Light-Induced Activation of the Du Bois [RhII 2 (Esp)2 ] Catalyst for Nitrogen Atom Transfer Reactions

ChemPhotoChem ◽  
2017 ◽  
Vol 1 (12) ◽  
pp. 562-567
Author(s):  
Rajaa Farran ◽  
Clémence Ducloiset ◽  
Julien Buendia ◽  
Nhat Tam Vo ◽  
Régis Guillot ◽  
...  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.


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