Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

2016 ◽  
Vol 2016 (21) ◽  
pp. 3506-3512 ◽  
Author(s):  
Aysun Bulut ◽  
Yunus Zorlu ◽  
Michael Wörle ◽  
Salih Paşa ◽  
Hüseyin Kurt ◽  
...  
2021 ◽  
Vol 7 (23) ◽  
pp. eabf9402
Author(s):  
Katherine C. Elbert ◽  
William Zygmunt ◽  
Thi Vo ◽  
Corbin M. Vara ◽  
Daniel J. Rosen ◽  
...  

The use of nanocrystal (NC) building blocks to create metamaterials is a powerful approach to access emergent materials. Given the immense library of materials choices, progress in this area for anisotropic NCs is limited by the lack of co-assembly design principles. Here, we use a rational design approach to guide the co-assembly of two such anisotropic systems. We modulate the removal of geometrical incompatibilities between NCs by tuning the ligand shell, taking advantage of the lock-and-key motifs between emergent shapes of the ligand coating to subvert phase separation. Using a combination of theory, simulation, and experiments, we use our strategy to achieve co-assembly of a binary system of cubes and triangular plates and a secondary system involving two two-dimensional (2D) nanoplates. This theory-guided approach to NC assembly has the potential to direct materials choices for targeted binary co-assembly.


Nanoscale ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 3129-3137 ◽  
Author(s):  
Huu Duy Nguyen ◽  
Joon Sang Kang ◽  
Man Li ◽  
Yongjie Hu

Rational design of two-dimensional tin selenide (SnSe) nanostructures enables high-performance field emission for developing nanoscale vacuum transistors.


2020 ◽  
Vol 13 (4) ◽  
pp. 1049-1075 ◽  
Author(s):  
Milan Jana ◽  
Rui Xu ◽  
Xin-Bing Cheng ◽  
Jeong Seok Yeon ◽  
Jae Min Park ◽  
...  

2D materials, their features and possible approaches to mitigating the challenges in Li–S batteries are discussed.


ACS Nano ◽  
2010 ◽  
Vol 4 (4) ◽  
pp. 1813-1820 ◽  
Author(s):  
Sebastian Stepanow ◽  
Robin Ohmann ◽  
Frederic Leroy ◽  
Nian Lin ◽  
Thomas Strunskus ◽  
...  

CrystEngComm ◽  
2016 ◽  
Vol 18 (9) ◽  
pp. 1645-1654 ◽  
Author(s):  
Yu Meng ◽  
Qiufeng Li ◽  
Tiantian Yu ◽  
Sen Zhang ◽  
Chao Deng

The principle for the rational design of a sulfate/C composite was based on its architecture–physicochemical property relationships and the requirement of its applications.


2015 ◽  
Vol 6 (11) ◽  
pp. 1896-1911 ◽  
Author(s):  
Zhonghua Xiang ◽  
Dapeng Cao ◽  
Liming Dai

Recent developments in the design, synthesis and application of 2D covalent organic polymers are reviewed, along with some perspectives and challenges.


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