scholarly journals Vanadium Analogues of Nonfunctionalized and Amino-Functionalized MOFs with MIL-101 Topology - Synthesis, Characterization, and Gas Sorption Properties (Eur. J. Inorg. Chem. 15/2012)

2012 ◽  
Vol 2012 (15) ◽  
pp. n/a-n/a
Author(s):  
Shyam Biswas ◽  
Sarah Couck ◽  
Maciej Grzywa ◽  
Joeri F. M. Denayer ◽  
Dirk Volkmer ◽  
...  
Keyword(s):  
Sorption Properties ◽  
Gas Sorption

scholarly journals Chemical modification of the polymer of intrinsic microporosity PIM-1 for enhanced hydrogen storage

Adsorption ◽  
2020 ◽  
Vol 26 (7) ◽  
pp. 1083-1091
Author(s):  
Mi Tian ◽  
Sébastien Rochat ◽  
Hamish Fawcett ◽  
Andrew D. Burrows ◽  
Christopher R. Bowen ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Surface Area ◽  
Hydrogen Adsorption ◽  
Sorption Properties ◽  
Bet Surface Area ◽  
Polymer Modification ◽  
Gas Sorption ◽  
Chemically Modified ◽  
Polymer Of Intrinsic Microporosity ◽  
Intrinsic Microporosity

Abstract A detailed investigation has been carried out of the pre-polymerisation modification of the polymer of intrinsic microporosity PIM-1 by the addition of two methyl (Me) groups to its spirobisindane unit to create a new chemically modified PIM-1 analogue, termed MePIM. Our work explores the effects of this modification on the porosity of PIM-1 and hence on its gas sorption properties. MePIM was successfully synthesised using either low (338 K) or high (423 K) temperature syntheses. It was observed that introduction of methyl groups to the spirobisindane part of PIM-1 generates additional microporous spaces, which significantly increases both surface area and hydrogen storage capacity. The BET surface area (N2 at 77 K) was increased by ~ 12.5%, resulting in a ~ 25% increase of hydrogen adsorption after modification. MePIM also maintains the advantages of good processability and thermal stability. This work provides new insights on a facile polymer modification that enables enhanced gas sorption properties.

Syntheses, structures and gas sorption properties of two coordination polymers with a unique type of supramolecular isomerism

2015 ◽  
Vol 2 (2) ◽  
pp. 136-140 ◽  
Author(s):  
Xiao-Lin Qi ◽  
Jia-Wen Ye ◽  
Rui-Biao Lin ◽  
Pei-Qin Liao ◽  
Si-Yang Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Difference ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Unique Type ◽  
Supramolecular Isomerism ◽  
Porous Properties

Two genuine supramolecular isomers with a unique type of structural difference and completely different porous properties have been synthesized and characterized.

Gas-sorption properties of 6FDA-durene/1,4-phenylenediamine (pPDA) and 6FDA-durene/1,3-phenylenediamine (mPDA) copolyimides

2003 ◽  
Vol 90 (8) ◽  
pp. 2187-2193 ◽  
Author(s):  
Si-Xue Cheng ◽  
Tai-Shung Chung ◽  
Rong Wang ◽  
Rohit H. Vora
Keyword(s):  
Sorption Properties ◽  
Gas Sorption

A unique magnesium-based 3D MOF with nanoscale cages and temperature dependent selective gas sorption properties

2013 ◽  
Vol 49 (17) ◽  
pp. 1753 ◽  
Author(s):  
Yong-Liang Huang ◽  
Yun-Nan Gong ◽  
Long Jiang ◽  
Tong-Bu Lu
Keyword(s):  
Sorption Properties ◽  
Gas Sorption ◽  
Temperature Dependent

Two cationic metal–organic frameworks featuring different cage-to-cage connections: syntheses, crystal structures, photoluminescence and gas sorption properties

CrystEngComm ◽  
2013 ◽  
Vol 15 (40) ◽  
pp. 8139 ◽  
Author(s):  
Zhen-Zhen Xue ◽  
Tian-Lu Sheng ◽  
Qi-Long Zhu ◽  
Da-Qiang Yuan ◽  
Yan-Long Wang ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Metal Organic

An unexpected relationship between solvent inclusion and gas sorption properties of chiral calixsalen solids

2018 ◽  
Vol 30 (5-6) ◽  
pp. 479-487 ◽  
Author(s):  
Agnieszka Janiak ◽  
Marcin Kwit ◽  
Leonard J. Barbour
Keyword(s):  
Sorption Properties ◽  
Gas Sorption
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