Transition-Metal-Free Cross-Coupling Reactions by Single Electron Transfer (SET)

2013 ◽  
Vol 2014 (2) ◽  
pp. 311-314 ◽  
Author(s):  
Suresh Kumar Sythana ◽  
Santhosh Unni ◽  
Yogesh M. Kshirsagar ◽  
Pundlik R. Bhagat
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Cross Coupling ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Coupling Reactions ◽  
Metal Free ◽  
Cross Coupling Reactions

ChemInform Abstract: Transition-Metal-Free Cross-Coupling Reactions by Single Electron Transfer (SET).

ChemInform ◽  
2014 ◽  
Vol 45 (42) ◽  
pp. no-no
Author(s):  
Suresh Kumar Sythana ◽  
Santhosh Unni ◽  
Yogesh M. Kshirsagar ◽  
Pundlik R. Bhagat
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Cross Coupling ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Coupling Reactions ◽  
Metal Free ◽  
Cross Coupling Reactions

Synthesis of Alkyl-Substituted Pyrazine N -Oxides by Transition-Metal-Free Oxidative Cross-Coupling Reactions

2018 ◽  
Vol 7 (6) ◽  
pp. 1118-1123 ◽  
Author(s):  
Miao Lai ◽  
Yuan Li ◽  
Zhiyong Wu ◽  
Mingqin Zhao ◽  
Xiaoming Ji ◽  
...  
Keyword(s):  
Transition Metal ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Metal Free ◽  
Cross Coupling Reactions

Transition-metal-free, ambient-pressure carbonylative cross-coupling reactions of aryl halides with potassium aryltrifluoroborates

2015 ◽  
Vol 51 (44) ◽  
pp. 9133-9136 ◽  
Author(s):  
Fengli Jin ◽  
Wei Han
Keyword(s):  
Transition Metal ◽  
Ambient Pressure ◽  
Cross Coupling ◽  
Suzuki Coupling ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Metal Free ◽  
General Methodology ◽  
Cross Coupling Reactions

A transition-metal-free, ambient-pressure, and general methodology for carbonylative Suzuki coupling has been developed.

scholarly journals Recent Strides in the Transition Metal-Free Cross-Coupling of Haloacetylenes with Electron-Rich Heterocycles in Solid Media

Molecules ◽  
2020 ◽  
Vol 25 (11) ◽  
pp. 2490 ◽  
Author(s):  
Lyubov’ N. Sobenina ◽  
Boris A. Trofimov
Keyword(s):  
Transition Metal ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
The Novel ◽  
Strong Electron ◽  
Metal Free ◽  
Cross Coupling Reactions ◽  
Solid Media ◽  
Solvent Free Conditions ◽  
Structural Peculiarities

The publications covering new, transition metal-free cross-coupling reactions of pyrroles with electrophilic haloacetylenes in solid medium of metal oxides and salts to regioselectively afford 2-ethynylpyrroles are discussed. The reactions proceed at room temperature without catalyst and base under solvent-free conditions. These ethynylation reactions seem to be particularly important, since the common Sonogashira coupling does not allow ethynylpyrroles with strong electron-withdrawing substituents at the acetylenic fragments to be synthesized. The results on the behavior of furans, thiophenes, and pyrazoles under the conditions of these reactions are also provided. The reactivity and structural peculiarities of nucleophilic addition to the activated acetylene moiety of the novel C-ethynylpyrroles are considered.

scholarly journals Photocatalyzed Transition-Metal-Free Oxidative Cross-Coupling Reactions of Tetraorganoborates

2020 ◽  
Author(s):  
Arif Music ◽  
Andreas N. Baumann ◽  
Florian Boser ◽  
Nicolas Müller ◽  
Florian Matz ◽  
...  
Keyword(s):  
Transition Metal ◽  
Blue Light ◽  
Cross Coupling ◽  
Light Irradiation ◽  
Computational Studies ◽  
Coupling Reactions ◽  
Conceptual Approach ◽  
Metal Free ◽  
Cross Coupling Reactions

Readily accessible tetraorganoborate salts undergo selective coupling reactions under blue light irradiation in the presence of catalytic amounts of transition-metal-free acridinium and rhodamine photocatalysts to furnish unsymmetrical biaryls, heterobiaryls and arylated olefins. This represents an interesting conceptual approach to forge C-C bonds between aryl, heteroaryl and alkenyl groups under smooth photochemical conditions. Computational studies were conducted to investigate the mechanism of the transformation.

Transition-Metal-Free C(sp3)–H Coupling of Cycloalkanes Enabled by Single-Electron Transfer and Hydrogen Atom Transfer

2021 ◽  
Vol 23 (5) ◽  
pp. 1714-1719
Author(s):  
Linlin Zhang ◽  
Zhengfen Liu ◽  
Xun Tian ◽  
Yujin Zi ◽  
Shengzu Duan ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Hydrogen Atom ◽  
Transition Metal ◽  
Hydrogen Atom Transfer ◽  
Single Electron ◽  
Atom Transfer ◽  
Single Electron Transfer ◽  
Metal Free

Photoinduced transition-metal and external photosensitizer free cross-coupling of aryl triflates with trialkyl phosphites

2021 ◽  
Author(s):  
Qian Dou ◽  
Li Geng ◽  
Bin Cheng ◽  
Chao-Jun Li ◽  
Huiying Zeng
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Bond Cleavage ◽  
Cross Coupling ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Rearrangement Process ◽  
Trialkyl Phosphites

Photoinduced phosphonation of aryl triflates with trialkyl phosphites via a tandem single-electron-transfer, C–O bond cleavage and Arbuzov rearrangement process in the absence of transition-metal and external photosensitizer is reported herein....

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