A Metal-Macrocycle Complex as a Fluorescent Sensor for Biological Phosphate Ions in Aqueous Solution

2010 ◽  
Vol 2010 (10) ◽  
pp. 1921-1927 ◽  
Author(s):  
Xiao-huan Huang ◽  
Yan Lu ◽  
Yong-bing He ◽  
Zhi-hong Chen
Chemosensors ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 65
Author(s):  
Minji Lee ◽  
Donghwan Choe ◽  
Soyoung Park ◽  
Hyeongjin Kim ◽  
Soomin Jeong ◽  
...  

A novel thiosemicarbazide-based fluorescent sensor (AFC) was developed. It was successfully applied to detect hypochlorite (ClO−) with fluorescence quenching in bis-tris buffer. The limit of detection of AFC for ClO− was analyzed to be 58.7 μM. Importantly, AFC could be employed as an efficient and practical fluorescent sensor for ClO− in water sample and zebrafish. Moreover, AFC showed a marked selectivity to ClO− over varied competitive analytes with reactive oxygen species. The detection process of AFC to ClO− was illustrated by UV–visible and fluorescent spectroscopy and electrospray ionization–mass spectrometry (ESI–MS).


2014 ◽  
Vol 12 (0) ◽  
pp. 404-409 ◽  
Author(s):  
Fumihiko Ogata ◽  
Daisuke Imai ◽  
Megumu Toda ◽  
Masashi Otani ◽  
Naohito Kawasaki

2019 ◽  
Vol 11 (4) ◽  
pp. 490-506 ◽  
Author(s):  
K. Radhakrishnan ◽  
P. Panneerselvam ◽  
M. Marieeswaran

In this work, a green synthetic route was used to create a number of surface passivated fluorescent carbon quantum dots, which are explored as promising sensing probes, via facile one-pot hydrothermal methods.


2019 ◽  
Vol 279 ◽  
pp. 476-482 ◽  
Author(s):  
Bholanath Dolai ◽  
Sk Nayim ◽  
Maidul Hossain ◽  
Pallab Pahari ◽  
Ananta Kumar Atta

2010 ◽  
Vol 5 (12) ◽  
pp. 1934578X1000501 ◽  
Author(s):  
Paul Slusarewicz ◽  
Keng Zhu ◽  
Tom Hedman

Degradation of genipin (GP), a low toxicity natural protein crosslinking agent, in aqueous solution was monitored by HPLC at various pH levels. Degradation of GP was consistent with a mechanism consisting of a first order reaction with a reversible first step. Formation of the intermediate was slowest at more neutral pHs while formation of the irreversible product was correlated to increasing alkalinity. Degradation at all pHs was enhanced by the presence of phosphate ions. Degradation of GP most likely proceeds via the reversible opening of the dihydropyran ring by water followed by irreversible polymerization of the intermediate. Degraded solutions containing no detectable GP or intermediate, however, are still capable of crosslinking proteins.


2012 ◽  
Vol 60 (2) ◽  
pp. 181-184 ◽  
Author(s):  
Mohammad Arifur Rahman ◽  
Tamanna Azam ◽  
A. M. Shafiqul Alam

Anthracite was used as an adsorbent to remove excess phosphate from wastewater. Anthracite used in the present study is environmentally friendly and of cost effective. The adsorption study was carried out using different particle size of adsorbents, different concentration of phosphate solution ranging from 25.0 mg/L to 100.0 mg/L, different pH values ranging from 0.5 to 11.5 along with different adsorbent amount from 1.0 g to 5.0 g. Flow rate was also varied in the range of 0.6 mL/min to 1.8 mL/min. Adsorption column methods show the optimum removal of phosphate under the following conditions: initial phosphate concentration 25 mg/L, initial volume 25.0 mL, flow rate 1.0 mL/min adsorbent amount 2.0 g, particle size, < 90?m. This removal method may provide a solution to the removal phosphate from wastewater in Bangladesh as well as other countries of the world.DOI: http://dx.doi.org/10.3329/dujs.v60i2.11490 Dhaka Univ. J. Sci. 60(2): 181-184, 2012 (July)


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