Palladium on Nitrogen-Doped Mesoporous Carbon: A Bifunctional Catalyst for Formate-Based, Carbon-Neutral Hydrogen Storage

ChemSusChem ◽  
2016 ◽  
Vol 9 (3) ◽  
pp. 246-251 ◽  
Author(s):  
Fanan Wang ◽  
Jinming Xu ◽  
Xianzhao Shao ◽  
Xiong Su ◽  
Yanqiang Huang ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Mesoporous Carbon ◽  
Neutral Hydrogen ◽  
Bifunctional Catalyst ◽  
Nitrogen Doped ◽  
Carbon Neutral

The Synthesis of Nitrogen-Doped Mesoporous Carbon Spheres for Hydrogen Storage

2016 ◽  
Vol 852 ◽  
pp. 864-869 ◽  
Author(s):  
Zi Qiang Wang ◽  
Li Xian Sun ◽  
Fen Xu ◽  
Xiao Jun Peng
Keyword(s):  
Hydrogen Storage ◽  
Mesoporous Carbon ◽  
Hydrogen Adsorption ◽  
Activated Carbons ◽  
Phenol Formaldehyde ◽  
Carbon Sources ◽  
Soft Template ◽  
Carbon Spheres ◽  
High Nitrogen ◽  
Nitrogen Doped

The nitrogen-doped mesoporous carbon spheres have been synthesized via soft-template and hydrothermal synthetic strategies using phenol/formaldehyde resins as carbon sources and melamine as a nitrogen source. The obtained carbon spheres exhibit a spherical morphology with a size range of 3-5 μm, which possess the narrow microporosity (ca. 1.2 nm) and mesoporosity (ca. 4 nm), large surface area (560-1200 m2 g-1) and high nitrogen contents (up to 15.7 wt%). Due to the well-developed porous structure and high nitrogen content, the carbon spheres show high performance for hydrogen storage, and the hydrogen adsorption capacities are in the range of 140-185 cm3 g-1, which is better than that of most activated carbons. The incorporation of nitrogen into carbons is favored for hydrogen uptake in low pressure.

scholarly journals High Capacity and Fast Kinetics of Potassium-Ion Batteries Boosted by Nitrogen-Doped Mesoporous Carbon Spheres

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Jiefeng Zheng ◽  
Yuanji Wu ◽  
Yong Tong ◽  
Xi Liu ◽  
Yingjuan Sun ◽  
...  
Keyword(s):  
Mesoporous Carbon ◽  
Active Sites ◽  
Carbon Materials ◽  
Potassium Ion ◽  
High Rate ◽  
Electrochemical Performances ◽  
Carbon Spheres ◽  
Fast Kinetics ◽  
Nitrogen Doped ◽  
Economic Price

AbstractIn view of rich potassium resources and their working potential, potassium-ion batteries (PIBs) are deemed as next generation rechargeable batteries. Owing to carbon materials with the preponderance of durability and economic price, they are widely employed in PIBs anode materials. Currently, porosity design and heteroatom doping as efficacious improvement strategies have been applied to the structural design of carbon materials to improve their electrochemical performances. Herein, nitrogen-doped mesoporous carbon spheres (MCS) are synthesized by a facile hard template method. The MCS demonstrate larger interlayer spacing in a short range, high specific surface area, abundant mesoporous structures and active sites, enhancing K-ion migration and diffusion. Furthermore, we screen out the pyrolysis temperature of 900 °C and the pore diameter of 7 nm as optimized conditions for MCS to improve performances. In detail, the optimized MCS-7-900 electrode achieves high rate capacity (107.9 mAh g−1 at 5000 mA g−1) and stably brings about 3600 cycles at 1000 mA g−1. According to electrochemical kinetic analysis, the capacitive-controlled effects play dominant roles in total storage mechanism. Additionally, the full-cell equipped MCS-7-900 as anode is successfully constructed to evaluate the practicality of MCS.

A template-directed bifunctional NiSx/nitrogen-doped mesoporous carbon electrocatalyst for rechargeable Zn–air batteries

2019 ◽  
Vol 7 (34) ◽  
pp. 19889-19897 ◽  
Author(s):  
Kai Wan ◽  
Jiangshui Luo ◽  
Xuan Zhang ◽  
Chen Zhou ◽  
Jin Won Seo ◽  
...  
Keyword(s):  
Mesoporous Carbon ◽  
Nitrogen Doped ◽  
Ordered Mesoporous

A highly ordered mesoporous NiSx/nitrogen-doped mesoporous carbon (NiSx/NMC) nanohybrid as a bifunctional oxygen electrocatalyst for rechargeable Zn–air batteries.

Nitrogen-Doped Mesoporous Carbon Derived from Polyaniline

2014 ◽  
Vol 926-930 ◽  
pp. 379-382
Author(s):  
De Yi Zhang ◽  
Li Wen Zheng ◽  
Long Yan Lei
Keyword(s):  
Mesoporous Carbon ◽  
Electronic Devices ◽  
Ordered Mesoporous Carbon ◽  
Additional Contribution ◽  
Electrochemical Capacitance ◽  
Supercapacitive Performance ◽  
Nitrogen Doped ◽  
Ordered Mesoporous ◽  
Capacitance Performance ◽  
A Current

In this paper, we demonstrate the successful fabrication of nitrogen doped ordered mesoporous carbon (PNOMC) materials using polyaniline as precursor. The synthesized PNOMC material exhibits enhanced supercapacitive performance due to the additional contribution from pseudo-capacitance originating from incorporation of nitrogen into the framework of carbon materials. Although the specific surface area of ​​the material is not high (386.2 m2/g), the specific capacitance is as high as the 271 F/g at a current density of 1A/g. The fabrication of nitrogen-doped ordered mesoporous carbon with enhanced electrochemical capacitance performance provides a viable route to promote its applications in electronic devices.

Synthesis and Properties of Nitrogen-Doped Mesoporous Carbon Materials Obtained by Templating of SBA-15 with Melamine-Formaldehyde Resin

2012 ◽  
Vol 554-556 ◽  
pp. 778-782 ◽  
Author(s):  
Chao Liu ◽  
Yong Qi Hu ◽  
Yi Feng Yu ◽  
Yue Zhang ◽  
Yan Yan Wang ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Mesoporous Carbon ◽  
Carbon Materials ◽  
Textural Properties ◽  
Formaldehyde Resin ◽  
Melamine Formaldehyde ◽  
X Ray ◽  
Nitrogen Doped ◽  
Surface Areas ◽  
Mesoporous Carbon Materials

Nitrogen-doped mesoporous carbon materials have been synthesized by using melamine-formaldehyde resin as carbon precursor and SBA-15 as a removable template. The structure of the materials was investigated by X-ray diffraction, BET specific surface area analysis, Fourier transform infrared spectroscopy, and thermogravimetric analysis. X-ray and BET studies confirmed that a pore nanostructure is inherited from the silica templates. Fourier transform infrared spectroscopy analysis showed N atoms are strongly bonded in the carbon structure in heterocycles or nitrile functions. These mesoporous nitrogen-doped carbon materials exhibits textural properties with BET surface areas ranging between 400 and 600 m2/g and uniform pore size(3.9 nm). The mechanism of carbonization process is studied by thermogravimetric analysis. The ratio of melamine/formaldehyde plays an important role during the carbonization process for the surface areas and textural properties, and element analysis reveals that the nitrogen content of the mesoporous carbon materials is as high as 10wt%.

Nitrogen-doped mesoporous carbon-armored cobalt nanoparticles as efficient hydrogen evolving electrocatalysts

2018 ◽  
Vol 514 ◽  
pp. 281-288 ◽  
Author(s):  
Duihai Tang ◽  
Kuo Li ◽  
Wenting Zhang ◽  
Zhen-An Qiao ◽  
Junjiang Zhu ◽  
...  
Keyword(s):  
Mesoporous Carbon ◽  
Cobalt Nanoparticles ◽  
Nitrogen Doped
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