Donor-Acceptor Complexes of Normal and Abnormal N-Heterocyclic Carbenes with Group 13 (B, Al, Ga) Elements: A Combined DFT and Atoms-in-Molecules Study

2013 ◽  
Vol 2013 (18) ◽  
pp. 3233-3239 ◽  
Author(s):  
Satyajit Sarmah ◽  
Ankur Kanti Guha ◽  
Ashwini K. Phukan
Keyword(s):  
Heterocyclic Carbenes ◽  
Atoms In Molecules ◽  
Group 13 ◽  
Donor Acceptor

scholarly journals In-Depth Investigation of a Donor–Acceptor Interaction on the Heavy-Group-14@Group-13-Diyls in Transition-Metal Tetrylone Complexes: Structure, Bonding, and Property

ACS Omega ◽  
2020 ◽  
Vol 5 (33) ◽  
pp. 21271-21287
Author(s):  
Huynh Thi Phuong Loan ◽  
Thanh Q. Bui ◽  
Tran Thi Ai My ◽  
Nguyen Thi Thanh Hai ◽  
Duong Tuan Quang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Group 14 ◽  
Acceptor Interaction ◽  
Group 13 ◽  
Donor Acceptor ◽  
Heavy Group

Recent advances in synthesis of organometallic complexes of indium

2020 ◽  
Vol 40 (3) ◽  
pp. 107-151
Author(s):  
Hira Anwar ◽  
Rosenani A. Haque ◽  
Rahman Shah Zaib Saleem ◽  
Muhammad Adnan Iqbal
Keyword(s):  
Material Science ◽  
Thin Film Transistors ◽  
Heterocyclic Carbenes ◽  
Organometallic Complexes ◽  
Organic Ligands ◽  
Group 13 ◽  
Indium Complexes ◽  
Different Types ◽  
Stirring Time ◽  
Different Temperatures

AbstractThe indium complexes are being used in many applications like catalysis, optoelectronics, sensors, solar cells, biochemistry, medicine, infrared (IR) mirrors and thin-film transistors (TFTs). In organometallic complexes of indium, it forms different types of complexes with single, double, triple and tetra linkages by coordinating with numerous elements like C, N, O and S and also with some other elements like Se and Ru. So, the present study comprises all the possible ways to synthesize the indium complexes by reacting with different organic ligands; most of them are N-heterocyclic carbenes, amines, amides and phenols. The commonly used solvents for these syntheses are tetrahydrofuran, dichloromethane, toluene, benzene, dimethyl sulfoxide (DMSO) and water. According to the nature of the ligands, indium complexes were reported at different temperatures and stirring time. Because of their unique characteristics, the organometallic chemistry of group 13 metal indium complexes remains a subject of continuing interest in synthetic chemistry as well as material science.

scholarly journals Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements

ACS Omega ◽  
2021 ◽  
Author(s):  
Lakhya J. Mazumder ◽  
Amlan J. Kalita ◽  
Shahnaz S. Rohman ◽  
Chayanika Kashyap ◽  
Sabnam S. Ullah ◽  
...  
Keyword(s):  
Noble Gases ◽  
Group 13 ◽  
Donor Acceptor

Donor−Acceptor “Dressing” of “Naked” Group 13−15 Cubanes

2009 ◽  
Vol 48 (17) ◽  
pp. 8145-8153 ◽  
Author(s):  
Alexey Y. Timoshkin
Keyword(s):  
Group 13 ◽  
Donor Acceptor

Probing Donor–Acceptor Interactions in peri-Substituted Diphenylphosphinoacenaphthyl–Element Dichlorides of Group 13 and 15 Elements

2014 ◽  
Vol 33 (24) ◽  
pp. 7247-7259 ◽  
Author(s):  
Emanuel Hupf ◽  
Enno Lork ◽  
Stefan Mebs ◽  
Lilianna Chęcińska ◽  
Jens Beckmann
Keyword(s):  
Group 13 ◽  
Donor Acceptor
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