Barium Carboxylate Metal-Organic Framework - Synthesis, X-ray Crystal Structure, Photoluminescence and Catalytic Study

2012 ◽  
Vol 2012 (30) ◽  
pp. 4914-4920 ◽  
Author(s):  
Tanmoy Maity ◽  
Debraj Saha ◽  
Soma Das ◽  
Subratanath Koner
Keyword(s):  
Crystal Structure ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Single crystal structure and photocatalytic behavior of grafted uranyl on the Zr-node of a pyrene-based metal–organic framework

CrystEngComm ◽  
2020 ◽  
Vol 22 (11) ◽  
pp. 2097-2102 ◽  
Author(s):  
Julia G. Knapp ◽  
Xuan Zhang ◽  
Tatyana Elkin ◽  
Laura E. Wolfsberg ◽  
Sylvia L. Hanna ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Uranyl Ion ◽  
Single Crystal Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Photo Oxidation ◽  
Metal Organic ◽  
Organic Framework

The zirconium MOF NU-1000 was post-synthetically modified through solvothermal deposition to include the uranyl ion and characterized via single-crystal X-ray diffraction; photo-oxidation was also performed.

Design, Synthesis, and X-Ray Crystal Structure of a Fullerene-Linked Metal-Organic Framework

2013 ◽  
Vol 126 (1) ◽  
pp. 164-167 ◽  
Author(s):  
Ping Peng ◽  
Fang-Fang Li ◽  
Venkata S. Pavan K. Neti ◽  
Alejandro J. Metta-Magana ◽  
Luis Echegoyen
Keyword(s):  
Crystal Structure ◽  
Metal Organic Framework ◽  
Design Synthesis ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

Synthesis, X-ray crystal structure and spin polarized DFT study of high spin Mn based metal-organic framework

2019 ◽  
Vol 1175 ◽  
pp. 439-444 ◽  
Author(s):  
Saghir Abbas ◽  
Khurshid Ayub ◽  
Manzar Sohail ◽  
Saqib Ali ◽  
Ralf Ludwig ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Spin ◽  
Metal Organic Framework ◽  
Dft Study ◽  
X Ray ◽  
Spin Polarized ◽  
Metal Organic ◽  
Organic Framework

Synthesis, Ab Initio X-ray Powder Diffraction Crystal Structure, and Magnetic Properties of Mn3(OH)2(C6H2O4S)2 Metal–Organic Framework

2012 ◽  
Vol 52 (2) ◽  
pp. 608-616 ◽  
Author(s):  
Romain Sibille ◽  
Thomas Mazet ◽  
Erik Elkaïm ◽  
Bernard Malaman ◽  
Michel François
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Ab Initio ◽  
Powder Diffraction ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

Design, Synthesis, and X-Ray Crystal Structure of a Fullerene-Linked Metal-Organic Framework

2013 ◽  
Vol 53 (1) ◽  
pp. 160-163 ◽  
Author(s):  
Ping Peng ◽  
Fang-Fang Li ◽  
Venkata S. Pavan K. Neti ◽  
Alejandro J. Metta-Magana ◽  
Luis Echegoyen
Keyword(s):  
Crystal Structure ◽  
Metal Organic Framework ◽  
Design Synthesis ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

Synthesis and Structure of a Clathrated Two-Dimensional Metal-Organic Framework: [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2·H2O (L = Bis(1-pyrazinylethylidene)hydrazine)

2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang
Keyword(s):  
Metal Organic Framework ◽  
Channel Structure ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
X Ray ◽  
Square Planar ◽  
Metal Organic ◽  
Aqueous Meoh ◽  
Organic Framework

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.

Synthesis, crystal structure, luminescence, and photocatalytic properties of a 2D Cu(II) metal-organic frameworks based on 3,5-di(1H-benzimidazol-1-yl)pyridine and 4,4′-oxybis(benzoate) ligands

2020 ◽  
Vol 75 (8) ◽  
pp. 727-732
Author(s):  
Chen Zhang ◽  
Jian-Qing Tao
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Uv Light ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
X Ray Diffraction ◽  
X Ray ◽  
Uv Light Irradiation ◽  
Photocatalytic Activities ◽  
Metal Organic

AbstractA new Cu(II) metal-organic framework, [Cu(L)(OBA)·H2O]n (1) [H2OBA = 4,4′-oxybis(benzoic acid), L = 3,5-di(1H-benzimidazol-1-yl)pyridine] was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis and single-crystal X-ray diffraction. Complex 1 is a four-connected uni-nodal 2D net with a (44·62) topology which shows an emission centered at λ ∼393 nm upon excitation at λ = 245 nm. Moreover, complex 1 possesses high photocatalytic activities for the decomposition of Rhodamine B (RhB) under UV light irradiation.

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

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