Influence of Hydrogen Bonding on the Hysteresis Width in Iron(II) Spin-Crossover Complexes

2011 ◽  
Vol 2011 (21) ◽  
pp. 3193-3206 ◽  
Author(s):  
Birgit Weber ◽  
Wolfgang Bauer ◽  
Toni Pfaffeneder ◽  
Marinela M. Dîrtu ◽  
Anil D. Naik ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Spin Crossover ◽  
Hysteresis Width ◽  
Spin Crossover Complexes

Colorimetric barbiturate sensing with hybrid spin crossover assemblies

2014 ◽  
Vol 50 (39) ◽  
pp. 5043-5045 ◽  
Author(s):  
Michael C. Young ◽  
Erica Liew ◽  
Richard J. Hooley
Keyword(s):  
Hydrogen Bonding ◽  
Spin Crossover ◽  
Biologically Relevant ◽  
Spin Crossover Complexes ◽  
Iron Based

Iron-based spin crossover complexes can be used as selective, visible sensors for barbiturates in the presence of other biologically relevant hydrogen bonding species.

The molecular and supramolecular aspects in mononuclear manganese(iii) Schiff-base spin crossover complexes

2017 ◽  
Vol 46 (33) ◽  
pp. 11063-11077 ◽  
Author(s):  
Shi Wang ◽  
Ya-Juan Li ◽  
Fei-Fei Ju ◽  
Wu-Tan Xu ◽  
Koichi Kagesawa ◽  
...  
Keyword(s):  
Schiff Base ◽  
Spin Crossover ◽  
Hysteresis Width ◽  
Spin Crossover Complexes

A cooperative SCO process with a hysteresis width of 18 K is the largest one reported in d4 SCO chemistry.

Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly

2013 ◽  
Vol 49 (56) ◽  
pp. 6331 ◽  
Author(s):  
Michael C. Young ◽  
Erica Liew ◽  
Jonathan Ashby ◽  
Kelsi E. McCoy ◽  
Richard J. Hooley
Keyword(s):  
Hydrogen Bonding ◽  
Spin State ◽  
Self Assembly ◽  
Spin Crossover ◽  
Spin Crossover Complexes

Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis

2021 ◽  
Author(s):  
Cyril Rajnák ◽  
Romana Mičová ◽  
Ján Moncoľ ◽  
Ľubor Dlháň ◽  
Christoph Krüger ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Mononuclear Complex ◽  
Hysteresis Width ◽  
Thermally Induced

A pentadentate Schiff-base ligand 3,5Cl-L2− and NCSe− form a iron(iii) mononuclear complex [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).

A New Family of Anionic FeIII Spin Crossover Complexes Featuring a Weak-Field N2 O4 Coordination Octahedron

2015 ◽  
Vol 22 (4) ◽  
pp. 1253-1257 ◽  
Author(s):  
Kazuyuki Takahashi ◽  
Kiko Kawamukai ◽  
Mitsunobu Okai ◽  
Tomoyuki Mochida ◽  
Takahiro Sakurai ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Weak Field ◽  
New Family ◽  
Spin Crossover Complexes

Relevance of supramolecular interactions, texture and lattice occupancy in the designer iron(II) spin crossover complexes

2009 ◽  
Vol 182 (6) ◽  
pp. 1365-1376 ◽  
Author(s):  
Anil D. Naik ◽  
Bernard Tinant ◽  
Kai Muffler ◽  
Juliusz A. Wolny ◽  
Volker Schünemann ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Supramolecular Interactions ◽  
Spin Crossover Complexes

Asymmetric Design of Spin-Crossover Complexes to Increase the Volatility for Surface Deposition

2021 ◽  
Author(s):  
Miguel Gakiya-Teruya ◽  
Xuanyuan Jiang ◽  
Duy Le ◽  
Ökten Üngör ◽  
Abdullah J. Durrani ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Surface Deposition ◽  
Spin Crossover Complexes

Targeted structural modification of spin crossover complexes: pyridine vs pyrazine

2017 ◽  
Vol 30 (4) ◽  
pp. 296-304 ◽  
Author(s):  
Humphrey L. C. Feltham ◽  
Matthew G. Cowan ◽  
Jonathan A. Kitchen ◽  
Guy N. L. Jameson ◽  
Sally Brooker
Keyword(s):  
Structural Modification ◽  
Spin Crossover ◽  
Spin Crossover Complexes
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