Electron Microscopy and X-ray Study of the Growth of FeCr2S4 Spinel Single Crystals by Chemical Vapour Transport

1993 ◽  
Vol 28 (8) ◽  
pp. 1051-1061 ◽  
Author(s):  
V. V. Volkov ◽  
C. Van Heurck ◽  
J. Van Landuyt ◽  
S. Amelinckx ◽  
E. G. Zhukov ◽  
...  
1998 ◽  
Vol 274 (1-2) ◽  
pp. 128-135 ◽  
Author(s):  
Wojciech Paszkowicz ◽  
Jarosław Domagała ◽  
Zbigniew Gołacki

2007 ◽  
Vol 130 ◽  
pp. 81-84 ◽  
Author(s):  
Izabela Jendrzejewska ◽  
Alicja Waśkowska ◽  
Elżbieta Augustyn

The single crystals of ZnCr2Se4 spinel doped with manganese were prepared by the chemical vapour transport in closed silica tubes using stoichiometric contents of ZnSe, MnSe and CrCl3 as the transporting agent. Chemical composition of four single crystals of Zn-Mn-Cr-Se system with different concentration of manganese was analyzed and confirmed by X-ray diffraction study. The structure refinements, taking into account site occupancy factors, indicated that Mn ion shared tetrahedral sites with Zn ion. Thus, the formula describing cation distribution in the system is: Zn1-xMnxCr2Se4. For all x values equal to 0.12, 0.13, 0.18 and 0.24, the observed symmetry was cubic, space group Fd 3m .


1987 ◽  
Vol 17 (3) ◽  
pp. 311-316 ◽  
Author(s):  
B. Vengatesan ◽  
N. Kanniah ◽  
P. Ramasamy

1982 ◽  
Vol 37 (3) ◽  
pp. 390-391 ◽  
Author(s):  
M. Schulte-Kellinghaus ◽  
V. Krämer

Abstract The title compounds were prepared by chemical vapour transport. They crystallize in the space group P3̅m 1 with the lattice parameters a = 7.532(3) (7.589(5)) and c = 36.54(2) (36.70(5))!. X-ray powder diffraction data are listed and the T,x phase diagram of the system AlInS3-In2S3 is shown.


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