scholarly journals Towards Mechanistic Understanding of Liquid‐Phase Cinnamyl Alcohol Oxidation with tert ‐Butyl Hydroperoxide over Noble‐Metal‐Free LaCo 1– x Fe x O 3 Perovskites

ChemPlusChem ◽  
2019 ◽  
Vol 84 (8) ◽  
pp. 1155-1163 ◽  
Author(s):  
Daniel Waffel ◽  
Baris Alkan ◽  
Qi Fu ◽  
Yen‐Ting Chen ◽  
Stefan Schmidt ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Noble Metal ◽  
Alcohol Oxidation ◽  
Cinnamyl Alcohol ◽  
Butyl Hydroperoxide ◽  
Metal Free ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Mechanistic Understanding

ChemInform Abstract: Metal-Free Csp3-N Bond Cleavage of Amides Using tert-Butyl Hydroperoxide as Oxidant.

ChemInform ◽  
2015 ◽  
Vol 46 (28) ◽  
pp. no-no ◽  
Author(s):  
Shengmei Guo ◽  
Zheng Zhu ◽  
Lin Lu ◽  
Wenbiao Zhang ◽  
Jiuhan Gong ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Butyl Hydroperoxide ◽  
Metal Free ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

scholarly journals Catalytic Performance of Ceria Nanorods in Liquid-Phase Oxidations of Hydrocarbons with tert-Butyl Hydroperoxide

Molecules ◽  
2010 ◽  
Vol 15 (2) ◽  
pp. 747-765 ◽  
Author(s):  
Andreia Macedo ◽  
Sílvia E. Fernandes ◽  
Anabela Valente ◽  
Rute. A. Ferreira ◽  
Luís Carlos ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Catalytic Performance ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

scholarly journals α-Acetoxyarone synthesis via iodine-catalyzed and tert-butyl hydroperoxide-mediateded self-intermolecular oxidative coupling of aryl ketones

2017 ◽  
Vol 13 ◽  
pp. 1079-1084 ◽  
Author(s):  
Liquan Tan ◽  
Cui Chen ◽  
Weibing Liu
Keyword(s):  
Oxidative Coupling ◽  
Optimum Conditions ◽  
Butyl Hydroperoxide ◽  
Metal Free ◽  
Tert Butyl ◽  
Radical Intermediates ◽  
Tert Butyl Hydroperoxide ◽  
Aryl Ketones

We present a metal-free method for α-acetoxyarone synthesis by self-intermolecular oxidative coupling of aryl ketones using I2−tert-butyl hydroperoxide (TBHP). Under the optimum conditions, various aryl ketones gave the corresponding products in moderate to excellent yields. A series of control experiments were performed; the results suggest the involvement of radical pathways. Multiple radical intermediates were generated in situ and the overall process involved several different reactions, which proceeded self-sequentially in a single reactor. A labeling experiment using 18O-labeled H2O confirmed that the oxygen in the product was derived from TBHP, not from H2O in the TBHP solvent.

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