Solvothermal Synthesis and Structural Characterisation of Metal-Organic Frameworks with Paddle-Wheel Zinc Carboxylate Clusters and Mixed Ligands

2011 ◽  
Vol 2011 (17) ◽  
pp. 2712-2719 ◽  
Author(s):  
Jia Li ◽  
Yu Peng ◽  
Hongwei Liang ◽  
Yang Yu ◽  
Bingjing Xin ◽  
...  
Keyword(s):  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Paddle Wheel ◽  
Structural Characterisation ◽  
Mixed Ligands ◽  
Metal Organic

Lanthanide metal–organic frameworks based on the 4,4′-oxybisbenzoic acid ligand: synthesis, structures and physical properties

2015 ◽  
Vol 39 (12) ◽  
pp. 9872-9878 ◽  
Author(s):  
Yun Li ◽  
Ning Wang ◽  
Yan-Ju Xiong ◽  
Qian Cheng ◽  
Jie-Fang Fang ◽  
...  
Keyword(s):  
Physical Properties ◽  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Lanthanide Ions ◽  
Acid Ligand ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Ligand Synthesis

Using solvothermal synthesis, eight new 3D microporous lanthanide-ions-based MOFs constructed from 4,4′-oxybisbenzoic acid were obtained and displayed two types of architecture.

scholarly journals Two-dimensional metal-organic frameworks containing linear dicarboxylates

2006 ◽  
Vol 62 (5) ◽  
pp. 808-814 ◽  
Author(s):  
Samuel M. Hawxwell ◽  
Harry Adams ◽  
Lee Brammer
Keyword(s):  
Dicarboxylic Acid ◽  
Solvothermal Synthesis ◽  
Interplanar Spacing ◽  
Metal Organic Frameworks ◽  
Dicarboxylic Acids ◽  
Two Dimensional ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Gas Molecules ◽  
Solvent Molecules

The solvothermal synthesis of four two-dimensional metal-organic frameworks containing linear dicarboxylic acids as ligands for ZnII centres is described. Zn(BDC)(DMF) [(1) where BDC = benzene-1,4-dicarboxylic acid; DMF = N,N-dimethylformamide] adopts a common paddlewheel motif leading to a 44 grid network, whereas Zn3(BDC)3(EtOH)2 (2), Zn3(BDC)3(H2O)2·4DMF (3) and Zn3(BPDC)3(DMF)2·4DMF (4) each form networks with the relatively uncommon 36 topology based upon Zn3(O2CR)6 secondary building units. All contain coordinated solvent molecules, namely DMF [(1) and (4)], ethanol (2) or H2O (3). Comparison of structures (2) and (3) illustrates a clay-like flexibility in interplanar spacing which sheds light on the ability of the Zn3(BDC)3 framework to undergo desolvation and uptake of small solvent and gas molecules.

scholarly journals Stability and Hydrolyzation of Metal Organic Frameworks with Paddle-Wheel SBUs upon Hydration

2012 ◽  
Vol 24 (16) ◽  
pp. 3153-3167 ◽  
Author(s):  
Kui Tan ◽  
Nour Nijem ◽  
Pieremanuele Canepa ◽  
Qihan Gong ◽  
Jing Li ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Paddle Wheel ◽  
Metal Organic

Resin-assisted solvothermal synthesis of transition metal–organic frameworks

2010 ◽  
Vol 39 (14) ◽  
pp. 3384 ◽  
Author(s):  
Yi Du ◽  
Amber L. Thompson ◽  
Nicola Russell ◽  
Dermot O'Hare
Keyword(s):  
Transition Metal ◽  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Metal Organic

Construction of Zn(ii) and Cd(ii) metal–organic frameworks of diimidazole and dicarboxylate mixed ligands for the catalytic photodegradation of rhodamine B in water

CrystEngComm ◽  
2015 ◽  
Vol 17 (9) ◽  
pp. 1935-1943 ◽  
Author(s):  
Chun-Ning Lü ◽  
Min-Min Chen ◽  
Wen-Hua Zhang ◽  
Duan-Xiu Li ◽  
Ming Dai ◽  
...  
Keyword(s):  
Rhodamine B ◽  
Metal Organic Frameworks ◽  
Mixed Ligands ◽  
Metal Organic

Violet Luminescence from Zinc-Based Metal-Organic Frameworks Prepared by Solvothermal Synthesis

2019 ◽  
Vol 92 (2) ◽  
pp. 427-434
Author(s):  
Tomoe Sanada ◽  
Satoshi Tominaka ◽  
Kazuo Kojima ◽  
Anthony K. Cheetham
Keyword(s):  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Violet Luminescence ◽  
Metal Organic
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