Tuning Ligand‐Coordinated Single Metal Atoms on TiO 2 and their Dynamic Response during Hydrogenation Catalysis

Front Cover: Tuning Ligand‐Coordinated Single Metal Atoms on TiO 2 and their Dynamic Response during Hydrogenation Catalysis (ChemSusChem 18/2021)

ChemSusChem ◽

10.1002/cssc.202101641 ◽

2021 ◽

Vol 14 (18) ◽

pp. 3632-3632

Author(s):

Xuemei Zhou ◽

George E. Sterbinsky ◽

Eman Wasim ◽

Linxiao Chen ◽

Steven L. Tait

Keyword(s):

Dynamic Response ◽

Front Cover ◽

Metal Atoms ◽

Hydrogenation Catalysis

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Incommensurate modulated phases of the NbxTa1-xTe4 charge density wave system

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100120692 ◽

1992 ◽

Vol 50 (1) ◽

pp. 58-59

Author(s):

S. Ritchie ◽

J. C. Bennett ◽

A. Prodan ◽

F.W. Boswell ◽

J.M. Corbett

Keyword(s):

Charge Density ◽

Charge Density Wave ◽

Direct Evidence ◽

Density Wave ◽

Wave System ◽

Modulated Phases ◽

Metal Atoms ◽

Incommensurate Modulation ◽

End Members ◽

Modulation Wave Vector

A continuous sequence of compounds having composition NbxTa1-xTe4; 0 ≤ x ≤ 1 have been studied by electron diffraction and microscopy. Previous studies have shown that the end members of the series, TaTε4 and NbTε4 possess a quasi-one-dimensional character and exhibit charge density wave (CDW) distortions. In these compounds, the subcell structure is tetragonal with axes (a × a × c) and consists of the metal atoms (Nb or Ta) centered within an extended antiprismatic cage of Te atoms. At room temperature, TaTε4 has a commensurate modulation structure with a 2a × 2a × 3c unit cell. In NbTε4, an incommensurate modulation with × ∼ 16c axes is observed. Preliminary studies of the mixed compounds NbxTα1-xTε4 showed a discontinuous jump of the modulation wave vector commensurate to incommensurate when the Nb dopant concentration x, exceeded x ≃ 0.3, In this paper, the nature of the compositional dependence of is studied in greater detail and evidence is presented for a stepwise variation of . This constitutes the first direct evidence for a Devil's staircase in CDW materials.

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Ultra high resolution SEM at high voltage images individual fab fragments applied as molecular label to cell surface receptors

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010015232x ◽

1989 ◽

Vol 47 ◽

pp. 70-71

Author(s):

Klaus-Ruediger Peters

Keyword(s):

High Resolution ◽

High Energy ◽

Metal Coating ◽

Beam Diameter ◽

Surface Receptors ◽

Surface Mobility ◽

Metal Atoms ◽

Shadowing Effect ◽

Imaging Mode ◽

Deposition Techniques

Topographic ultra high resolution can now routinely be established on bulk samples in cold field emission scanning electron microscopy with a second generation of microscopes (FSEM) designed to provide 0.5 nm probe diameters. If such small probes are used for high magnification imaging, topographic contrast is so high that remarkably fine details can be imaged on 2DMSO/osmium-impregnated specimens at ribosome surfaces even without a metal coating. On TCH/osmium-impregnated specimens topographic resolution can be increased further if the SE-I imaging mode is applied. This requires that beam diameter and metal coating thickness be made smaller than the SE range of ~1 nm and background signal contributions be reduced. Subnanometer small probes can be obtained (only) at high accelerating voltages. Subnanometer thin continuous metal films can be produced under the following conditions: self-shadowing effect between metal atoms must be reduced through appropriate deposition techniques and surface mobility of metal atoms must be diminished through high energy sputtering and/or specimen cooling.

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