Small-Molecule Activation by Reactive Metal Complexes

2013 ◽  
Vol 2013 (22-23) ◽  
pp. 3731-3732 ◽  
Author(s):  
Connie C. Lu ◽  
Karsten Meyer
Keyword(s):  
Metal Complexes ◽  
Small Molecule ◽  
Small Molecule Activation ◽  
Reactive Metal

scholarly journals Low-coordinate first-row transition metal complexes in catalysis and small molecule activation

2019 ◽  
Vol 48 (33) ◽  
pp. 12365-12381 ◽  
Author(s):  
Laurence J. Taylor ◽  
Deborah L. Kays
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Small Molecules ◽  
Transition Metal Complexes ◽  
Small Molecule ◽  
High Reactivity ◽  
Small Molecule Activation ◽  
Coordination Numbers

In this Perspective, we will highlight selected examples of transition metal complexes with low coordination numbers whose high reactivity has been exploited in catalysis and the activation of small molecules featuring strong bonds (N2, CO2, and CO).

Molecular quaterpyridine-based metal complexes for small molecule activation: water splitting and CO2 reduction

2020 ◽  
Vol 49 (20) ◽  
pp. 7271-7283
Author(s):  
Lingjing Chen ◽  
Gui Chen ◽  
Chi-Fai Leung ◽  
Claudio Cometto ◽  
Marc Robert ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Water Splitting ◽  
Small Molecule ◽  
Co2 Reduction ◽  
Small Molecule Activation ◽  
Recent Developments

This tutorial describes recent developments in the use of metal quaterpyridine complexes as electrocatalysts and photocatalysts for water splitting and CO2 reduction.

Small molecule activation by mixed methyl/methylidene rare earth metal complexes

2016 ◽  
Vol 45 (15) ◽  
pp. 6641-6649 ◽  
Author(s):  
Jianquan Hong ◽  
Zhenhua Li ◽  
Zhening Chen ◽  
Linhong Weng ◽  
Xigeng Zhou ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Complexes ◽  
Small Molecule ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Rare Earth Complexes ◽  
Small Molecule Activation ◽  
Rare Earth Metal Complexes

Diverse reactivity patterns of mixed tetramethyl/methylidene rare-earth complexes bearing bulky benzamidinate coligands with PhCN, alkynes, and CS2 have been established and fully characterized.

scholarly journals d/f‐Polypnictides Derived by Non‐Classical Ln2+ Compounds: Synthesis, Small Molecule Activation and Optical Properties

2021 ◽  
Author(s):  
Peter Werner Roesky ◽  
Niklas Reinfandt ◽  
Nadine Michenfelder ◽  
Christoph Schoo ◽  
Ravi Yadav ◽  
...  
Keyword(s):  
Optical Properties ◽  
Small Molecule ◽  
Small Molecule Activation

Tuning metal–metal interactions for cooperative small molecule activation

2021 ◽  
Author(s):  
Qiuran Wang ◽  
Sam H. Brooks ◽  
Tianchang Liu ◽  
Neil C. Tomson
Keyword(s):  
Small Molecule ◽  
Small Molecule Activation ◽  
Feature Article ◽  
Metal Interactions ◽  
Recent Advances ◽  
Metal Metal

This Feature Article describes recent advances in the design of multinucleating ligands that support small molecule activation chemistry.

Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity

2021 ◽  
Author(s):  
Rong Zhang ◽  
Yanchao Wang ◽  
Yanxia Zhao ◽  
Carl Redshaw ◽  
Igor L. Fedushkin ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Small Molecule ◽  
Main Group ◽  
Group Metal ◽  
Diimine Ligands ◽  
Main Group Metal ◽  
Metal Metal ◽  
Low Valent

The use of dad (and bian) ligands in the stabilization of main-group complexes, in particular metal–metal-bonded compounds, as well as the small molecule reactivity of these (low-valent) metal complexes, is summarized.

Small Molecule Activation by POC sp 3OP-Nickel Complexes

2014 ◽  
Vol 20 (39) ◽  
pp. 12544-12552 ◽  
Author(s):  
Jingjun Hao ◽  
Boris Vabre ◽  
Berline Mougang-Soumé ◽  
Davit Zargarian
Keyword(s):  
Small Molecule ◽  
Nickel Complexes ◽  
Small Molecule Activation
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