Synthesis, Solid-State Analyses, and Anion-Binding Properties ofmeso-Aryldipyrrin-5,5′-diylbis(phenol) and -bis(aniline) Ligands

2014 ◽  
Vol 2014 (22) ◽  
pp. 4759-4766 ◽  
Author(s):  
Laurent Copey ◽  
Ludivine Jean-Gérard ◽  
Eric Framery ◽  
Guillaume Pilet ◽  
Bruno Andrioletti
Keyword(s):  
Solid State ◽  
Anion Binding ◽  
Binding Properties

Recognition of nitrate by the ammonium derivative of a 20-membered dioxadiaza-calix[4]arene analog—solution and solid-state study of the anion binding properties

Tetrahedron ◽  
2015 ◽  
Vol 71 (8) ◽  
pp. 1232-1240 ◽  
Author(s):  
Ramón Moreno-Corral ◽  
Herbert Höpfl ◽  
Anatoly K. Yatsimirsky ◽  
Juan Carlos Gálvez-Ruiz ◽  
Karen O. Lara
Keyword(s):  
Solid State ◽  
Anion Binding ◽  
Binding Properties ◽  
Ammonium Derivative ◽  
State Study

scholarly journals Synthesis and anion binding properties of phthalimide-containing corona[6]arenes

2019 ◽  
Vol 15 ◽  
pp. 1976-1983 ◽  
Author(s):  
Meng-Di Gu ◽  
Yao Lu ◽  
Mei-Xiang Wang
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Noncovalent Interactions ◽  
Condensation Reaction ◽  
Anion Binding ◽  
The Novel ◽  
Binding Properties ◽  
One Pot ◽  
Mild Conditions ◽  
Complex Anions

Functionalized O6-corona[3]arene[3]tetrazines were synthesized efficiently and conveniently by means of a macrocyclic condensation reaction between N-functionalized 3,6-dihydroxyphthalimides and 3,6-dichlorotetrazine under mild conditions in a one-pot reaction manner. The novel macrocycles exist as a mixture of rapidly interconvertible conformers in solution while in the solid state they adopt the conformation in which three phthalimide units are cis,trans-orientated. Acting as electron-deficient macrocyclic hosts, the synthesized O6-corona[3]arene[3]tetrazines self-regulated conformational structures to complex anions in the gas phase and in the solid state owing to the anion–π noncovalent interactions between anions and the tetrazine rings.

Anion binding with biphenyl-bis-urea derivatives: solution and solid-state studies

2020 ◽  
Vol 44 (38) ◽  
pp. 16294-16301
Author(s):  
Toni Grgurić ◽  
Mario Cetina ◽  
Manuel Petroselli ◽  
Corrado Bacchiocchi ◽  
Zoran Dzolić ◽  
...  
Keyword(s):  
Solid State ◽  
Anion Binding ◽  
Dmso Solution ◽  
Binding Properties ◽  
Urea Derivatives

Bis-urea derivatives 1–3, featuring a biphenyl spacer, were synthesized, characterized and investigated about their anion binding properties in DMSO solution and in the solid state.

scholarly journals Synthesis of Carbohydrate Based Macrolactones and Their Applications as Receptors for Ion Recognition and Catalysis

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3394
Author(s):  
Surya B. Adhikari ◽  
Anji Chen ◽  
Guijun Wang
Keyword(s):  
Nucleophilic Substitution ◽  
Supramolecular Chemistry ◽  
Copper Sulfate ◽  
Substitution Reaction ◽  
Biological Properties ◽  
Anion Binding ◽  
Nucleophilic Substitution Reaction ◽  
Binding Properties ◽  
Intramolecular Nucleophilic Substitution ◽  
Leaving Groups

Glycomacrolactones exhibit many interesting biological properties, and they are also important in molecular recognitions and for supramolecular chemistry. Therefore, it is important to be able to access glycomacrocycles with different sizes and functionality. A new series of carbohydrate-based macrocycles containing triazole and lactone moieties have been designed and synthesized. The synthesis features an intramolecular nucleophilic substitution reaction for the macrocyclization step. In this article, the effect of some common sulfonate leaving groups is evaluated for macrolactonization. Using tosylate gave good selectivity for monolactonization products with good yields. Fourteen different macrocycles have been synthesized and characterized, of which eleven macrocycles are from cyclization of the C1 to C6 positions of N-acetyl D-glucosamine derivatives and three others from C2 to C6 cyclization of functionalized D-glucosamine derivatives. These novel macrolactones have unique structures and demonstrate interesting anion binding properties, especially for chloride. The macrocycles containing two triazoles form complexes with copper sulfate, and they are effective ligands for copper sulfate mediated azide-alkyne cycloaddition reactions (CuAAC). In addition, several macrocycles show some selectivity for different alkynes.

scholarly journals Tuning Anion-Binding Properties of 22-Membered Unclosed Cryptands by Structural Modification of the Lariat Arm

ACS Omega ◽  
2020 ◽  
Vol 5 (45) ◽  
pp. 29601-29608
Author(s):  
Kajetan Dąbrowa ◽  
Patryk Niedbała ◽  
Marcin Pawlak ◽  
Marcin Lindner ◽  
Wiktor Ignacak ◽  
...  
Keyword(s):  
Structural Modification ◽  
Anion Binding ◽  
Binding Properties

Anion binding properties for pyrophosphate derived from a 2,6-diamidopyridinedipyrromethane macrocycle

2021 ◽  
Author(s):  
Rui Yi ◽  
Xing-Li Liu ◽  
Zheng-He Tang ◽  
Chao Huang ◽  
Bi-Xue Zhu ◽  
...  
Keyword(s):  
Anion Binding ◽  
Binding Properties

Folding and Anion-Binding Properties of Fluorescent Oligoindole Foldamers

2008 ◽  
Vol 14 (36) ◽  
pp. 11406-11414 ◽  
Author(s):  
Uk-Il Kim ◽  
Jae-min Suk ◽  
Veluru Ramesh Naidu ◽  
Kyu-Sung Jeong
Keyword(s):  
Anion Binding ◽  
Binding Properties
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