The Interplay between Yttrium and Barium or Copper Trifluoroacetates andN-Methyldiethanolamine: Synthesis of a Heterometallic Y3Cu Trifluoroacetate Complex and a Homometallic Ba-TFA 1D Polymer

2007 ◽  
Vol 2007 (4) ◽  
pp. 602-608 ◽  
Author(s):  
Shashank Mishra ◽  
Jianyong Zhang ◽  
Liliane G. Hubert-Pfalzgraf ◽  
Dominique Luneau ◽  
Erwann Jeanneau
Keyword(s):  
Trifluoroacetate Complex

Synthesis of a New Tetranuclear Cobalt(III) Trifluoroacetate Complex [Co4(μ3-O)4(μ-O2CCF3)2(C5H5N)8](ClO4)2

2004 ◽  
Vol 74 (4) ◽  
pp. 632 ◽  
Author(s):  
A. N. Belyaev ◽  
A. I. Fisher ◽  
M. Yu. Gorlov ◽  
S. A. Simanova
Keyword(s):  
Trifluoroacetate Complex

scholarly journals One-step access to N-enoxyimides by gold-catalysed addition of N-hydroxyimides to terminal alkynes

2019 ◽  
Vol 6 (2) ◽  
pp. 209-212 ◽  
Author(s):  
Coralie Duchemin ◽  
Nicolai Cramer
Keyword(s):  
Terminal Alkynes ◽  
One Step ◽  
Trifluoroacetate Complex

A gold(i)trifluoroacetate complex promotes direct additions of N-hydroxyimides to a wide variety of terminal alkynes yielding synthetically valuable N-enoxyimides.

scholarly journals Synthesis and crystalline structure of palladium(II) mononuclear trifluoroacetate complex

2011 ◽  
Vol 81 (2) ◽  
pp. 427-427
Author(s):  
A. V. Eremin ◽  
D. D. Vaulina ◽  
M. A. Stepanova ◽  
A. N. Belyaev
Keyword(s):  
Crystalline Structure ◽  
Trifluoroacetate Complex

Synthesis, crystal structure and photophysical properties of a neodymium trifluoroacetate complex with 2,2'-bipyridine

2011 ◽  
Vol 29 (3) ◽  
pp. 193-197 ◽  
Author(s):  
Jiangbo SHE ◽  
Dongdong LI ◽  
Chaoqi HOU ◽  
Wenzheng YANG ◽  
Wei WEI ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Photophysical Properties ◽  
Trifluoroacetate Complex

Aqueous trifluoroacetic acid as a medium for organic reactions. I. Acidity functions and the identity of the manganese(VII) species found in powerfully acidic media

1976 ◽  
Vol 54 (3) ◽  
pp. 440-447 ◽  
Author(s):  
Udo A. Spitzer ◽  
Trevor W. Toone ◽  
Ross Stewart
Keyword(s):  
Trifluoroacetic Acid ◽  
Water System ◽  
Visible Spectrum ◽  
Pair Formation ◽  
Acidity Function ◽  
Acidic Media ◽  
Uv Visible ◽  
Acidity Functions ◽  
Trifluoroacetate Complex

The HR acidity function has been determined for the trifluoroacetic acid–water system, and extended beyond 100% acid by the addition of trifluoroacetic anhydride, to 99.5 wt.% anhydride. The existing H0 acidity function is corrected and extended to 100% trifluoroacetic acid, confirming Eaborn's observation that H0 attains a minimum value at approximately 97% acid. Comparison of the acidity functions shows that although trifluoroacetic acid is only weakly protonating, it is a strongly protonating-dehydrating medium. Changes in the uv–visible spectrum of potassium permanganate produced by changing acid concentration are used to calculate the degree of further ionization of the permanganate ion; the correlation of this with the HR acidity function further suggests the presence of the permanganyl cation, MnO3+, or its trifluoroacetate complex or ester, MnO3•O2CCF3, in these solutions. A cryoscopic investigation into the mode of ionization of permanganate in trifluoroacetic acid reveals that extensive ion-pair formation occurs in this solvent. Although this effect prevents an unequivocal determination of the number of solute particles being made the results are consistent with the presence of a permanganyl species in solution.

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