Superior Ion-Conducting Hybrid Solid Electrolyte for All-Solid-State Batteries

ChemSusChem ◽  
2014 ◽  
Vol 8 (4) ◽  
pp. 636-641 ◽  
Author(s):  
Jae-Kwang Kim ◽  
Johan Scheers ◽  
Tae Joo Park ◽  
Youngsik Kim
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Solid State Batteries ◽  
All Solid State Batteries ◽  
Ion Conducting

Stabilizing a high-voltage LiNi0.5Mn1.5O4 cathode towards all solid state batteries: a Li–Al–Ti–P–O solid electrolyte nano-shell with a host material

Nanoscale ◽  
2019 ◽  
Vol 11 (18) ◽  
pp. 8967-8977 ◽  
Author(s):  
Li Li ◽  
Rui Zhao ◽  
Tinghua Xu ◽  
Dandan Wang ◽  
Du Pan ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
High Voltage ◽  
Cathode Surface ◽  
Lithium Ion ◽  
Host Material ◽  
Kinetic Characteristics ◽  
Solid State Batteries ◽  
All Solid State Batteries ◽  
Ion Conducting

A lithium ion conducting modification shell is introduced onto the cathode surface, which realizes excellent kinetic characteristics.

scholarly journals Inside Cover: Superior Ion-Conducting Hybrid Solid Electrolyte for All-Solid-State Batteries (ChemSusChem 4/2015)

ChemSusChem ◽  
2015 ◽  
Vol 8 (4) ◽  
pp. 570-570
Author(s):  
Jae-Kwang Kim ◽  
Johan Scheers ◽  
Tae Joo Park ◽  
Youngsik Kim
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Solid State Batteries ◽  
All Solid State Batteries ◽  
Ion Conducting

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Study on Li0.33La0.55TiO3 Solid Electrolyte with High Ionic Conductivity and Its Application in Flexible All Solid-State Battery

Nanoscale ◽  
2021 ◽  
Author(s):  
Feihu Tan ◽  
Hua An ◽  
Ning Li ◽  
Jun Du ◽  
Zhengchun Peng
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Solid Electrolyte ◽  
High Ionic Conductivity ◽  
Energy Sources ◽  
Solid State Battery ◽  
Solid State Batteries ◽  
All Solid State Batteries

As flexible all-solid-state batteries are highly safe and lightweight, they can be considered as candidates for wearable energy sources. However, their performance needs to be first improved, which can be...

Hydrated Alkali-B11H14 Salts as Potential Solid-State Electrolytes†

2021 ◽  
Author(s):  
Diego Holanda Pereira de Souza ◽  
Kasper T. Møller ◽  
Stephen A. Moggach ◽  
Terry D Humphries ◽  
Anita D’Angelo ◽  
...  
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Solid Electrolyte ◽  
High Ionic Conductivity ◽  
Solid State Batteries ◽  
All Solid State Batteries ◽  
Solid State Electrolytes

Metal boron-hydrogen compounds are considered as promising solid electrolyte candidates for the development of all-solid-state batteries (ASSB), owing to the high ionic conductivity exhibited by closo- and nido-boranes. In this...

Enhancing interfacial contact in all solid state batteries with a cathode-supported solid electrolyte membrane framework

2019 ◽  
Vol 12 (3) ◽  
pp. 938-944 ◽  
Author(s):  
Xinzhi Chen ◽  
Wenjun He ◽  
Liang-Xin Ding ◽  
Suqing Wang ◽  
Haihui Wang
Keyword(s):  
Solid State ◽  
Electrochemical Performance ◽  
Solid Electrolyte ◽  
Electrolyte Membrane ◽  
Interfacial Contact ◽  
Solid State Batteries ◽  
All Solid State Batteries

A cathode-supported solid electrolyte membrane framework with enhanced interfacial contact can significantly improve the electrochemical performance of all solid state batteries.

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