The Stabilization Effect of π-Backdonation Ligands on the Catalytic Reactivities of Amido-Ene(amido) Iron Catalysts in the Asymmetric Transfer Hydrogenation of Ketones

2020 ◽  
Author(s):  
Qingquan Xue ◽  
Rongliang Wu ◽  
Di Wang ◽  
Meifang Zhu ◽  
Weiwei Zuo
Keyword(s):  
Transfer Hydrogenation ◽  
Iron Catalysts ◽  
Asymmetric Transfer Hydrogenation ◽  
Stabilization Effect

Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

Science ◽  
2013 ◽  
Vol 342 (6162) ◽  
pp. 1080-1083 ◽  
Author(s):  
W. Zuo ◽  
A. J. Lough ◽  
Y. F. Li ◽  
R. H. Morris
Keyword(s):  
Transfer Hydrogenation ◽  
Iron Catalysts ◽  
Asymmetric Transfer Hydrogenation

scholarly journals Rational development of iron catalysts for asymmetric transfer hydrogenation

2014 ◽  
Vol 43 (21) ◽  
pp. 7650 ◽  
Author(s):  
Peter E. Sues ◽  
Karl Z. Demmans ◽  
Robert H. Morris
Keyword(s):  
Transfer Hydrogenation ◽  
Iron Catalysts ◽  
Asymmetric Transfer Hydrogenation ◽  
Rational Development

ChemInform Abstract: Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines.

ChemInform ◽  
2014 ◽  
Vol 45 (19) ◽  
pp. no-no
Author(s):  
Weiwei Zuo ◽  
Alan J. Lough ◽  
Young Feng Li ◽  
Robert H. Morris
Keyword(s):  
Transfer Hydrogenation ◽  
Iron Catalysts ◽  
Asymmetric Transfer Hydrogenation

scholarly journals Design of Iridium N-Heterocyclic Carbene Amino Acid Catalysts for Asymmetric Transfer Hydrogenation of Aryl Ketones

Catalysts ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 671
Author(s):  
Chad M. Bernier ◽  
Joseph S. Merola
Keyword(s):  
Amino Acids ◽  
Amino Acid ◽  
Enantiomeric Excess ◽  
Transfer Hydrogenation ◽  
Acid Catalysts ◽  
Asymmetric Transfer Hydrogenation ◽  
Reaction Conditions ◽  
Chiral Complexes ◽  
Acetophenone Derivatives ◽  
Aryl Ketones

A series of chiral complexes of the form Ir(NHC)2(aa)(H)(X) (NHC = N-heterocyclic carbene, aa = chelated amino acid, X = halide) was synthesized by oxidative addition of -amino acids to iridium(I) bis-NHC compounds and screened for asymmetric transfer hydrogenation of ketones. Following optimization of the reaction conditions, NHC, and amino acid ligands, high enantioselectivity was achieved when employing the Ir(IMe)2(l-Pro)(H)(I) catalyst (IMe = 1,3-dimethylimidazol-2-ylidene), which asymmetrically reduces a range of acetophenone derivatives in up to 95% enantiomeric excess.

Enantioselectivity in the Noyori–Ikariya Asymmetric Transfer Hydrogenation of Ketones

2021 ◽  
Author(s):  
Pavel A. Dub ◽  
Nikolay V. Tkachenko ◽  
Vijyesh K. Vyas ◽  
Martin Wills ◽  
Justin S. Smith ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation

Dendritic catalysts for asymmetric transfer hydrogenation based (1S,2R)-norephedrine derived ligands

2003 ◽  
Vol 14 (16) ◽  
pp. 2481-2485 ◽  
Author(s):  
Pei Nian Liu ◽  
Ying Chun Chen ◽  
Xue Qiang Li ◽  
Yong Qiang Tu ◽  
Jin Gen Deng
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation
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