scholarly journals Lewis Acidic Behavior of MoOF4 towards the Alkali Metal Fluorides in Anhydrous Hydrogen Fluoride Solutions

2019 ◽  
Vol 2019 (32) ◽  
pp. 3672-3682 ◽  
Author(s):  
Riane E. Stene ◽  
Benjamin Scheibe ◽  
Antti J. Karttunen ◽  
Winfried Petry ◽  
Florian Kraus
Keyword(s):  
Alkali Metal ◽  
Hydrogen Fluoride ◽  
Metal Fluorides ◽  
Anhydrous Hydrogen Fluoride

Disproportionation of chlorine in hydrogen fluoride and related media

1989 ◽  
Vol 67 (11) ◽  
pp. 1828-1831 ◽  
Author(s):  
Mario Gambardella ◽  
Santad Kongpricha ◽  
James J. Pitts ◽  
Albert W. Jache
Keyword(s):  
Alkali Metal ◽  
Hydrogen Chloride ◽  
Hydrogen Fluoride ◽  
Silver Chloride ◽  
Solvent System ◽  
Antimony Pentafluoride ◽  
Alkali Metal Chlorides ◽  
Metal Chlorides ◽  
Metal Fluorides ◽  
Silver Fluoride

Chlorine can be made to disproportionate to chlorine monofluoride and chloride, taking advantage of Le Chatelier's principle in several different ways. It will disproportionate to form insoluble silver chloride and chlorine monofluoride when silver fluoride is present. It will disproportionate in a melt of alkali metal fluorides to form alkali metal chlorides and chlorine monofluoride. The alkali metal chlorides will react with hydrogen fluoride to regenerate the metal fluorides and hydrogen chloride. Chlorine will also disproportionate in hydrogen fluoride containing antimony pentafluoride to yield antimony pentafluoride adducts of chlorine monofluoride and of hydrogen chloride. These adducts are readily decomposed to yield the disproportionation products and the original antimony pentafluoride. Keywords: hydrogen fluoride, disproportionation, chlorine, waterlike, solvent system.

Isotropic and anisotropic Raman scattering from molten alkali-metal fluorides

2000 ◽  
Vol 2 (9) ◽  
pp. 2021-2025 ◽  
Author(s):  
V. Dracopoulos ◽  
G. N. Papatheodorou
Keyword(s):  
Alkali Metal ◽  
Raman Scattering ◽  
Metal Fluorides
Sign in / Sign up

Export Citation Format

Share Document