Guanidino-Functionalised Aromatic Electron Donors at Work: Competing Hydrogen- and Electron-Transfer Reactions in the Course of the Synthesis of Gold Acetylide Complexes

2011 ◽  
Vol 2011 (19) ◽  
pp. 2975-2983 ◽  
Author(s):  
Dimitri Emeljanenko ◽  
Elisabeth Kaifer ◽  
Hans-Jörg Himmel
2015 ◽  
Vol 17 (46) ◽  
pp. 30854-30866 ◽  
Author(s):  
P. Antoniou ◽  
Z. Ma ◽  
P. Zhang ◽  
D. N. Beratan ◽  
S. S. Skourtis

Electron donors are connectedvialeft and right bridges to electron acceptors. Following electron-transfer initiation, the IR excitation of selected bridge vibrational modes can tune the directionality of electron transfer.


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