A New Family of 2D Coordination Polymers Based on 3d-4f 15-Metallacrown-5 Units: Synthesis, Structure, and Single-Molecule Magnet Behavior

2019 ◽  
Vol 2019 (23) ◽  
pp. 2839-2843 ◽  
Author(s):  
Hong-Gang Zhang ◽  
Hua Yang ◽  
Lei Sun ◽  
Da-Cheng Li ◽  
Jian-Min Dou
Keyword(s):  
Coordination Polymers ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
New Family

Recent advances in lanthanide coordination polymers and clusters with magnetocaloric effect or single-molecule magnet behavior

2021 ◽  
Author(s):  
Jun-Jie Hu ◽  
Yan Peng ◽  
Sui-Jun Liu ◽  
He-Rui Wen
Keyword(s):  
Quantum Computing ◽  
Low Temperature ◽  
Magnetocaloric Effect ◽  
Coordination Polymers ◽  
Single Molecule ◽  
Information Storage ◽  
Lanthanide Ions ◽  
Single Molecule Magnets ◽  
Single Molecule Magnet ◽  
Lanthanide Coordination Polymers

The molecular magnetorefrigerant materials for low-temperature magnetic refrigeration and single-molecule magnets for high-density information storage and quantum computing have received extensive attention from chemists and magnetic experts. Lanthanide ions with...

A new family of dinuclear lanthanide complexes exhibiting luminescence, magnetic entropy changes and single molecule magnet behaviors

CrystEngComm ◽  
2021 ◽  
Author(s):  
Lu Dong ◽  
Ying-Bing Lu ◽  
Shui-Dong Zhu ◽  
Jun-Wei Wu ◽  
Xin-Ting Zhang ◽  
...  
Keyword(s):  
Magnetocaloric Effect ◽  
Single Molecule ◽  
Lanthanide Complexes ◽  
Magnetic Entropy ◽  
Single Molecule Magnet ◽  
Entropy Changes ◽  
New Family

Four isomorphic and dinuclear lanthanide complexes were synthesized. Complexes EuIII and TbIII exhibit strong emissions, while GdIII shows the magnetocaloric effect and DyIII displays a single-molecule magnet.

A new family of hetero-tri-metallic complexes [M(CuTb)]n (n = 1, 2, ∞; M = Co, Cr, Fe): synthesis, structure and tailored single-molecule magnet behavior

2015 ◽  
Vol 44 (11) ◽  
pp. 5170-5178 ◽  
Author(s):  
N. Bridonneau ◽  
G. Gontard ◽  
V. Marvaud
Keyword(s):  
Magnetic Properties ◽  
Single Molecule ◽  
Structural Characterization ◽  
Single Molecule Magnet ◽  
New Family

The synthesis, structural characterization and magnetic properties of a new family of hetero-tri-metallic complexes [M(CuTb)]n (n = 1, 2, ∞; M = Co, Cr, Fe), exhibiting single molecule magnet behaviour have been reported.

A new family of [CuIILnIIIMV] heterotrimetallic complexes (Ln = La, Gd, Tb; M = Mo, W): model systems to probe exchange interactions and single-molecule magnet properties

2016 ◽  
Vol 45 (18) ◽  
pp. 7642-7649 ◽  
Author(s):  
Diana Visinescu ◽  
Maria-Gabriela Alexandru ◽  
Augustin M. Madalan ◽  
Ie-Rang Jeon ◽  
Corine Mathonière ◽  
...  
Keyword(s):  
Single Molecule ◽  
Exchange Interactions ◽  
Model Systems ◽  
Single Molecule Magnet ◽  
New Family

Four 3d–4f–4(5)d heterotrimetallic complexes, [L2CuLn(H2O)5(μ-NC)M(CN)7], were obtained from the association of the binuclear 3d–4f complexes and {MV(CN)8}3− metalloligands.

Coordination polymers of a bis-isophthalate bridging ligand with single molecule magnet behaviour of the CoII analogue

2020 ◽  
Vol 49 (16) ◽  
pp. 5241-5249 ◽  
Author(s):  
Ali Y. Chahine ◽  
Wasinee Phonsri ◽  
Keith S. Murray ◽  
David R. Turner ◽  
Stuart R. Batten
Keyword(s):  
Coordination Polymer ◽  
Barrier Height ◽  
Coordination Polymers ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
Effective Barrier Height ◽  
Effective Barrier ◽  
Bridging Ligand

A Co(ii) coordination polymer shows SMM behaviour with an effective barrier height among the highest reported for such materials.

One-dimensional lanthanide coordination polymers supported by pentadentate Schiff-base and diphenyl phosphate ligands: single molecule magnet behavior and photoluminescence

2020 ◽  
Vol 44 (18) ◽  
pp. 7270-7276 ◽  
Author(s):  
Guo Peng ◽  
Yue Chen ◽  
Bo Li
Keyword(s):  
Schiff Base ◽  
Coordination Polymers ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
One Dimensional ◽  
Lanthanide Coordination Polymers ◽  
Diphenyl Phosphate ◽  
Phosphate Ligands

Four one-dimensional lanthanide coordination polymers constructed from Ln2 dimers showing single molecule magnet behavior and photoluminescence are reported.

2D chain layer versus 1D chain: rigid aromatic benzoate disassembling flexible alicyclic dicarboxylate-based lanthanide coordination polymers with enhanced photoluminescence and characteristic single-molecule magnet behavior

CrystEngComm ◽  
2020 ◽  
Vol 22 (26) ◽  
pp. 4449-4467 ◽  
Author(s):  
Jia-Yin Wang ◽  
Yang Shi ◽  
Dong-Liang Tao ◽  
Guo-Yin Yin ◽  
Qi-Bing Bo
Keyword(s):  
Coordination Polymers ◽  
Single Molecule ◽  
Layer Versus ◽  
Single Molecule Magnet ◽  
Lanthanide Coordination Polymers ◽  
Enhanced Photoluminescence ◽  
Characteristic Behavior ◽  
1D Chain

Used as photosensitizer and structural separator, aromatic benzoate activator was grafted on cyclopropane dicarboxylate-based lanthanide coordination polymers with efficient photoluminescence and characteristic behavior of single molecule magnet.

Synthesis and Magnetic Properties of a New Family of Macrocyclic MII3LnIII Complexes: Insights into the Effect of Subtle Chemical Modification on Single-Molecule Magnet Behavior

2012 ◽  
Vol 51 (20) ◽  
pp. 10603-10612 ◽  
Author(s):  
Humphrey L. C. Feltham ◽  
Rodolphe Clérac ◽  
Liviu Ungur ◽  
Veacheslav Vieru ◽  
Liviu F. Chibotaru ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Chemical Modification ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
New Family

Single molecule magnet behavior observed in a 1-D dysprosium chain with quasi-D5h symmetry

2015 ◽  
Vol 44 (48) ◽  
pp. 20834-20838 ◽  
Author(s):  
Xing-Cai Huang ◽  
Ming Zhang ◽  
Dayu Wu ◽  
Dong Shao ◽  
Xin-Hua Zhao ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Single Molecule Magnet ◽  
One Dimensional ◽  
Slow Magnetic Relaxation

Two one-dimensional coordination polymers with pentagonal bipyramidal DyIII centres show slow magnetic relaxation featuring single molecule magnet behavior.

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