Controlled Hydrophobic Functionalization of Natural Fibers through Self-Assembly of Amphiphilic Diblock Copolymer Micelles

ChemSusChem ◽  
2013 ◽  
Vol 6 (7) ◽  
pp. 1203-1208 ◽  
Author(s):  
Niko Aarne ◽  
Janne Laine ◽  
Tuomas Hänninen ◽  
Ville Rantanen ◽  
Jani Seitsonen ◽  
...  
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Natural Fibers ◽  
Amphiphilic Diblock Copolymer ◽  
Copolymer Micelles

Synthesis of poly(methyl methacrylate)-b-poly(acrylic acid) by DPE method

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Dong Chen ◽  
Ruixue Liu ◽  
Zhifeng Fu ◽  
Yan Shi
Keyword(s):  
Molecular Weight ◽  
Acrylic Acid ◽  
Methyl Methacrylate ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Gel Permeation Chromatography ◽  
Amphiphilic Diblock Copolymer ◽  
Poly Methyl Methacrylate ◽  
Copolymer Poly ◽  
Poly Acrylic Acid

AbstractAmphiphilic diblock copolymer poly(methyl methacrylate)-b-poly(acrylic acid) (PMMA-b-PAA) was prepared by 1,1-diphenylethene (DPE) method. Firstly, free radical polymerization of methyl methacrylate was carried out with AIBN as initiator in the presence of DPE, giving a DPE-containing PMMA precursor with controlled molecular weight. tert-Butyl acrylate (tBA) was then polymerized in the presence of the PMMA precursor, and PMMA-b-PtBA diblock copolymer with controlled molecular weight was prepared. Finally, amphiphilic diblock copolymer PMMA-b-PAA was obtained by hydrolysis of PMMA-b-PtBA. The formation of PMMA-b-PAA was confirmed by 1H NMR spectrum and gel permeation chromatography. Transmission electron microscopy and dynamic light scattering were used to detect the self-assembly behavior of the amphiphilic diblock polymers in methanol.

Inside Front Cover: Self-Assembly of Diblock-Copolymer Micelles for Template-Based Preparation of PbTiO3 Nanograins (Adv. Funct. Mater. 18/2006)

2006 ◽  
Vol 16 (18) ◽  
pp. NA-NA
Author(s):  
S. Kronholz ◽  
S. Rathgeber ◽  
S. Karthäuser ◽  
H. Kohlstedt ◽  
S. Clemens ◽  
...  
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Front Cover ◽  
Copolymer Micelles

scholarly journals Synthesis and self-assembly of a novel amphiphilic diblock copolymer consisting of isotactic polystyrene and 1,4-trans-polybutadiene-graft-poly(ethylene oxide)

RSC Advances ◽  
2018 ◽  
Vol 8 (23) ◽  
pp. 12752-12759
Author(s):  
HuaQing Liang ◽  
QiHua Zhou ◽  
YongJiang Long ◽  
WanChu Wei ◽  
Shuo Feng ◽  
...  
Keyword(s):  
Ethylene Oxide ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Amphiphilic Diblock Copolymer ◽  
Isotactic Polystyrene ◽  
Poly Ethylene Oxide ◽  
Assembly Behavior ◽  
Poly Ethylene

Herein, a novel amphiphilic diblock copolymer consisting of isotactic polystyrene and 1,4-trans-polybutadiene-graft-poly(ethylene oxide) was synthesized and its self-assembly behavior was investigated.

Sequential pH-Dependent Adsorption of Ionic Amphiphilic Diblock Copolymer Micelles and Choline Oxidase Onto Conductive Substrates: Toward the Design of Biosensors

2014 ◽  
Vol 14 (7) ◽  
pp. 1039-1051 ◽  
Author(s):  
Larisa V. Sigolaeva ◽  
Ulrike Günther ◽  
Dmitry V. Pergushov ◽  
Snezhana Yu. Gladyr ◽  
Ilya N. Kurochkin ◽  
...  
Keyword(s):  
Diblock Copolymer ◽  
Choline Oxidase ◽  
Amphiphilic Diblock Copolymer ◽  
Conductive Substrates ◽  
Ph Dependent ◽  
Copolymer Micelles

Multiple morphologies of amphiphilic diblock copolymer micelles in two and three dimensions

1997 ◽  
Vol 118 (1) ◽  
pp. 647-655 ◽  
Author(s):  
Chris J. Clarke ◽  
Lifeng Zhang ◽  
Jiayi Zhu ◽  
Kui Yu ◽  
R. Bruce Lennox ◽  
...  
Keyword(s):  
Diblock Copolymer ◽  
Three Dimensions ◽  
Amphiphilic Diblock Copolymer ◽  
Copolymer Micelles

Self-Assembly of Diblock-Copolymer Micelles for Template-Based Preparation of PbTiO3 Nanograins

2006 ◽  
Vol 16 (18) ◽  
pp. 2346-2354 ◽  
Author(s):  
S. Kronholz ◽  
S. Rathgeber ◽  
S. Karthäuser ◽  
H. Kohlstedt ◽  
S. Clemens ◽  
...  
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Copolymer Micelles
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