Facile Production of 2,5‐Furandicarboxylic Acid (FDCA) via Oxidation of Industrially Sourced Crude 5‐Hydroxymethylfurfural (HMF)

ChemSusChem ◽  
2021 ◽  
Author(s):  
Bala Subramaniam ◽  
Xiaobin Zuo ◽  
Padmesh Venkitasubramanian ◽  
Kevin J. Martin
Keyword(s):  
Furandicarboxylic Acid

Status of Biocatalysis in the Production of 2,5-Furandicarboxylic Acid

ACS Catalysis ◽  
2020 ◽  
Vol 10 (16) ◽  
pp. 9145-9169
Author(s):  
Derek Troiano ◽  
Valérie Orsat ◽  
Marie-Josée Dumont
Keyword(s):  
Furandicarboxylic Acid

Catalytic Synthesis of 2,5‐Furandicarboxylic Acid from Concentrated 2,5‐Diformylfuran Mediated by N ‐hydroxyimides under Mild Conditions

2019 ◽  
Vol 14 (19) ◽  
pp. 3329-3334 ◽  
Author(s):  
Fei Xia ◽  
Jiping Ma ◽  
Xiuquan Jia ◽  
Meiling Guo ◽  
Xuebin Liu ◽  
...  
Keyword(s):  
Catalytic Synthesis ◽  
Mild Conditions ◽  
Furandicarboxylic Acid

scholarly journals Heterogeneous Catalytic Conversion of Sugars Into 2,5-Furandicarboxylic Acid

2020 ◽  
Vol 8 ◽  
Author(s):  
Athukoralalage Don K. Deshan ◽  
Luqman Atanda ◽  
Lalehvash Moghaddam ◽  
Darryn W. Rackemann ◽  
Jorge Beltramini ◽  
...  
Keyword(s):  
Catalytic Conversion ◽  
Heterogeneous Catalytic ◽  
Furandicarboxylic Acid

Binding of calcium, lead, and copper(II) cations to galactaric and 2,5-furandicarboxylic acids and to D-galacturonic acid and its derivatives

1986 ◽  
Vol 51 (5) ◽  
pp. 1150-1159 ◽  
Author(s):  
Rudolf Kohn ◽  
Ján Hirsch
Keyword(s):  
Galacturonic Acid ◽  
Uronic Acid ◽  
Indicator Method ◽  
Cu Complex ◽  
Carboxylate Groups ◽  
Counter Ions ◽  
Galactaric Acid ◽  
Furandicarboxylic Acid ◽  
The Difference ◽  
Calcium Lead

The binding of Ca2+, Pb2+, and Cu2+ ions to galactaric and 2,5-furandicarboxylic acids and of Pb2+ and Cu2+ ions to D-galacturonic acid, its α-methylglycoside, and (methyl-4-deoxy-α-D-galactopyranosid)uronic acid was evaluated in terms of the activity coefficients of the counter-ions and the degrees of their association with the carboxylate groups of the acids. The activity of Ca2+ ions was determined by the metallochromic indicator method with tetramethylmurexide, that of Pb2+ and Cu2+ ions, with ion specific electrodes. Galactaric acid bids 89.5% Ca2+ ions, practically all (99.9%) Pb2+ ions and nearly all (98.6% Cu2+ ions, mostly with the formation of insoluble salts. As little as 7.6% Ca2+, 34.0% Pb2+, and 23.9% Cu2+ were bound to 2,5-furandicarboxylic acid in the form of soluble complexes, and slightly more, 4.1% Ca2+, 43.9% Pb2+, and 38.0% Cu2+, to D-galacturonic acid. The difference in the degrees of binding to galactaric acid and 2,5-furandicarboxylic acid is due to the different flexibility of their molecular skeletons. The activities of Pb2+ and Cu2+ ions in solutions of salts of D-galacturonic acid and its derivatives indicate that the OH group at C(4) of D-galacturonic acid takes part in the complexation. For the Pb2+ complex, the OH group at C(1) of the unsubstituted acid in the β-anomeric form also seems to participate in the complexation; this is not the case with the similar Cu complex.

scholarly journals High Performance Polyesters Prepared from Bio‐Based 2,5‐Furandicarboxylic Acid

2016 ◽  
Vol 72 (2) ◽  
pp. 54-60 ◽  
Author(s):  
Yusuke Kanetaka ◽  
Shinichi Yamazaki ◽  
Kunio Kimura
Keyword(s):  
High Performance ◽  
Furandicarboxylic Acid

Chemosynthesis and characterization of fully biomass-based copolymers of ethylene glycol, 2,5-furandicarboxylic acid, and succinic acid

2013 ◽  
Vol 130 (2) ◽  
pp. 1415-1420 ◽  
Author(s):  
Zuolong Yu ◽  
Jiadong Zhou ◽  
Fei Cao ◽  
Binbin Wen ◽  
Xuan Zhu ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Succinic Acid ◽  
Furandicarboxylic Acid

Semi-bio-based aromatic polyamides from 2,5-furandicarboxylic acid: toward high-performance polymers from renewable resources

RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 87013-87020 ◽  
Author(s):  
Kaiju Luo ◽  
Yan Wang ◽  
Junrong Yu ◽  
Jing Zhu ◽  
Zuming Hu
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Molecular Weight ◽  
High Molecular Weight ◽  
Renewable Resources ◽  
High Performance ◽  
Good Thermal Stability ◽  
Aromatic Polyamides ◽  
High Performance Polymers ◽  
Furandicarboxylic Acid

Aromatic furanic polyamides with relatively high molecular weight were synthesized, and good thermal stability and mechanical properties were demonstrated.

Synthesis and Characterization of Poly(terephthalic acid-2,5-furandicarboxylic acid-1,8-octanediol) Copolyester

2021 ◽  
Vol 36 (4) ◽  
pp. 557-561
Author(s):  
Zhengzai Cheng ◽  
Junpeng Cheng ◽  
Jun Chen ◽  
Jing Xiong ◽  
Xin Sun ◽  
...  
Keyword(s):  
Terephthalic Acid ◽  
Synthesis And Characterization ◽  
Furandicarboxylic Acid

Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic acid over Ru/Al2O3in a Trickle-Bed Reactor

2018 ◽  
Vol 58 (1) ◽  
pp. 128-137 ◽  
Author(s):  
Anna Danielli da Fonseca Ferreira ◽  
Matheus Dorneles de Mello ◽  
Mônica Antunes Pereira da Silva
Keyword(s):  
Catalytic Oxidation ◽  
Trickle Bed Reactor ◽  
Furandicarboxylic Acid ◽  
Trickle Bed

scholarly journals Synthesis of Furandicarboxylic Acid Esters From Nonfood Feedstocks Without Concomitant Levulinic Acid Formation

ChemSusChem ◽  
2017 ◽  
Vol 10 (7) ◽  
pp. 1460-1468 ◽  
Author(s):  
Frits van der Klis ◽  
Jacco van Haveren ◽  
Daan S. van Es ◽  
Johannes H. Bitter
Keyword(s):  
Levulinic Acid ◽  
Acid Formation ◽  
Furandicarboxylic Acid ◽  
Acid Esters
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