Flexible and Redox-Active Coordination Polymer: Control of the Network Structure by Pendant Arms of a Macrocyclic Complex

2010 ◽  
Vol 2010 (24) ◽  
pp. 3795-3803 ◽  
Author(s):  
Hoi Ri Moon ◽  
Myunghyun Paik Suh
Keyword(s):  
Coordination Polymer ◽  
Network Structure ◽  
Macrocyclic Complex ◽  
Redox Active ◽  
Pendant Arms

New 3-D Mn(II) coordination polymer with redox active oxalate linker; an efficient and robust electrocatalyst for oxygen evolution reaction

2021 ◽  
Vol 514 ◽  
pp. 119982
Author(s):  
Abdul Mannan Butt ◽  
Saghir Abbas ◽  
Tayyaba Noor ◽  
Muhammad Nawaz Tahir ◽  
Ehsan Ullah Mughal ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Redox Active

Poly[deca-μ2-cyanido-dicyanidobis(μ2-ethylenediamine)bis(ethylenediamine)tricadmium(II)dicobalt(III)]: a two-dimensional coordination polymer

2009 ◽  
Vol 65 (3) ◽  
pp. m118-m120
Author(s):  
Olha Sereda ◽  
Helen Stoeckli-Evans
Keyword(s):  
Coordination Polymer ◽  
Network Structure ◽  
General Position ◽  
Rotation Axis ◽  
Three Dimensional ◽  
The Other ◽  
Dimensional Structure ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Dimensional Network

The title coordination polymer, [Cd3Co2(CN)12(C2H8N2)4]n, has an infinite two-dimensional network structure. The asymmetric unit is composed of two crystallographically independent CdIIatoms, one of which is located on a twofold rotation axis. There are two independent ethylenediamine (en) ligands, one of which bis-chelates to the Cd atom that sits in a general position, while the other bridges this Cd atom to that sitting on the twofold axis. The Cd atom located on the twofold rotation axis is linked to four equivalent CoIIIatomsviacyanide bridges, while the Cd atom that sits in a general position is connected to three equivalent CoIIIatomsviacyanide bridges. In this way, a series of trinuclear, tetranuclear and pentanuclear macrocycles are linked to form a two-dimensional network structure lying parallel to thebcplane. In the crystal structure, these two-dimensional networks are linkedviaN—H...N hydrogen bonds involving an en NH2H atom and a cyanide N atom, leading to the formation of a three-dimensional structure. This coordination polymer is only the second example involving a cyanometallate where the en ligand is present in both chelating and bridging coordination modes.

Redox-active porous coordination polymer based on trinuclear pivalate: Temperature-dependent crystal rearrangement and redox-behavior

2015 ◽  
Vol 223 ◽  
pp. 122-130 ◽  
Author(s):  
Anton S. Lytvynenko ◽  
Mikhail A. Kiskin ◽  
Victoria N. Dorofeeva ◽  
Andrey M. Mishura ◽  
Vladimir E. Titov ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Redox Behavior ◽  
Temperature Dependent ◽  
Redox Active ◽  
Porous Coordination Polymer

1D Coordination Polymer Derived from Redox‐Active Digallane

2021 ◽  
Vol 2021 (7) ◽  
pp. 675-680
Author(s):  
Tatyana S. Koptseva ◽  
Natalia L. Bazyakina ◽  
Mikhail V. Moskalev ◽  
Evgeny V. Baranov ◽  
Igor L. Fedushkin
Keyword(s):  
Coordination Polymer ◽  
1D Coordination Polymer ◽  
Redox Active

A Three-Component 1D/2D → 2D Interpenetrated Coordination Network: Structure and Gas Adsorption Studies

2014 ◽  
Vol 67 (10) ◽  
pp. 1391 ◽  
Author(s):  
Jin-Xiang Chen ◽  
Ni-Ni Ding ◽  
Ming Chen ◽  
Wen-Hua Chen ◽  
David J. Young ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Network Structure ◽  
Gas Adsorption ◽  
Two Dimensional ◽  
One Dimensional ◽  
Adsorption Studies ◽  
Coordination Network

We herein report a Cd-based coordination polymer containing three integrated polymeric components: two neutral and entangled two-dimensional (6,3) nets and one zwitterionic one-dimensional polymer with corner-sharing double-stranded chains propagating along the c-direction to lock the consecutive ligand struts of the (6,3) nets. Despite a sophisticated entanglement, this coordination polymer is porous to selectively adsorb CO2.

Electronic, Optical, and Computational Studies of a Redox-Active Napthalenediimide-Based Coordination Polymer

2013 ◽  
Vol 52 (24) ◽  
pp. 14246-14252 ◽  
Author(s):  
Chanel F. Leong ◽  
Bun Chan ◽  
Thomas B. Faust ◽  
Peter Turner ◽  
Deanna M. D’Alessandro
Keyword(s):  
Coordination Polymer ◽  
Computational Studies ◽  
Redox Active

Coordination Networks with Carborane Anions: Ag(I) and Nitrogen Bridging Ligands

2006 ◽  
Vol 59 (1) ◽  
pp. 40 ◽  
Author(s):  
Luís Cunha-Silva ◽  
Ruksanna Ahmad ◽  
Michaele J. Hardie
Keyword(s):  
Infrared Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Network Structure ◽  
X Ray Diffraction ◽  
Coordination Networks ◽  
Bridging Ligands ◽  
X Ray ◽  
1D Coordination Polymer ◽  
Carborane Anions

New crystalline coordination networks based on Ag(i) and N-bridging ligands — pyrazine (pyz), 4,4′-bipyridine (bpy), and 2,3-bis-(2-pyridyl)pyrazine (bppz) — incorporating carborane monoanions (CB11H12)− or [Co(C2B9H11)2]− were isolated and characterized using single crystal X-ray diffraction, microanalysis, and infrared spectroscopy. All the complexes with the bpy and bppz ligands reveal 1D coordination infinite chains involving the Ag(i) and the ligands, and layered extended structures with rows of carborane anions between the layers of chains. Interestingly, two polymorphs of the complex [Ag(bpy)(CH3CN)][Co(C2B9H11)2] were observed. The complex [Ag(pyz)(CH3CN)2][Co(C2B9H11)2] shows a 1D coordination polymer, while the pyz complex with the smaller carborane anion {[Ag(pyz)](CB11H12)} exhibits a 3D coordination network structure with four Ag···H−B interactions between the silver centre and carborane anions.

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