Bringing Redox Reactivity to a Redox Inactive Metal Center - E-I (E = C, Si) Bond Cleavage with a Thorium Bis(α-diimine) Complex

Agnes Mrutu; Charles L. Barnes; Suzanne C. Bart; Justin R. Walensky

doi:10.1002/ejic.201300390

Bringing Redox Reactivity to a Redox Inactive Metal Center - E-I (E = C, Si) Bond Cleavage with a Thorium Bis(α-diimine) Complex

European Journal of Inorganic Chemistry ◽

10.1002/ejic.201300390 ◽

2013 ◽

Vol 2013 (22-23) ◽

pp. 4050-4055 ◽

Cited By ~ 19

Author(s):

Agnes Mrutu ◽

Charles L. Barnes ◽

Suzanne C. Bart ◽

Justin R. Walensky

Keyword(s):

Bond Cleavage ◽

Metal Center ◽

Redox Reactivity

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Redox reactivity of transition-metal phthalocyanines: ligand radical formation vs. metal center oxidation

The Journal of Physical Chemistry ◽

10.1021/j100264a025 ◽

1985 ◽

Vol 89 (18) ◽

pp. 3890-3894 ◽

Cited By ~ 18

Author(s):

D. K. Geiger ◽

G. Ferraudi ◽

K. Madden ◽

J. Granifo ◽

D. P. Rillema

Keyword(s):

Transition Metal ◽

Metal Center ◽

Radical Formation ◽

Metal Phthalocyanines ◽

Redox Reactivity

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Photochemically Activated Phosphorus-Carbon Bond Cleavage in the Binuclear Ruthenium Complex [cyclic] Ru2(CO)6(bpcd). Redox Reactivity, Molecular Orbital Properties, and X-ray Diffraction Structures of [cyclic] Ru2(CO)6(bpcd) and [cyclic] Ru2(CO)6[.mu.-C:C(PPh2)C(O)CH2C(O)](.mu.2-PPh2)

Organometallics ◽

10.1021/om00010a029 ◽

1995 ◽

Vol 14 (10) ◽

pp. 4625-4634 ◽

Cited By ~ 40

Author(s):

Huafeng Shen ◽

Simon G. Bott ◽

Michael G. Richmond

Keyword(s):

Molecular Orbital ◽

Ruthenium Complex ◽

Bond Cleavage ◽

X Ray Diffraction ◽

Carbon Bond ◽

X Ray ◽

Redox Reactivity

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Bioinspired iron(II)-β-diketonate and iron(II)-α-hydroxy ketone complexes of a carbanionic N3C ligand: Oxidation of metal center vs C C bond cleavage of co-ligand with dioxygen

Inorganica Chimica Acta ◽

10.1016/j.ica.2019.119200 ◽

2020 ◽

Vol 501 ◽

pp. 119200 ◽

Cited By ~ 1

Author(s):

Sridhar Banerjee ◽

Tapan Kanti Paine

Keyword(s):

Bond Cleavage ◽

Metal Center ◽

Hydroxy Ketone

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A Facile N≡N Bond Cleavage by the Trinuclear Metal Center in Vanadium Carbide Cluster Anions V3C4–

Journal of the American Chemical Society ◽

10.1021/jacs.0c02021 ◽

2020 ◽

Vol 142 (24) ◽

pp. 10747-10754 ◽

Cited By ~ 6

Author(s):

Zi-Yu Li ◽

Yao Li ◽

Li-Hui Mou ◽

Jiao-Jiao Chen ◽

Qing-Yu Liu ◽

...

Keyword(s):

Vanadium Carbide ◽

Bond Cleavage ◽

Metal Center ◽

Cluster Anions ◽

Carbide Cluster

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Metal−Metal Cooperativity Effects in Promoting C−H Bond Cleavage of a Methyl Group by an Adjacent Metal Center

Journal of the American Chemical Society ◽

10.1021/ja983525o ◽

1999 ◽

Vol 121 (15) ◽

pp. 3666-3683 ◽

Cited By ~ 29

Author(s):

Jeffrey R. Torkelson ◽

Frederick H. Antwi-Nsiah ◽

Robert McDonald ◽

Martin Cowie ◽

Justin G. Pruis ◽

...

Keyword(s):

Bond Cleavage ◽

Metal Center ◽

Methyl Group ◽

Metal Metal ◽

Cooperativity Effects

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ChemInform Abstract: Transformation of a Terminal to a Bridging Carbonyl Ligand Accompanied by Ir-Ir Bond Cleavage: An Example of Transmission of Electronic Effects from One Metal Center to Another.

Chemischer Informationsdienst ◽

10.1002/chin.198648297 ◽

1986 ◽

Vol 17 (48) ◽

Author(s):

M. COWIE ◽

G. VASAPOLLO ◽

B. R. SUTHERLAND ◽

J. P. ENNETT

Keyword(s):

Bond Cleavage ◽

Metal Center ◽

Electronic Effects ◽

Carbonyl Ligand

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A carbon-carbon bond cleavage reaction of carbon suboxide at a metal center. Synthesis and structural characterization of WCl2(CO)(PMePh2)2{C,C':.eta.2-C(O)CPMePh2} [Erratum to document cited in CA109(9):73587a]

Journal of the American Chemical Society ◽

10.1021/ja00228a076 ◽

1988 ◽

Vol 110 (20) ◽

pp. 6926-6926 ◽

Cited By ~ 3

Author(s):

Adam K. List ◽

Gregory L. Hillhouse ◽

Arnold L. Rheingold

Keyword(s):

Structural Characterization ◽

Bond Cleavage ◽

Metal Center ◽

Cleavage Reaction ◽

Carbon Suboxide ◽

Carbon Bond ◽

Bond Cleavage Reaction ◽

Carbon Carbon Bond

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A carbon-carbon bond cleavage reaction of carbon suboxide at a metal center. Synthesis and structural characterization of WCl2(CO)(PMePh2)2{C,C':.eta.2-C(O)CPMePh2}

Journal of the American Chemical Society ◽

10.1021/ja00222a070 ◽

1988 ◽

Vol 110 (14) ◽

pp. 4855-4856 ◽

Cited By ~ 22

Author(s):

Adam K. List ◽

Gregory L. Hillhouse ◽

Arnold L. Rheingold

Keyword(s):

Structural Characterization ◽

Bond Cleavage ◽

Metal Center ◽

Cleavage Reaction ◽

Carbon Suboxide ◽

Carbon Bond ◽

Bond Cleavage Reaction ◽

Carbon Carbon Bond

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Transformation of a terminal to a bridging carbonyl ligand accompanied by iridium-iridium bond cleavage: an example of transmission of electronic effects from one metal center to another

Inorganic Chemistry ◽

10.1021/ic00235a032 ◽

1986 ◽

Vol 25 (15) ◽

pp. 2648-2653 ◽

Cited By ~ 18

Author(s):

Martin Cowie ◽

Giuseppe Vasapollo ◽

Bruce R. Sutherland ◽

Jimmie P. Ennett

Keyword(s):

Bond Cleavage ◽

Metal Center ◽

Electronic Effects ◽

Carbonyl Ligand

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ChemInform Abstract: A Carbon-Carbon Bond Cleavage Reaction of Carbon Suboxide at a Metal Center. Synthesis and Structural Characterization of WCl2(CO)(PMePh2)2(C,C′:η2-C(O)CPMePh2).

ChemInform ◽

10.1002/chin.198845267 ◽

1988 ◽

Vol 19 (45) ◽

Author(s):

A. K. LIST ◽

G. L. HILLHOUSE ◽

A. L. RHEINGOLD

Keyword(s):

Structural Characterization ◽

Bond Cleavage ◽

Metal Center ◽

Cleavage Reaction ◽

Carbon Suboxide ◽

Carbon Bond ◽

Bond Cleavage Reaction ◽

Carbon Carbon Bond

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