Coordination Chemistry of the PdmBOX Pincer Ligand: Reactivity at the Metal and the Ligand

2017 ◽  
Vol 2017 (47) ◽  
pp. 5545-5556 ◽  
Author(s):  
Jan Wenz ◽  
Vladislav Vasilenko ◽  
Alexander Kochan ◽  
Hubert Wadepohl ◽  
Lutz H. Gade
Keyword(s):  
Coordination Chemistry ◽  
Pincer Ligand ◽  
Ligand Reactivity

Coordination Chemistry and Reactivity of Zinc Complexes Supported by a Phosphido Pincer Ligand

2012 ◽  
Vol 18 (8) ◽  
pp. 2349-2360 ◽  
Author(s):  
Ilaria D'Auria ◽  
Marina Lamberti ◽  
Mina Mazzeo ◽  
Stefano Milione ◽  
Giuseppina Roviello ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Zinc Complexes ◽  
Pincer Ligand

scholarly journals Synthesis and Platinum Coordination Chemistry of the Perfluoroalkyl Acceptor Pincer Ligand 1,3-(CH2P(CF3)2)2C6H4

2008 ◽  
Vol 47 (22) ◽  
pp. 10796-10796 ◽  
Author(s):  
Jeramie J. Adams ◽  
Ade Lau ◽  
Navamoney Arulsamy ◽  
Dean M. Roddick
Keyword(s):  
Coordination Chemistry ◽  
Pincer Ligand

scholarly journals The Fascinating Flexibility and Coordination Modes of a Pentamethylene Connected Macrocyclic CNC Pincer Ligand

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1669
Author(s):  
Ronja Jordan ◽  
Doris Kunz
Keyword(s):  
Crystal Structure ◽  
Coordination Chemistry ◽  
Nmr Spectroscopy ◽  
Carbon Atom ◽  
Coordination Mode ◽  
Alkyl Chain ◽  
Crystal Structure Analysis ◽  
Pincer Ligand ◽  
X Ray ◽  
Central Carbon

The coordination chemistry of an electron-rich macrocyclic CNC pincer-ligand consisting of two pentamethylene tethered N-heterocyclic carbene moieties on a carbazole backbone (bimcaC5) is investigated by mainly NMR spectroscopy and X-ray crystal structure analysis. A bridging coordination mode is found for the lithium complex. With the larger and softer potassium ion, the ligand adopts a facial coordination mode and a polymeric structure by intermolecular potassium nitrogen interactions. The facial coordination is also confirmed at a Cp*Ru fragment, while C-H activation under dehydrogenation at the alkyl chain is observed upon reaction with [Ru(PPh3)3Cl2]. In contrast, Pd(OAc)2 reacts under C-H activation at the central carbon atom of the pentamethylene tether to an alkyl-pincer macrocycle.

scholarly journals Unexpected Reactivity of a PONNOP ‘Expanded Pincer’ Ligand

2020 ◽  
Author(s):  
Arthur Scheerder ◽  
Martin Lutz ◽  
Daniël Broere
Keyword(s):  
Coordination Chemistry ◽  
Pincer Ligand ◽  
Close Proximity

<p>We report the synthesis, characterization and coordination chemistry of a new naphthyridine-derived phosphinite PONNOP expanded pincer ligand. As envisioned, the dinucleating ligand readily binds two copper(I) centers in close proximity, but undergoes an unexpected rearrangement in the presence of nickel(II) salts to form an interesting PONNP pincer platform. </p>

scholarly journals Unexpected Reactivity of a PONNOP ‘Expanded Pincer’ Ligand

2020 ◽  
Author(s):  
Arthur Scheerder ◽  
Martin Lutz ◽  
Daniël Broere
Keyword(s):  
Coordination Chemistry ◽  
Pincer Ligand ◽  
Close Proximity

<p>We report the synthesis, characterization and coordination chemistry of a new naphthyridine-derived phosphinite PONNOP expanded pincer ligand. As envisioned, the dinucleating ligand readily binds two copper(I) centers in close proximity, but undergoes an unexpected rearrangement in the presence of nickel(II) salts to form an interesting PONNP pincer platform. </p>

Synthesis and Platinum Coordination Chemistry of the Perfluoroalkyl Acceptor Pincer Ligand, 1,3-(CH2P(CF3)2)2C6H4

2007 ◽  
Vol 46 (26) ◽  
pp. 11328-11334 ◽  
Author(s):  
Jeramie J. Adams ◽  
Ade Lau ◽  
Navamoney Arulsamy ◽  
Dean M. Roddick
Keyword(s):  
Coordination Chemistry ◽  
Pincer Ligand
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