Front Cover: [Pt(SCN)4 ]2- -Based Coordination Polymers and Supramolecular Squares: Intermolecular Pt···H-C Interactions Probed by Luminescence Spectroscopy at Variable Pressure (Eur. J. Inorg. Chem. 22/2017)

2017 ◽  
Vol 2017 (22) ◽  
pp. 2863-2863
Author(s):  
Yan Suffren ◽  
Masayuki Kobayashi ◽  
Jeffrey S. Ovens ◽  
Alexandre Rodrigue-Witchel ◽  
Caroline Genre ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Variable Pressure ◽  
Luminescence Spectroscopy ◽  
Front Cover

scholarly journals [Pt(SCN)4 ]2- -Based Coordination Polymers and Supramolecular Squares: Intermolecular Pt···H-C Interactions Probed by Luminescence Spectroscopy at Variable Pressure

2017 ◽  
Vol 2017 (22) ◽  
pp. 2864-2864 ◽  
Author(s):  
Yan Suffren ◽  
Masayuki Kobayashi ◽  
Jeffrey S. Ovens ◽  
Alexandre Rodrigue-Witchel ◽  
Caroline Genre ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Variable Pressure ◽  
Luminescence Spectroscopy

[Pt(SCN)4]2--Based Coordination Polymers and Supramolecular Squares: Intermolecular Pt···H-C Interactions Probed by Luminescence Spectroscopy at Variable Pressure

2017 ◽  
Vol 2017 (22) ◽  
pp. 2865-2875 ◽  
Author(s):  
Yan Suffren ◽  
Masayuki Kobayashi ◽  
Jeffrey S. Ovens ◽  
Alexandre Rodrigue-Witchel ◽  
Caroline Genre ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Variable Pressure ◽  
Luminescence Spectroscopy

Interaction of Thioether Groups at the Open Coordination Sites of Palladium(II) and Platinum(II) Complexes Probed by Luminescence Spectroscopy at Variable Pressure

2010 ◽  
Vol 49 (11) ◽  
pp. 4901-4908 ◽  
Author(s):  
Esther Pierce ◽  
Etienne Lanthier ◽  
Caroline Genre ◽  
Yurii Chumakov ◽  
Dominique Luneau ◽  
...  
Keyword(s):  
Variable Pressure ◽  
Luminescence Spectroscopy ◽  
Coordination Sites

Controlling dimensionality via a dual ligand strategy in Ln-thiophene-2,5-dicarboxylic acid-terpyridine coordination polymers

2015 ◽  
Vol 44 (36) ◽  
pp. 15843-15854 ◽  
Author(s):  
Korey P. Carter ◽  
Cecília H. F. Zulato ◽  
Emille M. Rodrigues ◽  
Simon J. A. Pope ◽  
Fernando A. Sigoli ◽  
...  
Keyword(s):  
Single Crystal ◽  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Luminescence Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray

Eleven new lanthanide-2,5-TDC-terpyridine coordination polymers which employ a dual ligand strategy have been synthesized and characterized by single crystal and powder X-ray diffraction as well as luminescence spectroscopy.

scholarly journals Front Cover: Luminescent Coordination Polymers Constructed from a Flexible, Tetradentate Diisopyrazole Ligand and Copper(I) Halides (Chem. Asian J. 5/2020)

2020 ◽  
Vol 15 (5) ◽  
pp. 546-546
Author(s):  
Tomoki Yoneda ◽  
Chika Kasai ◽  
Yumehiro Manabe ◽  
Makoto Tsurui ◽  
Yuichi Kitagawa ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Front Cover

Inside Front Cover: A Combined Top-Down/Bottom-Up Approach for the Nanoscale Patterning of Spin-Crossover Coordination Polymers (Adv. Mater. 16/2007)

2007 ◽  
Vol 19 (16) ◽  
pp. NA-NA
Author(s):  
G. Molnár ◽  
S. Cobo ◽  
J. A. Real ◽  
F. Carcenac ◽  
E. Daran ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Spin Crossover ◽  
Top Down ◽  
Bottom Up ◽  
Front Cover ◽  
Nanoscale Patterning

Temperature- and pressure-dependent luminescence spectroscopy on the trans-[ReO2(pyridine)4]+ complex — Analysis of vibronic structure, luminescence energies, and bonding characteristics

2004 ◽  
Vol 82 (6) ◽  
pp. 1083-1091 ◽  
Author(s):  
John K Grey ◽  
Ian S Butler ◽  
Christian Reber
Keyword(s):  
Molecular Structure ◽  
Low Temperature ◽  
Room Temperature ◽  
Complex Analysis ◽  
Variable Pressure ◽  
Luminescence Spectroscopy ◽  
Luminescence Spectra ◽  
Vibronic Structure ◽  
Temperature Spectra ◽  
Temperature And Pressure

Resolved vibronic structure in electronic spectra provides a detailed view into how molecular structure changes after absorption or emission of a photon. We report temperature- and pressure-dependent luminescence spectra of trans-[ReO2(pyridine)4]I. Low-temperature spectra reveal long vibronic progressions in the totally symmetric O=Re=O (907 cm–1) and Re-pyridine (211 cm–1) stretching modes, indicating large structural displacements along these normal coordinates. The luminescence band maximum is at ca. 15 500 cm–1. Room-temperature spectra are somewhat less-resolved; however, intervals closely matching the O=Re=O frequency (~870 cm–1) persist at higher temperatures. The variable pressure spectra exhibit distinct changes in the vibronic patterns, and luminescence energies decrease by 16 ± 2 cm–1/kbar (1 bar = 100 kPa). Low-temperature spectra are modeled using two-dimensional potential energy surfaces to represent the initial and final electronic states, from which the quantitative normal coordinate offsets can be determined. We then adapt this model to the room-temperature, pressure-dependent data where it is possible to determine how the offsets and other important spectroscopic parameters vary with the pressure-induced changes of the molecular structure. Key words: trans-[ReO2(pyridine)4]I, low-temperature luminescence spectroscopy, high-pressure luminescence spectroscopy, vibronic structure, emitting state distortions.

Sign in / Sign up

Export Citation Format

Share Document