Reactivity of a Monomeric Aluminium Hydrazide towards Isocyanates and Isothiocyanates: Active Lewis Pair Behaviour versus Classical Insertion Reactions

2016 ◽  
Vol 2016 (17) ◽  
pp. 2721-2730 ◽  
Author(s):  
Werner Uhl ◽  
Julia Silissa Bruchhage ◽  
Matthias Willeke ◽  
Alexander Hepp ◽  
Jutta Kösters
Keyword(s):  
Insertion Reactions

scholarly journals Reply to “Comment on ‘Atomistic Mechanisms of Mg Insertion Reactions in Group XIV Anodes for Mg-Ion Batteries’”

2020 ◽  
Vol 12 (13) ◽  
pp. 14739-14740
Author(s):  
Mingchao Wang ◽  
Jodie A. Yuwono ◽  
Vallabh Vasudevan ◽  
Nick Birbilis ◽  
Nikhil V. Medhekar
Keyword(s):  
Insertion Reactions ◽  
Group Xiv

The chemistry of stabilized clusters

1982 ◽  
Vol 308 (1501) ◽  
pp. 27-34 ◽  
Keyword(s):  
Electron Donor ◽  
Organic Molecules ◽  
Metal Cluster ◽  
Organic Substrates ◽  
Insertion Reactions ◽  
Donor Ligand ◽  
Small Organic Molecules ◽  
Wide Range ◽  
Metal Metal ◽  
High Yields

Studies of the chemistry of metal cluster complexes and, in particular, their reactions with small organic molecules, have been confined to relatively few systems. Among the reasons for this are: (i) not many clusters are easily synthesized in high yields; (ii) their reactions often give a multitude of products that are difficult to separate and characterize; (iii) the conditions required to bring about reactions often lead to fragmentation of the cluster into lower nuclearity (often mononuclear) species. One cluster whose chemistry has been extensively studied is [Os 3 H 2 (CO) 10 ]. This can be synthesized in high yields from [Os 3 (CO) 12 ] + H 2 (Knox et al. 1975) and reacts readily under mild conditions with a wide range of electron-donor molecules by virtue of its coordinative unsaturation (Shapley et al. 1975; Deeming & Hasso 1976; Adams & Golembeski 1979). Formally, one may consider that a metal—metal double bond is present, which is reduced to a single bond on coordination of an additional two-electron donor ligand such as an organophosphine. The presence of metal—hydrogen bonds in this cluster and the cluster’s ability to coordinate organic substrates enable it to undergo a wide variety of insertion reactions, leading to products that may be regarded as intermediates in the reduction of organic molecules by clusters (Deeming & Hasso 1975; Keister & Shapley 1975).

Insertion Reactions of CO into the Rhenium−Nitrogen Bond. η2-Carbamoyl Complexes and Their Reactions

1998 ◽  
Vol 17 (2) ◽  
pp. 131-138 ◽  
Author(s):  
Tein-Fu Wang ◽  
Chong-Chen Hwu ◽  
Chia-Wen Tsai ◽  
Yuh-Sheng Wen
Keyword(s):  
Insertion Reactions ◽  
Nitrogen Bond

The insertion reactions of “crowned” indium(I) trifluoromethanesulfonate into carbon–chlorine bonds

2007 ◽  
Vol 692 (13) ◽  
pp. 2843-2848 ◽  
Author(s):  
Benjamin F.T. Cooper ◽  
Christopher G. Andrews ◽  
Charles L.B. Macdonald
Keyword(s):  
Insertion Reactions

Catalytic Generation of Zinc Carbenes from Alkynes: Zinc-Catalyzed Cyclopropanation and SiH Bond Insertion Reactions

2012 ◽  
Vol 124 (32) ◽  
pp. 8187-8191 ◽  
Author(s):  
Rubén Vicente ◽  
Jesús González ◽  
Lorena Riesgo ◽  
Javier González ◽  
Luis A. López
Keyword(s):  
Insertion Reactions
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