How Dimerization Through a Spiro Junction Modifies the Nonlinear Optical Properties of a Push-Pull Organic Dye: Insights from Theory and Hyper-Rayleigh Scattering

ChemPhotoChem ◽  
2017 ◽  
Vol 1 (3) ◽  
pp. 93-101
Author(s):  
Frédéric Castet ◽  
Timothée Lerychard ◽  
Kornelia Pielak ◽  
György Szalóki ◽  
Clément Dalinot ◽  
...  
2004 ◽  
Vol 13 (03n04) ◽  
pp. 423-426 ◽  
Author(s):  
L. SANGUINET ◽  
S. AHMED ◽  
J. L. POZZO ◽  
V. RODRIGUEZ ◽  
F. ADAMIETZ

New acidochromic and photochromic compounds with nonlinear optical properties have been designed and synthesized. The hyperpolarizabilities of the zwitterionic colored forms have been quantified with polarized hyper-Rayleigh scattering experiments. The static value of oxazolidino-indoline 2 is found to be as high as Disperse Red One. This opens the way to novel multi-addressable NLO-systems.


2001 ◽  
Vol 190 (1-6) ◽  
pp. 345-349 ◽  
Author(s):  
Guangyong Zhou ◽  
Xiaomei Wang ◽  
Dong Wang ◽  
Chun Wang ◽  
Zongshu Shao ◽  
...  

2017 ◽  
Vol 121 (3) ◽  
pp. 1851-1860 ◽  
Author(s):  
Kornelia Pielak ◽  
Flavie Bondu ◽  
Lionel Sanguinet ◽  
Vincent Rodriguez ◽  
Benoît Champagne ◽  
...  

1998 ◽  
Vol 07 (01) ◽  
pp. 113-120 ◽  
Author(s):  
Stephan Houbrechts ◽  
Carlo Boutton ◽  
Koen Clays ◽  
André Persoons ◽  
Ian R. Whittall ◽  
...  

Hyper-Rayleigh scattering is used to investigate the nonlinear optical properties of novel metal (ruthenium, nickel and gold) σ-arylacetylide complexes. The influence of the organometallic donor group and conjugating bridge on the quadratic hyperpolarizability is studied. For all organic ligands, the addition of the metal (donor) group is shown to increase the static hyperpolarizability by a factor of 2, 4 and 7 for gold, nickel and ruthenium complexes, respectively. Moreover, replacement of phenyl with a heterocyclic ring is demonstrated to enlarge the hyperpolarizability in the case of gold and ruthenium compounds.


1998 ◽  
Vol 5 (5-6) ◽  
pp. 495-498 ◽  
Author(s):  
De-gang Fu ◽  
Ming Li ◽  
Xin Wang ◽  
Ji-qi Cheng ◽  
Yu Zhang ◽  
...  

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