Crucial Role of the Conjugate Base for Silyl Lewis Acid Induced Mukaiyama Aldol Reactions

2006 ◽  
Vol 2006 (8) ◽  
pp. 1837-1844 ◽  
Author(s):  
Yukihiro Hiraiwa ◽  
Kazuaki Ishihara ◽  
Hisashi Yamamoto
Keyword(s):  
Lewis Acid ◽  
Crucial Role ◽  
Aldol Reactions ◽  
Mukaiyama Aldol ◽  
Conjugate Base

ChemInform Abstract: Crucial Role of the Ligand of Silyl Lewis Acid in the Mukaiyama Aldol Reaction.

ChemInform ◽  
2010 ◽  
Vol 33 (47) ◽  
pp. no-no
Author(s):  
Kazuaki Ishihara ◽  
Yukihiro Hiraiwa ◽  
Hisashi Yamamoto
Keyword(s):  
Lewis Acid ◽  
Crucial Role ◽  
Aldol Reaction ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol

Stereoselective Synthesis of Functionalized Triol Units by SnCl4 Promoted Allylation of α-Benzyloxyaldehydes: Crucial Role of the Stoichiometry of the Lewis Acid.

ChemInform ◽  
2004 ◽  
Vol 35 (49) ◽  
Author(s):  
Christophe Dubost ◽  
Bernard Leroy ◽  
Istvan E. Marko ◽  
Bernard Tinant ◽  
Jean-Paul Declercq ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Crucial Role ◽  
Stereoselective Synthesis

Novel chiral gallium Lewis acid catalysts with semi-crown ligands for aqueous asymmetric Mukaiyama aldol reactions

2002 ◽  
pp. 2994-2995 ◽  
Author(s):  
Hui-Jing Li ◽  
Hong-Yu Tian ◽  
Yong-Jun Chen ◽  
Dong Wang ◽  
Chao-Jun Li
Keyword(s):  
Lewis Acid ◽  
Aldol Reactions ◽  
Acid Catalysts ◽  
Lewis Acid Catalysts ◽  
Mukaiyama Aldol

Stereoselective synthesis of functionalised triol units by SnCl4 promoted allylation of α-benzyloxyaldehydes: crucial role of the stoichiometry of the Lewis acid

Tetrahedron ◽  
2004 ◽  
Vol 60 (35) ◽  
pp. 7693-7704 ◽  
Author(s):  
Christophe Dubost ◽  
Bernard Leroy ◽  
Istvan E. Markó ◽  
Bernard Tinant ◽  
Jean-Paul Declercq ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Crucial Role ◽  
Stereoselective Synthesis

The effect of auxiliary ligand on the mechanism and reactivity: DFT study on H2 activation by Lewis acid–transition metal complex (tris(phosphino)borane)Fe(L)

2017 ◽  
Vol 7 (20) ◽  
pp. 4866-4878 ◽  
Author(s):  
Jianyu Zhang ◽  
Jiasheng Lin ◽  
Yinwu Li ◽  
Youxiang Shao ◽  
Xiao Huang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Lewis Acid ◽  
Crucial Role ◽  
Transition Metal Complex ◽  
Dft Study ◽  
Dft Studies ◽  
Auxiliary Ligand ◽  
Hydrogen Activation

The crucial role of the auxiliary ligand in hydrogen activation is revealed by DFT studies for the LA–TM ferraboratrane complex.

ChemInform Abstract: Lewis Acid Assisted Vinylogous Mannich and Mukaiyama Aldol Reactions: A Route to Densely Hydroxylated Indolizidine Alkaloid Analogues.

ChemInform ◽  
2010 ◽  
Vol 30 (36) ◽  
pp. no-no
Author(s):  
Gloria Rassu ◽  
Paola Carta ◽  
Luigi Pinna ◽  
Lucia Battistini ◽  
Franca Zanardi ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Aldol Reactions ◽  
Mukaiyama Aldol

Lewis Acid Assisted Vinylogous Mannich and Mukaiyama Aldol Reactions: A Route to Densely Hydroxylated Indolizidine Alkaloid Analogues

1999 ◽  
Vol 1999 (6) ◽  
pp. 1395-1400 ◽  
Author(s):  
Gloria Rassu ◽  
Paola Carta ◽  
Luigi Pinna ◽  
Lucia Battistini ◽  
Franca Zanardi ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Aldol Reactions ◽  
Mukaiyama Aldol
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