Versatile Coordination Modes of 2-(Diformylmethylene)-3,3-dimethylindole towards Late-Transition-Metal Ions: C-H Bond Activation and Formation of Cyclic Acyl-Palladium(II) Complexes

2011 ◽  
Vol 2011 (15) ◽  
pp. 2394-2404 ◽  
Author(s):  
Hamid Khaledi ◽  
Hapipah Mohd Ali ◽  
Marilyn M. Olmstead
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Bond Activation ◽  
Transition Metal Ions ◽  
Late Transition Metal ◽  
Coordination Modes ◽  
Late Transition

Alkane activation on crystalline metal oxide surfaces

2014 ◽  
Vol 43 (22) ◽  
pp. 7536-7547 ◽  
Author(s):  
Jason F. Weaver ◽  
Can Hakanoglu ◽  
Abbin Antony ◽  
Aravind Asthagiri
Keyword(s):  
Transition Metal ◽  
Metal Oxide ◽  
Bond Activation ◽  
Oxide Surfaces ◽  
Late Transition Metal ◽  
Alkane Activation ◽  
Metal Oxide Surfaces ◽  
Metal Atoms ◽  
Late Transition ◽  
Crystalline Metal

Late transition-metal oxide surfaces that expose coordinatively-unsaturated metal atoms promote the formation and bond activation of alkane σ-complexes.

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