undertaken, the reaction was apparently first order with respect to the concentration of epoxide and catalyst. Furthermore, the rate constants were determined over a temperature range of 100–130°C and the activation energy was determined to be 45.9 kJ mol−1. Finally, a possible reaction mechanism was proposed. The amino-functional ionic liquids showed the advantage of high catalytic activity and were easily recyclable for CO2 chemical fixation into valuable chemicals.


ChemInform ◽  
2014 ◽  
Vol 45 (30) ◽  
pp. no-no
Author(s):  
Binshen Wang ◽  
Elnazeer H. M. Elageed ◽  
Dawei Zhang ◽  
Sijuan Yang ◽  
Shi Wu ◽  
...  

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