Synthesis of Metforminium(2+) Decavanadates - Crystal Structures and Solid-State Characterization

2014 ◽  
Vol 2014 (27) ◽  
pp. 4581-4588 ◽  
Author(s):  
Irma Sánchez-Lombardo ◽  
Eduardo Sánchez-Lara ◽  
Aarón Pérez-Benítez ◽  
Ángel Mendoza ◽  
Sylvain Bernès ◽  
...  
Keyword(s):  
Solid State ◽  
Crystal Structures ◽  
Solid State Characterization

Mono- and difunctional furan-based 1,2,3,5-dithiadiazolyl radicals; preparation and solid state structures of 2,5-[(S2N2C)OC4H2(CN2S2)] and 2,5-[(S2N2C)OC4H2(CN)]

1992 ◽  
Vol 70 (3) ◽  
pp. 919-925 ◽  
Author(s):  
A. Wallace Cordes ◽  
Charles M. Chamchoumis ◽  
Robin G. Hicks ◽  
Richard T. Oakley ◽  
Kelly M. Young ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Crystal Structures ◽  
Monoclinic Space Group ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
The Mean ◽  
Solid State Structures ◽  
Solid State Characterization

The preparation and solid state characterization of the bifunctional radical furan-2,5-bis(1,2,3,5-dithiadiazolyl) 2,5-[(S2N2C)OC4H2(CN2S2)] and the related monofunctional radical 2-cyanofuran-5-(1,2,3,5-dithiadiazolyl) 2,5-[(S2N2C)OC4H2(CN)] are described. The crystal structure of 2,5-[(S2N2C)OC4H2(CN2S2)] is orthorhombic, space group Pna21, and consists of interleaved arrays of dimers, for which the mean interannular [Formula: see text] contact is 3.137 Å. The crystal structure of the monofunctional radical 2,5-[(S2N2C)OC4H2(CN)] is monoclinic, space group P21/n, and consists of a ribbon-like network of dimers (mean interannular [Formula: see text] interconnected by close head-to-tail [Formula: see text] contacts. The dimer units form stacks parallel to z, with a mean interdimer [Formula: see text] separation of 3.956 Å. The similarities and differences between these two crystal structures and those of related benzene-substituted systems are discussed. Keywords: dithiadiazolyl radicals, furan-based diradicals, cyanofuran-based radicals, radical dimers, crystal structures.

Deciphering preferred solid-state conformations in nitrogen-containing bisphosphonates and their coordination compounds. A case study of discrete Cu(ii) complexes based on Cα-substituted analogues of zoledronic acid: crystal structures and solid-state characterization

CrystEngComm ◽  
2019 ◽  
Vol 21 (29) ◽  
pp. 4340-4353 ◽  
Author(s):  
Tomasz Rojek ◽  
Waldemar Goldeman ◽  
Katarzyna Ślepokura ◽  
Wiktor Zierkiewicz ◽  
Ewa Matczak-Jon
Keyword(s):  
Zoledronic Acid ◽  
Solid State ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Coordination Compounds ◽  
Acid Crystal ◽  
Bisphosphonic Acids ◽  
Solid State Characterization

Conformation diversity of N-containing bisphosphonic acids and related anions within their metal complexes and salts.

scholarly journals Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 199-227
Author(s):  
Young Hoon Lee ◽  
Jee Young Kim ◽  
Sotaro Kusumoto ◽  
Hitomi Ohmagari ◽  
Miki Hasegawa ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Weak Interactions ◽  
Dispersion Interactions ◽  
Derivatives Of

Analysis of the weak interactions within the crystal structures of 33 complexes of various 4′-aromatic derivatives of 2,2′:6′,2″-terpyridine (tpy) shows that interactions that exceed dispersion are dominated, as expected, by cation⋯anion contacts but are associated with both ligand–ligand and ligand–solvent contacts, sometimes multicentred, in generally complicated arrays, probably largely determined by dispersion interactions between stacked aromatic units. With V(V) as the coordinating cation, there is evidence that the polarisation of the ligand results in an interaction exceeding dispersion at a carbon bound to nitrogen with oxygen or fluorine, an interaction unseen in the structures of M(II) (M = Fe, Co, Ni, Cu, Zn, Ru and Cd) complexes, except when 1,2,3-trimethoxyphenyl substituents are present in the 4′-tpy.

Cocrystals of Propylthiouracil and Nutraceuticals toward Sustained-Release: Design, Structure Analysis, and Solid-State Characterization

2021 ◽  
Vol 21 (2) ◽  
pp. 1202-1217
Author(s):  
Yuntian Xiao ◽  
Ling Zhou ◽  
Hongxun Hao ◽  
Ying Bao ◽  
Qiuxiang Yin ◽  
...  
Keyword(s):  
Solid State ◽  
Sustained Release ◽  
Structure Analysis ◽  
Design Structure ◽  
Solid State Characterization

Bis(1-phenyl-1-propyne) complexes of tungsten(II): crystal structures of [WI2(CO)(NCR)(η2-MeC2Ph)2] (R = Me, Et, or Ph)

2001 ◽  
Vol 79 (3) ◽  
pp. 263-271
Author(s):  
Paul K Baker ◽  
Michael GB Drew ◽  
Deborah S Evans
Keyword(s):  
Carbon Monoxide ◽  
Solid State ◽  
Crystal Structures ◽  
Octahedral Geometry ◽  
X Ray ◽  
X Ray Crystallography ◽  
Alkyne Complexes ◽  
First Time

Reaction of [WI2(CO)3(NCMe)2] with two equivalents of 1-phenyl-1-propyne (MeC2Ph) in CH2Cl2, and in the absence of light, gave the bis(1-phenyl-1-propyne) complex [WI2(CO)(NCMe)(η2-MeC2Ph)2] (1) in 77% yield. Treatment of equimolar quantities of 1 and NCR (R = Et, i-Pr, t-Bu, Ph) in CH2Cl2 afforded the nitrile-exchanged products, [WI2(CO)(NCR)(η2-MeC2Ph)2] (2-5) (R = Et (2), i-Pr (3), t-Bu (4), Ph (5)). Complexes 1, 2, and 5 were structurally characterized by X-ray crystallography. All three structures have the same pseudo-octahedral geometry, with the equatorial sites being occupied by cis and parallel alkyne groups, which are trans to the cis-iodo groups. The trans carbon monoxide and acetonitrile ligands occupy the axial sites. In structures 1 and 2, the methyl and phenyl substituents of the 1-phenyl-1-propyne ligands are cis to each other, whereas for the bulkier NCPh complex (5), the methyl and phenyl groups are trans to one another. This is the first time that this arrangement has been observed in the solid state in bis(alkyne) complexes of this type.Key words: bis(1-phenyl-1-propyne), carbonyl, nitrile, diiodo, tungsten(II), crystal structures.

Solid-State Characterization of Amorphous and Mesomorphous Calcium Ketoprofen

2010 ◽  
Vol 99 (9) ◽  
pp. 3684-3697 ◽  
Author(s):  
Faraj Atassi ◽  
Chen Mao ◽  
Ahmad S. Masadeh ◽  
Stephen R. Byrn
Keyword(s):  
Solid State ◽  
Solid State Characterization

Microwave assisted synthesis and solid-state characterization of lithocholyl amides of isomeric aminopyridines

Steroids ◽  
2011 ◽  
Vol 76 (3) ◽  
pp. 261-268 ◽  
Author(s):  
Kari V. Ahonen ◽  
Manu K. Lahtinen ◽  
Arto M. Valkonen ◽  
Martin Dračínský ◽  
Erkki T. Kolehmainen
Keyword(s):  
Solid State ◽  
Microwave Assisted Synthesis ◽  
Microwave Assisted ◽  
Solid State Characterization
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