High‐Loading Single‐Atom Copper Catalyst Supported on Coordinatively Unsaturated Al 2 O 3 for Selective Synthesis of Homoallylboronates

ChemSusChem ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 3115-3121 ◽  
Author(s):  
Tenglong Guo ◽  
Nanfang Tang ◽  
Feng Lin ◽  
Qinghao Shang ◽  
Shuai Chen ◽  
...  
Keyword(s):  
Copper Catalyst ◽  
High Loading ◽  
Single Atom ◽  
Selective Synthesis

scholarly journals Fabricating high-loading Fe-N4 single-atom catalysts for oxygen reduction reaction by carbon-assisted pyrolysis of metal complexes

2021 ◽  
Vol 42 (5) ◽  
pp. 753-761
Author(s):  
Jun-Sheng Jiang ◽  
He-Lei Wei ◽  
Ai-Dong Tan ◽  
Rui Si ◽  
Wei-De Zhang ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Metal Complexes ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
High Loading ◽  
Single Atom

High‐Loading Pt Single‐Atom Catalyst on CeO 2 ‐Modified Diatomite Support

2021 ◽  
Vol 16 (18) ◽  
pp. 2622-2625
Author(s):  
Yang Zhou ◽  
Wei Xi ◽  
Zixin Xie ◽  
Zhixin You ◽  
Xunzhu Jiang ◽  
...  
Keyword(s):  
High Loading ◽  
Single Atom ◽  
Modified Diatomite

scholarly journals Multilayer stabilization for fabricating high-loading single-atom catalysts

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Yazhou Zhou ◽  
Xiafang Tao ◽  
Guangbo Chen ◽  
Ruihu Lu ◽  
Ding Wang ◽  
...  
Keyword(s):  
Heterogeneous Reactions ◽  
High Loading ◽  
Single Atom ◽  
Hydrogen Electrode ◽  
Long Term Stability ◽  
Metal Precursors ◽  
Half Wave ◽  
Large Peak ◽  
Oxygen Reduction Catalyst

AbstractMetal single-atom catalysts (M-SACs) have emerged as an attractive concept for promoting heterogeneous reactions, but the synthesis of high-loading M-SACs remains a challenge. Here, we report a multilayer stabilization strategy for constructing M-SACs in nitrogen-, sulfur- and fluorine-co-doped graphitized carbons (M = Fe, Co, Ru, Ir and Pt). Metal precursors are embedded into perfluorotetradecanoic acid multilayers and are further coated with polypyrrole prior to pyrolysis. Aggregation of the metals is thus efficiently inhibited to achieve M-SACs with a high metal loading (~16 wt%). Fe-SAC serves as an efficient oxygen reduction catalyst with half-wave potentials of 0.91 and 0.82 V (versus reversible hydrogen electrode) in alkaline and acid solutions, respectively. Moreover, as an air electrode in zinc–air batteries, Fe-SAC demonstrates a large peak power density of 247.7 mW cm−2 and superior long-term stability. Our versatile method paves an effective way to develop high-loading M-SACs for various applications.

High loading single-atom Cu dispersed on graphene for efficient oxygen reduction reaction

Nano Energy ◽  
2019 ◽  
Vol 66 ◽  
pp. 104088 ◽  
Author(s):  
Guokang Han ◽  
Yu Zheng ◽  
Xue Zhang ◽  
Zhiqiang Wang ◽  
Yue Gong ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
High Loading ◽  
Single Atom

Single-atom Ru catalyst for selective synthesis of 3-pentanone via ethylene hydroformylation

2021 ◽  
Author(s):  
Tingting Qin ◽  
Yaru Dang ◽  
Tiejun Lin ◽  
Bingbao Mei ◽  
Bo Wu ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Single Atom ◽  
Selective Synthesis ◽  
Ru Catalyst ◽  
Ethylene Hydroformylation

Ru single-atom (Ru SA) catalyst supported on activated carbon was adopted to synthesize 3-pentanone with 83.3 % selectivity via heterogeneous ethylene hydroformylation, while 52.1 % of ethane selectivity was obtained...

scholarly journals High-loading and thermally stable Pt1/MgAl1.2Fe0.8O4 single-atom catalysts for high-temperature applications

2020 ◽  
Vol 63 (6) ◽  
pp. 949-958 ◽  
Author(s):  
Kaipeng Liu ◽  
Yan Tang ◽  
Zhiyang Yu ◽  
Binghui Ge ◽  
Guoqing Ren ◽  
...  
Keyword(s):  
High Temperature ◽  
High Loading ◽  
Single Atom ◽  
Thermally Stable ◽  
Temperature Applications
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