scholarly journals Cyclopalladated Compounds with Polyhalogenated Benzylphosphanes for the Mizoroki-Heck Reaction

2020 ◽  
Vol 2020 (25) ◽  
pp. 2470-2484
Author(s):  
Cristina López-Mosquera ◽  
Arnald Grabulosa ◽  
Mercè Rocamora ◽  
Mercè Font-Bardia ◽  
Guillermo Muller
Keyword(s):  
Heck Reaction ◽  
Cyclopalladated Compounds

Development of Recent Total Syntheses Based on the Heck Reaction

2013 ◽  
Vol 17 (19) ◽  
pp. 2192-2224 ◽  
Author(s):  
Majid Heravi ◽  
Elaheh Hashemi ◽  
Nazanin Ghobadi
Keyword(s):  
Heck Reaction ◽  
Total Syntheses

Recent Developments in Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles

Synthesis ◽  
2020 ◽  
Author(s):  
Lili Shi ◽  
Junkai Fu ◽  
Shuangqiu Gao ◽  
Le Chang ◽  
Binglin Wang
Keyword(s):  
Heck Reaction ◽  
Alkyl Radicals ◽  
Type Reaction ◽  
The Past ◽  
Alkyl Electrophiles ◽  
Recent Developments ◽  
Palladium Catalyzed ◽  
Initial Work ◽  
Activated Olefins ◽  
Pseudo Halides

AbstractThe Mizoroki–Heck reaction is considered as one of the most ingenious and widely used methods for constructing C–C bonds. This reaction mainly focuses on activated olefins (styrenes, acrylates, or vinyl ethers) and aryl/vinyl (pseudo) halides. In comparison, the studies on unactivated alkenes and alkyl electrophiles are far less due to the low reactivity, poor selectivity, as well as competitive β-H elimination. In the past years, a growing interest has thus been devoted and significant breakthroughs have been achieved in the employment of unactivated alkenes and alkyl electrophiles as the reaction components, and this type of coupling is called as Heck-type or Heck-like reaction, which distinguishes from the traditional Heck reaction. Herein, we give a brief summary on Heck-type reaction between unactivated alkenes and alkyl electrophlies, covering its initial work, recent advancements, and mechanistic discussions.1 Introduction2 Intramolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles2.1 Cobalt-Catalyzed Intramolecular Heck-Type Reaction2.2 Palladium-Catalyzed Intramolecular Heck-Type Reaction2.3 Nickel-Catalyzed Intramolecular Heck-Type Reaction2.4 Photocatalysis and Multimetallic Protocol for Intramolecular Heck-Type Reaction3 Intermolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles3.1 Electrophilic Trifluoromethylating Reagent as Reaction Partners3.2 Alkyl Electrophiles as Reaction Partners4 Oxidative Heck-Type Reaction of Unactivated Alkenes and Alkyl Radicals5 Conclusions and Outlook

Bimetallic nano alloy architecture on a special polymer: Ni or Cu merged with Pd for the promotion of the Mizoroki–Heck reaction and the Suzuki–Miyaura coupling

2021 ◽  
Vol 133 (1) ◽  
Author(s):  
VIJAY P PATIL ◽  
ABHIJIT A KASHID ◽  
BHANUPRATAP S SOLANKI ◽  
ULHAS K KHARUL ◽  
SURESH IYER
Keyword(s):  
Heck Reaction

Triethanolamine‐Mediated Magnetically Separable Fe 3 O 4 −Pd Nanoparticles Catalyzed Heck Reaction under Ligand‐Free Conditions

2021 ◽  
Vol 6 (31) ◽  
pp. 7944-7949
Author(s):  
Chandan Kumar Pal ◽  
Ashis Kumar Jena ◽  
Dibya Das ◽  
Swagatika Sahu ◽  
Rajesh Kumar Singh
Keyword(s):  
Heck Reaction ◽  
Pd Nanoparticles ◽  
Ligand Free ◽  
Magnetically Separable

Cross-Coupling of Organic Halides with Alkenes: The Heck Reaction

ChemInform ◽  
2005 ◽  
Vol 36 (8) ◽  
Author(s):  
Stefan Braese ◽  
Armin de Meijere
Keyword(s):  
Heck Reaction ◽  
Cross Coupling ◽  
Organic Halides
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