Syntheses of Sterically Hindered Pyridinium Phenoxides as Model Compounds in Nonlinear Optics

2006 ◽  
Vol 2006 (12) ◽  
pp. 2727-2738 ◽  
Author(s):  
Vincent Diemer ◽  
Hélène Chaumeil ◽  
Albert Defoin ◽  
Alain Fort ◽  
Alex Boeglin ◽  
...  
Keyword(s):  
Nonlinear Optics ◽  
Model Compounds ◽  
Sterically Hindered

Syntheses of Sterically Hindered Zwitterionic Pyridinium Phenolates as Model Compounds in Nonlinear Optics

2008 ◽  
Vol 2008 (10) ◽  
pp. 1767-1776 ◽  
Author(s):  
Vincent Diemer ◽  
Hélène Chaumeil ◽  
Albert Defoin ◽  
Alain Fort ◽  
Alex Boeglin ◽  
...  
Keyword(s):  
Nonlinear Optics ◽  
Model Compounds ◽  
Sterically Hindered

Excimer formation in sterically hindered poly(9-vinylcarbazole) and its dimer model compounds

1990 ◽  
Vol 23 (10) ◽  
pp. 2666-2673 ◽  
Author(s):  
Shinzaburo Ito ◽  
Kazukiyo Takami ◽  
Yoshinobu Tsujii ◽  
Masahide Yamamoto
Keyword(s):  
Model Compounds ◽  
Dimer Model ◽  
Excimer Formation ◽  
Sterically Hindered

Slow-light Enhanced Nonlinear Optics in Silicon Photonic Crystal Waveguides

PIERS Online ◽  
2010 ◽  
Vol 6 (3) ◽  
pp. 273-278 ◽  
Author(s):  
David J. Moss ◽  
B. Corcoran ◽  
C. Monat ◽  
Christian Grillet ◽  
T. P. White ◽  
...  
Keyword(s):  
Photonic Crystal ◽  
Nonlinear Optics ◽  
Slow Light ◽  
Photonic Crystal Waveguides ◽  
Silicon Photonic

Structure Revision of Protoaculeine B, a Posttranslationally Modified N-Terminal Residue in the Peptide Toxin Aculeine B

2020 ◽  
Author(s):  
Raku Irie ◽  
Kei Miyako ◽  
Satoko Matsunaga ◽  
Ryuichi Sakai ◽  
Masato Oikawa
Keyword(s):  
Mass Spectra ◽  
Chemical Reactivity ◽  
Model Compounds ◽  
Structural Revision ◽  
Structure Revision ◽  
Peptide Toxin ◽  
One Step ◽  
Marine Peptide ◽  
Synthetic Models ◽  
Long Chain

<div>Here, we newly propose the structure of protoaculeine B, an N-terminal moiety of the marine peptide toxin aculeine B, as possessing the cis-disubstituted tetrahydro-beta-carboline framework. We prepared two truncated model compounds that lack long-chain polyamine by one-step Pictet-Spengler reaction of tryptophan, and compared the NMR and mass spectra and chemical reactivity with those of natural protoaculeine B. The synthetic models reproduced the profiles of the natural product well, which was conclusive for the structural revision.</div>

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