Coordination of Carbon Dioxide to the Lewis Acid Site of a Zinc-Substituted Polyoxometalate and Formation of an Adduct Using a Polyoxometalate-2,4,6-Trimethylpyridine Frustrated Lewis Pair

2018 ◽  
Vol 2018 (6) ◽  
pp. 791-794 ◽  
Author(s):  
Bo Chen ◽  
Ronny Neumann
Keyword(s):  
Carbon Dioxide ◽  
Lewis Acid ◽  
Acid Site ◽  
Lewis Acid Site ◽  
Frustrated Lewis Pair

Lewis Acid Site-Promoted Single-Atomic Cu Catalyzes Electrochemical CO2 Methanation

Nano Letters ◽  
2021 ◽  
Author(s):  
Shenghua Chen ◽  
Bingqing Wang ◽  
Jiexin Zhu ◽  
Liqiang Wang ◽  
Honghui Ou ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Acid Site ◽  
Lewis Acid Site ◽  
Co2 Methanation

Bimetallic Metal-Organic Frameworks: Probing the Lewis Acid Site for CO2Conversion

Small ◽  
2016 ◽  
Vol 12 (17) ◽  
pp. 2334-2343 ◽  
Author(s):  
Ruyi Zou ◽  
Pei-Zhou Li ◽  
Yong-Fei Zeng ◽  
Jia Liu ◽  
Ruo Zhao ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Acid Site ◽  
Metal Organic Frameworks ◽  
Lewis Acid Site ◽  
Metal Organic

scholarly journals Lewis Acid Site and Hydrogen-Bond-Mediated Polarization Synergy in the Catalysis of Diels–Alder Cycloaddition by Band-Gap Transition-Metal Oxides

ACS Catalysis ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 701-715 ◽  
Author(s):  
Taha Salavati-fard ◽  
Efterpi S. Vasiliadou ◽  
Glen R. Jenness ◽  
Raul F. Lobo ◽  
Stavros Caratzoulas ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Metal Oxides ◽  
Band Gap ◽  
Lewis Acid ◽  
Transition Metal Oxides ◽  
Acid Site ◽  
Lewis Acid Site ◽  
Diels Alder

Propane Dehydrogenation Catalyzed by Single Lewis Acid Site in Sn-Beta Zeolite

2021 ◽  
Author(s):  
Yuanyuan Yue ◽  
Jing Fu ◽  
Chuanming Wang ◽  
Pei Yuan ◽  
Xiaojun Bao ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Acid Site ◽  
Lewis Acid Site ◽  
Propane Dehydrogenation ◽  
Beta Zeolite

scholarly journals Sintesis Dan Karakterisasi H-Aluminosilikat Sebagai Katalis Sintesis Biogasoline Dari Asam Oleat

2019 ◽  
Vol 4 (2) ◽  
pp. 100
Author(s):  
Deasi Adhiani Farida ◽  
Abdulloh Abdulloh ◽  
Ahmadi Jaya Permana
Keyword(s):  
Oleic Acid ◽  
Hydrothermal Method ◽  
Lewis Acid ◽  
Acid Site ◽  
Lewis Acid Site ◽  
Bronsted Acid ◽  
Bronsted Acid Site ◽  
Brønsted Acid Site ◽  
Brönsted Acid ◽  
Cracking Reaction

ABSTRACT          Aluminosilicate can be used for cracking reaction. In this study, catalyst of H-aluminosilicate has been synthesized by hydrothermal method with ratio molar Si/Al is 20. The characterizations has been performed by XRD, FTIR and acidity test. Characterization by XRD showed that catalyst of H-aluminosilicate have structure amorphous, while FTIR showed Si-O-Al bond at 457 cm-1. The acidity test showed that catalyst of H-aluminosilicate have Brønsted acid site 0.0272 mmol/g and Lewis acid site 0.0005 mmol/g. Oleic acid was cracking at 340 oC for 3 and 5 hours. The product has been analyzed by GC-MS not showed compound forming biogasoline.Keywords: H-aluminosilicate, biogasoline, oleic acid ABSTRAK          Aluminosilikat dapat digunakan sebagai katalis dalam reaksi prengkahan. Pada penelitian ini telah dilakukan sintesis katalis H-aluminosilikat melalui metode hidrotermal dengan rasio Si/Al sebesar 20. Karakterisasi yang telah dilakukan meliputi uji XRD, FTIR, dan keasaman.Hasil XRD menunjukkan katalis H-aluminosilikat berbentuk amorf, sedangkan pada FTIR menunjukkan ikatan Si-O-Al pada bilangan gelombang 457 cm-1. Uji situs asam menunjukkan katalis H-aluminosilikat memiliki jumlah asam Brønsted sebesar 0.0272 mmol/g dan jumlah sisi asam Lewis sebesar 0.0005 mmol/g. Proses perengkahan asam oleat telah dilakukan pada suhu 340oC selama 3 jam dan 5 jam. Produk cracking yang diuji dengan GC-MS tidak menunjukkan pembentukan senyawa biogasoline.Kata kunci: H-aluminosilikat, biogasoline, asam oleat

Photoinduced electron injection from an organic dye having a pyridyl anchor to Lewis acid site of TiO2 surface

RSC Advances ◽  
2015 ◽  
Vol 5 (87) ◽  
pp. 71387-71392 ◽  
Author(s):  
Yutaka Harima ◽  
Yuta Kano ◽  
Takuya Fujita ◽  
Ichiro Imae ◽  
Yousuke Ooyama ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Acid Site ◽  
Lewis Acid Site ◽  
Electron Injection ◽  
Organic Dye ◽  
Principal Factor ◽  
High Electron ◽  
Tio2 Surface

Adsorbability of dye onto TiO2 is not a principal factor for a high electron injection probability from dye to TiO2.

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