scholarly journals Synthesis of Polycycles by Single or Double Domino Nucleophilic Substitution/Diels-Alder Reaction

2015 ◽  
Vol 2015 (22) ◽  
pp. 5013-5020 ◽  
Author(s):  
Pelayo Camps ◽  
David Lozano ◽  
Mercè Font-Bardia
Keyword(s):  
Nucleophilic Substitution ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Facile access to novel chromeno-2,6,9-trioxabicyclo[3.3.1]nonadienes via tandem nucleophilic substitution and [4+2] hetero Diels–Alder reaction: experimental and theoretical study

Tetrahedron ◽  
2013 ◽  
Vol 69 (9) ◽  
pp. 2142-2149 ◽  
Author(s):  
Satyanarayana Reddy Jaggavarapu ◽  
Anand Solomon Kamalakaran ◽  
Gaddamanugu Gayatri ◽  
Matsyendranath Shukla ◽  
Kavita Dorai ◽  
...  
Keyword(s):  
Nucleophilic Substitution ◽  
Theoretical Study ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Consecutive nucleophilic substitution and aza Diels–Alder reaction—an efficient strategy to functionalized 2,2′-bipyridines

2006 ◽  
Vol 47 (6) ◽  
pp. 869-872 ◽  
Author(s):  
Dmitry N. Kozhevnikov ◽  
Valery N. Kozhevnikov ◽  
Anton M. Prokhorov ◽  
Maria M. Ustinova ◽  
Vladimir L. Rusinov ◽  
...  
Keyword(s):  
Nucleophilic Substitution ◽  
Alder Reaction ◽  
Diels Alder ◽  
Efficient Strategy ◽  
Diels Alder Reaction

ChemInform Abstract: Facile Access to Novel Chromeno-2,6,9-trioxabicyclo[3.3.1]nonadienes via Tandem Nucleophilic Substitution and [4 + 2] Hetero Diels-Alder Reaction: Experimental and Theoretical Study.

ChemInform ◽  
2013 ◽  
Vol 44 (24) ◽  
pp. no-no
Author(s):  
Satyanarayana Reddy Jaggavarapu ◽  
Anand Solomon Kamalakaran ◽  
Gaddamanugu Gayatri ◽  
Matsyendranath Shukla ◽  
Kavita Dorai ◽  
...  
Keyword(s):  
Nucleophilic Substitution ◽  
Theoretical Study ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

The Diels-Alder Reaction of 2-Ethenyl-1,4-Benzodioxin: A New and Simple Synthesis of Bisaryl Ethers

Synlett ◽  
1989 ◽  
Vol 1989 (01) ◽  
pp. 30-32
Author(s):  
Thomas V. Lee ◽  
Alistair J. Leigh ◽  
Christopher B. Chapleo
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Simple Synthesis ◽  
Diels Alder Reaction

The intermolecular anthracene-transfer in a regiospecific antipodal C60 difunctionalization

2020 ◽  
Author(s):  
Radu Talmazan ◽  
Klaus R. Liedl ◽  
Bernhard Kräutler ◽  
Maren Podewitz
Keyword(s):  
Noncovalent Interactions ◽  
Interaction Model ◽  
Alder Reaction ◽  
Diels Alder ◽  
Stacking Interactions ◽  
Pi Stacking ◽  
Diels Alder Reaction ◽  
Double Decker ◽  
Anthracene Molecule ◽  
New Strategies

We analyze the mechanism of the topochemically controlled difunctionalization of C60 and anthracene, where an anthracene molecule is transferred from one C60 monoadduct to another one under exclusive formation of equal amounts of C60 and the difficult to make antipodal C60 bisadduct. Our herein disclosed dispersion corrected DFT studies show the anthracene transfer to take place in a synchronous retro Diels-Alder/Diels-Alder reaction: an anthracene molecule dissociates from one fullerene under formation of an intermediate, while already undergoing stabilizing interactions with both neighboring fullerenes, facilitating the reaction kinetically. In the intermediate, a planar anthracene molecule is sandwiched between two neighboring fullerenes and forms equally strong "double-decker" type pi-pi stacking interactions with both of these fullerenes. Analysis with the distorsion interaction model shows that the anthracene unit of the intermediate is almost planar with minimal distorsions. This analysis sheds light on the existence of noncovalent interactions engaging both faces of a planar polyunsaturated ring and two convex fullerene surfaces in an unprecedented 'inverted sandwich' structure. Hence, it sheds light on new strategies to design functional fullerene based materials.<br>

Natural Products Biosynthesis Involving a Putative Diels-Alder Reaction

2016 ◽  
Vol 20 (22) ◽  
pp. 2421-2442 ◽  
Author(s):  
Kévin Cottet ◽  
Maria Kolympadi ◽  
Dean Markovic ◽  
Marie-Christine Lallemand
Keyword(s):  
Natural Products ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction
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