In-situ investigation of the temperature dependent structural phase transition in CuInSe2 by synchrotron radiation

2006 ◽  
Vol 41 (5) ◽  
pp. 450-457 ◽  
Author(s):  
S. Schorr ◽  
G. Geandier
Keyword(s):  
Phase Transition ◽  
Synchrotron Radiation ◽  
Structural Phase Transition ◽  
Structural Phase ◽  
Temperature Dependent ◽  
In Situ Investigation

From structural phase transition to highly sensitive lifetime based luminescent thermometer: multifaceted modification of thermometric performance in Y0.9-xNdxYb0.1PO4 nanocrystals

2021 ◽  
Author(s):  
Kamila Maciejewska ◽  
Marcin Szalkowski ◽  
Artur Bednarkiewicz ◽  
Lukasz Marciniak
Keyword(s):  
Phase Transition ◽  
Structural Properties ◽  
Structural Phase Transition ◽  
Structural Phase ◽  
Deep Understanding ◽  
Luminescent Properties ◽  
Host Material ◽  
Temperature Dependent ◽  
Highly Sensitive

The development of highly sensitive luminescent thermometer requires deep understanding of the correlation between structural properties of the host material with temperature-dependent luminescent properties of lanthanide emitters embedded in these...

scholarly journals The correlation between phase transition and photoluminescence properties of CsPbX3 (X = Cl, Br, I) perovskite nanocrystals

2020 ◽  
Vol 2 (10) ◽  
pp. 4390-4394 ◽  
Author(s):  
Jun Yi ◽  
Xueying Ge ◽  
Exian Liu ◽  
Tong Cai ◽  
Chujun Zhao ◽  
...  
Keyword(s):  
Phase Transition ◽  
Steady State ◽  
Structural Phase Transition ◽  
Structural Phase ◽  
Photoluminescence Properties ◽  
Temperature Dependent ◽  
Time Resolved ◽  
Perovskite Nanocrystals

We report a correlation between the structural phase transition of CsPbX3 (X = Cl, Br, I) nanocrystals (NCs) and their temperature dependent steady-state photoluminescence (PL) and time-resolved PL (TRPL).

Dynamic Order-Disorder Transition in the S = ½ Kagome Antiferromagnets Barlowite and Claringbullite

2018 ◽  
Author(s):  
Alyssa Henderson ◽  
Lianyang Dong ◽  
Sananda Biswas ◽  
Hannah Revell ◽  
Yan Xin ◽  
...  
Keyword(s):  
Phase Transition ◽  
Structural Phase Transition ◽  
Density Functional ◽  
Structural Phase ◽  
Density Functional Theory Calculations ◽  
Temperature Dependent ◽  
Orthorhombic Space Group ◽  
Functional Theory ◽  
Dynamic Disorder ◽  
Disorder Type

The nature of the structural phase transition in the quantum magnets barlowite, Cu4(OH)6FBr, and claringbullite, Cu4(OH)6FCl was investigated. These materials consist of parallel-stacked Cu2+ kagome layers, separated by planes that contain Cu2+ cations and halide anions. The structural transition is of an order-disorder type, where at ambient temperature the interlayer Cu2+ ions are disordered over three equivalent positions. In barlowite, the dynamic disorder becomes static as the temperature is decreased, resulting in a lowering of the overall symmetry from hexagonal P63/mmc to orthorhombic. The dynamic disorder in claringbullite persists to lower temperatures, with a transition to orthorhombic space group Pnma observed in some samples. Ab initio density functional theory calculations explain this temperature-dependent structural phase transition and provide additional insights regarding the differences between these two materials.

Dynamic Order-Disorder Transition in the S = ½ Kagome Antiferromagnets Barlowite and Claringbullite

2018 ◽  
Author(s):  
Alyssa Henderson ◽  
Lianyang Dong ◽  
Sananda Biswas ◽  
Hannah Revell ◽  
Yan Xin ◽  
...  
Keyword(s):  
Phase Transition ◽  
Structural Phase Transition ◽  
Density Functional ◽  
Structural Phase ◽  
Density Functional Theory Calculations ◽  
Temperature Dependent ◽  
Orthorhombic Space Group ◽  
Functional Theory ◽  
Dynamic Disorder ◽  
Disorder Type

The nature of the structural phase transition in the quantum magnets barlowite, Cu4(OH)6FBr, and claringbullite, Cu4(OH)6FCl was investigated. These materials consist of parallel-stacked Cu2+ kagome layers, separated by planes that contain Cu2+ cations and halide anions. The structural transition is of an order-disorder type, where at ambient temperature the interlayer Cu2+ ions are disordered over three equivalent positions. In barlowite, the dynamic disorder becomes static as the temperature is decreased, resulting in a lowering of the overall symmetry from hexagonal P63/mmc to orthorhombic. The dynamic disorder in claringbullite persists to lower temperatures, with a transition to orthorhombic space group Pnma observed in some samples. Ab initio density functional theory calculations explain this temperature-dependent structural phase transition and provide additional insights regarding the differences between these two materials.

Sign in / Sign up

Export Citation Format

Share Document