3D Coordination Polymer of [HW7O24]5-Stabilized by a Copper(II) Complex and Sodium Cations: Structure, Solid-State Stability, and Aqueous Solution Behavior

2012 ◽  
Vol 2013 (10-11) ◽  
pp. 1788-1792 ◽  
Author(s):  
Xin-Fang Wang ◽  
Jie Cao ◽  
Kun-Lin Huang ◽  
Yan-Qing Xu ◽  
Ying-Nan Chi ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Solid State ◽  
Coordination Polymer ◽  
Solution Behavior ◽  
Sodium Cations ◽  
Solid State Stability

The NaCl Adduct of the Iron-Indium Compound Fe2(CO)6(μ-CO)(μ-InR)2 [R = C(SiMe3)3] – a One-Dimensional Coordination Polymer with Sodium Oxygen Bridges

2003 ◽  
Vol 58 (5) ◽  
pp. 385-388 ◽  
Author(s):  
Werner Uhl ◽  
Fritjof Schmock ◽  
Wolfgang Petz
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Chlorine Atom ◽  
Coordination Compound ◽  
Coordination Sphere ◽  
One Dimensional ◽  
Sodium Cations ◽  
Oxygen Atoms

The organoindium subhalide [R(Cl)In-In(Cl)R]2 [R = C(SiMe3)3] 1 reacts with Na2[Fe2(CO)8] to form an iron-indium coordination compound which was isolated as the sodium choride adduct [Na(THF)4][Fe2(CO)6(μ-CO)(μ-InR)2Cl] 2. The iron atoms of 2 are bridged by a CO ligand and two InR groups, the indium atoms of which are further connected by the μ2-bridging chlorine atom. Four THF molecules and two oxygen atoms of terminal CO ligands of different anions span the coordination sphere of the sodium cations to give a one-dimensional coordination polymer in the solid state.

A novel multichromic Zn (Ⅱ) cationic coordination polymer based on a new flexible viologen ligand exhibiting aniline detection in solid state

2021 ◽  
Author(s):  
Jiayun Zou ◽  
jie Ji ◽  
Meihong Fan ◽  
Jiayu Li ◽  
Haiyu Wang ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Pyromellitic Acid

In this paper, a novel multichromic catioic coordination polymer, named [Zn4 (BTC)3(bcbpy)2] ·5H2O (1) based on a new flexible viologen ligand 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine-1,1'-diium (H2bcbpy·2Cl), Zn(NO3)2·6H2O and pyromellitic acid (H4BTC), was synthesized....

Separation of phenylenediamine isomers by using decamethylcucurbit[5]uril

2021 ◽  
Author(s):  
Long Cao ◽  
Han-Ling Guo ◽  
Rui Lian Lin ◽  
Li-Fei Tian ◽  
Zhi-Hua Zhang ◽  
...  
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Solid State ◽  
Phenylenediamine Isomers

Using multiple techniques, this work studied the binding behaviors of decamethylcucurbit[5]uril (Me10Q[5]) with o-, m- and p-phenylenediamine (PDA) isomers both in solid state and in aqueous solution. Experimental data indicate...

scholarly journals Proton-conductive coordination polymer glass for solid-state anhydrous proton batteries

2021 ◽  
Vol 12 (16) ◽  
pp. 5818-5824
Author(s):  
Nattapol Ma ◽  
Soracha Kosasang ◽  
Atsushi Yoshida ◽  
Satoshi Horike
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
Coordination Polymer ◽  
Proton Battery ◽  
Polymer Glass

Melt-quenched coordination polymer glass shows exclusive H+ conductivity (8.0 × 10−3 S cm−1 at 120 °C, anhydrous) and optimal mechanical properties (42.8 Pa s at 120 °C), enables the operation of an all-solid-state proton battery from RT to 110 °C.

Effect of grinding on the solid-state stability of cefixime trihydrate

1989 ◽  
Vol 56 (2) ◽  
pp. 125-134 ◽  
Author(s):  
Kitamura Satoshi ◽  
Miyamae Akira ◽  
Koda Shigetaka ◽  
Morimoto Yukiyoshi
Keyword(s):  
Solid State ◽  
Solid State Stability

A paramagnetic Cu(i)/Cu(ii)/Zn(ii) coordination polymer with multiple CN-binding modes and its solid-state NMR characterization

2006 ◽  
pp. 744 ◽  
Author(s):  
Liang Ouyang ◽  
Pedro M. Aguiar ◽  
Raymond J. Batchelor ◽  
Scott Kroeker ◽  
Daniel B. Leznoff
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Solid State Nmr ◽  
Binding Modes ◽  
Nmr Characterization

scholarly journals Electrochemiluminescence Study of Europium (III) Complex with Coumarin3-Carboxylic Acid

2008 ◽  
Vol 2008 ◽  
pp. 1-6 ◽  
Author(s):  
Stefan Lis ◽  
Krzysztof Staninski ◽  
Tomasz Grzyb
Keyword(s):  
Aqueous Solution ◽  
Spectral Analysis ◽  
Energy Transfer ◽  
Solid State ◽  
Carboxylic Acid ◽  
Elemental Analysis ◽  
Aluminium Electrode ◽  
The Eu

The europium (III) complex of coumarin-3-carboxylic acid (C3CA) has been prepared and characterized on the basis of elemental analysis, IR, and emission (photoluminescence and electrochemiluminescence) spectroscopy. The synthesised complex having a formula Eu was photophysically characterized in solution and in the solid state. Electrochemiluminescence, ECL, of the system containing the Eu(III)/C3CA complex was studied using an oxide-covered aluminium electrode. The goal of these studies was to show the possibility of the use of electrochemical excitation of the Eu(III) ion in aqueous solution for emission generation. The generated ECL emission was very weak, and therefore its measurements and spectral analysis were carried out with the use of cut-off filters method. The studies proved a predominate role of the ligand-to-metal energy transfer (LMET) in the generated ECL.

scholarly journals Effects of grinding and drying on the solid-state stability of ampicillin trihydrate.

1984 ◽  
Vol 32 (12) ◽  
pp. 4963-4970 ◽  
Author(s):  
YOSHITERU TAKAHASHI ◽  
KAZUKO NAKASHIMA ◽  
HIROSHI NAKAGAWA ◽  
ISAO SUGIMOTO
Keyword(s):  
Solid State ◽  
Solid State Stability ◽  
Ampicillin Trihydrate
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