Reversible Reactions of Ni and Pd Hydroxo Pincer Complexes [(iPrPCP)M-OH] with CO2: Solid-State Study of the Decarboxylation of the Monomeric Bicarbonate Complexes [(iPrPCP)M-OCOOH] (M = Ni, Pd)

2013 ◽  
Vol 2013 (32) ◽  
pp. 5555-5566 ◽  
Author(s):  
Luis Miguel Martínez-Prieto ◽  
Concepción Real ◽  
Elena Ávila ◽  
Eleuterio Álvarez ◽  
Pilar Palma ◽  
...  
Keyword(s):  
Solid State ◽  
Pincer Complexes ◽  
State Study ◽  
Reversible Reactions

scholarly journals Four Thermochromic o-Hydroxy Schiff Bases of α-Aminodiphenylmethane: Solution and Solid State Study

Crystals ◽  
2017 ◽  
Vol 7 (1) ◽  
pp. 25 ◽  
Author(s):  
Marija Zbačnik ◽  
Katarina Pičuljan ◽  
Jelena Parlov-Vuković ◽  
Predrag Novak ◽  
Andreas Roodt
Keyword(s):  
Solid State ◽  
Schiff Bases ◽  
State Study

scholarly journals From μ3- to μ- Agostic Methyl Coordination: NMR and Solid State Study of Donor Ligands Uptake by the Triangular Cluster Anion [Re3(μ-H)3(μ3-CH3)(CO)9]-

2021 ◽  
pp. 120641
Author(s):  
Daniela Maggioni ◽  
Donato Tunzi ◽  
Pasquale Illiano ◽  
Pierluigi Mercandelli ◽  
Angelo Sironi ◽  
...  
Keyword(s):  
Solid State ◽  
Cluster Anion ◽  
Donor Ligands ◽  
State Study

scholarly journals Not Your Usual Bioisostere: Solid State Study of 3D Interactions in Cubanes

2019 ◽  
Vol 25 (28) ◽  
pp. 6941-6954 ◽  
Author(s):  
Keith J. Flanagan ◽  
Stefan S. R. Bernhard ◽  
Shane Plunkett ◽  
Mathias O. Senge
Keyword(s):  
Solid State ◽  
State Study

Reactions of a pincer proligand with copper iodide: bridging instead of C–H metalation

2020 ◽  
Vol 98 (9) ◽  
pp. 524-530
Author(s):  
Taghrid Chahrour ◽  
Annie Castonguay ◽  
Paul O. Oguadinma ◽  
Frank Schaper ◽  
Davit Zargarian
Keyword(s):  
Solid State ◽  
The Other ◽  
Strong Preference ◽  
Pincer Complexes ◽  
Divalent Copper ◽  
Copper Iodide ◽  
Tetrahedral Geometry ◽  
Central Carbon ◽  
Copper Center ◽  
Solid State Structures

Various precursors of divalent copper have been treated with the meta-disubstituted phenylene-based proligand POC(H)OP (1,3-(i-Pr2PO)2C6H4) with the objective of preparing classical pincer complexes (POCOP)CuX. However, in no case was such species obtained, presumably owing to the difficult C–H metallation step. Analogous reactions of monovalent precursors were also unsuccessful, whereas reaction of POC(H)OP with CuI under different conditions gave the non-metallated adducts {(μ, κP, [Formula: see text]-POC(H)OP)Cu(μ-Ι)}2, 1, {(μ, κP, [Formula: see text]-POC(H)OP)Cu2(μ-Ι)2(DMAP)2}, 2 (DMAP = 4-dimethylaminopyridine), and {(μ, κP, [Formula: see text]-POC(H)OP)Cu2(μ3-Ι)2}2, 3. Treating 1 with DMAP gave the adduct 2, whereas 3 could be obtained by treating 1 with BuLi or by sublimation of 1. The solid state structures of these complexes revealed the tetrahedral geometry that might be anticipated for the d10 Cu(I) centers, in addition to fairly close I–H distances; on the other hand, no C–H interaction (agostic or otherwise) was observed with the Cu centers in any of these structures. The unsuccessful metallation of the C(2)–H moiety is thought to be a result of the strong preference of monovalent copper center to form bridging interactions with iodide and the POC(H)OP ligand; this appears to prevent the approach of the central carbon of the ligand to the Cu centers.

Solid-state study of charge-transfer interactions in copolymers

1990 ◽  
Vol 23 (24) ◽  
pp. 5127-5132 ◽  
Author(s):  
Alexandra Simmons ◽  
Almeria Natansohn
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
State Study

Stereochemistry and Stereoelectronics of Azines. A Solid State Study of Symmetrical, (E,E)-Configured, Para-Substituted (H, F, Cl, Br, CN) Acetophenone Azines

1994 ◽  
Vol 59 (15) ◽  
pp. 4336-4340 ◽  
Author(s):  
Grace Shiahuy Chen ◽  
Mitchell Anthamatten ◽  
Charles L. Barnes ◽  
Rainer Glaser
Keyword(s):  
Solid State ◽  
State Study

Re2I2(CO)6(Se7), a Coordination Compound of Elemental Selenium with a Transition Metal: A Solution- and Solid-State Study

1994 ◽  
Vol 33 (2) ◽  
pp. 193-195 ◽  
Author(s):  
Alessia Bacchi ◽  
Walter Baratta ◽  
Fausto Calderazzo ◽  
Fabio Marchetti ◽  
Giancarlo Pelizzi
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Coordination Compound ◽  
Elemental Selenium ◽  
State Study

Palladium(II) Complexation byp-Cyclophane Receptors. A Solution and Solid State Study

1999 ◽  
Vol 38 (9) ◽  
pp. 2064-2070 ◽  
Author(s):  
Andrea Bencini ◽  
Antonio Bianchi ◽  
Vieri Fusi ◽  
Claudia Giorgi ◽  
Piero Paoletti ◽  
...  
Keyword(s):  
Solid State ◽  
State Study
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