Mononuclear Iron(II) Dicarbonyls Derived from NNS Ligands - Structural Models Related to a “Pre-Acyl” Active Site of Mono-Iron (Hmd) Hydrogenase

2015 ◽  
Vol 2015 (10) ◽  
pp. 1675-1691 ◽  
Author(s):  
Keren A. Thomas Muthiah ◽  
Gummadi Durgaprasad ◽  
Zhu-Lin Xie ◽  
Owen M. Williams ◽  
Christopher Joseph ◽  
...  
Keyword(s):  
Active Site ◽  
Structural Models ◽  
Mononuclear Iron

Structural Models for the Active Site of Acetyl-CoA Synthase: Synthesis of Dinuclear Nickel Complexes Having Thiolate, Isocyanide, and Thiourea on the NipSite

2009 ◽  
Vol 48 (3) ◽  
pp. 1250-1256 ◽  
Author(s):  
Mikinao Ito ◽  
Mai Kotera ◽  
Yumei Song ◽  
Tsuyoshi Matsumoto ◽  
Kazuyuki Tatsumi
Keyword(s):  
Active Site ◽  
Nickel Complexes ◽  
Structural Models ◽  
Acetyl Coa

scholarly journals Coordination and conformational isomers in mononuclear iron complexes with pertinence to the [FeFe] hydrogenase active site

2014 ◽  
Vol 43 (11) ◽  
pp. 4537-4549 ◽  
Author(s):  
Andreas Orthaber ◽  
Michael Karnahl ◽  
Stefanie Tschierlei ◽  
Daniel Streich ◽  
Matthias Stein ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Active Site ◽  
Iron Complexes ◽  
Computational Studies ◽  
Mononuclear Iron ◽  
Conformational Isomers ◽  
Ligand Modification ◽  
Fe Complexes ◽  
Ir Spectroscopic

6 Fe complexes of the type [Fe(X-bdt)(PR2NPh2)(CO)] were prepared and the possibility to tune their electronic properties by ligand modification was demonstrated. IR spectroscopic and computational studies suggest that the compounds exist as a mixture of isomers in solution.

scholarly journals A 2‐Tyr‐1‐carboxylate Mononuclear Iron Center Forms the Active Site of a Paracoccus Dimethylformamidase

2020 ◽  
Vol 132 (39) ◽  
pp. 17109-17114
Author(s):  
Chetan Kumar Arya ◽  
Swati Yadav ◽  
Jonathan Fine ◽  
Ana Casanal ◽  
Gaurav Chopra ◽  
...  
Keyword(s):  
Active Site ◽  
Mononuclear Iron ◽  
Iron Center

Anion Binding Tripodal Receptors as Structural Models for the Active Site of Vanadium Haloperoxidases and Acid Phosphatases

2006 ◽  
Vol 18 (1) ◽  
pp. 55-58 ◽  
Author(s):  
Sophia Tapper ◽  
Jennifer A. Littlechild ◽  
Yann Molard ◽  
Ivan Prokes ◽  
James H. R. Tucker
Keyword(s):  
Active Site ◽  
Structural Models ◽  
Anion Binding ◽  
Acid Phosphatases
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