Self-Assembly of Anionic Porphyrins and Alkaline or Alkaline Earth Metal Ions Mediated by Cucurbit[7,8]uril

ChemPhysChem ◽  
2013 ◽  
Vol 14 (5) ◽  
pp. 1003-1008 ◽  
Author(s):  
Wanhua Lei ◽  
Guoyu Jiang ◽  
Qianxiong Zhou ◽  
Yuanjun Hou ◽  
Baowen Zhang ◽  
...  
Keyword(s):  
Metal Ions ◽  
Self Assembly ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Alkaline Earth Metal Ions

Nuclear magnetic resonance and mass spectrometry studies of 2′,3′,5′-O-triacetylguanosine self-assembly in the presence of alkaline earth metal ions (Ca2+, Sr2+, Ba2+)

2011 ◽  
Vol 89 (7) ◽  
pp. 835-844 ◽  
Author(s):  
Irene C.M. Kwan ◽  
Yi-Min She ◽  
Gang Wu
Keyword(s):  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Metal Ions ◽  
Self Assembly ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Alkaline Earth Metal Ions ◽  
Nuclear Magnetic

We report structural determination of cation-templated self-assembly of a guanosine derivative, 2′,3′,5′-O-triacetylguanosine (TAG), in the presence of three alkaline earth metal ions (Ca2+, Sr2+, and Ba2+) in CDCl3. Using a combination of nuclear magnetic resonance (NMR) and electrospray ionization mass spectrometry (ESI-MS) methods, we have found that TAG molecules form discrete octamers in the form of [TAG]8M2+ (M2+ = Ca2+, Sr2+, and Ba2+), which is composed of two G-quartets and a sandwiched metal ion. We have determined the ability of the three alkaline earth metal ions to promote TAG self-assembly (relative binding affinity) to be Sr2+ ≫ Ba2+ > Ca2+. More importantly, we have used two-dimensional (2D) NMR methods to determine the structural details of [TAG]8Sr2+. In particular, we found that each octamer consists of an all-anti G-quartet stacking on top of an all-syn G-quartet in a tail-to-head fashion with a twist angle of 45° between the two G-quartets. This TAG octamer structure represents a unique case quite different from other lipophilic guanosine octamers reported in the literature.

Difference of Coordination between Alkali- and Alkaline-Earth-Metal Ions to a Symmetrical α,α′,δ,δ′-Tetramethylcucurbit[6]uril

2011 ◽  
Vol 50 (15) ◽  
pp. 6956-6964 ◽  
Author(s):  
Wen-Jian Chen ◽  
Da-Hai Yu ◽  
Xin Xiao ◽  
Yun-Qian Zhang ◽  
Qian-Jiang Zhu ◽  
...  
Keyword(s):  
Metal Ions ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Alkaline Earth Metal Ions

Membranes for Separation of Alkali/Alkaline Earth Metal Ions: A Review

2021 ◽  
pp. 119640
Author(s):  
Yiran Wang ◽  
Wen Zhang ◽  
Xianjie Zeng ◽  
Tao Deng ◽  
Jianyou Wang
Keyword(s):  
Metal Ions ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Alkaline Earth Metal Ions

scholarly journals Dansyl - Substituted Aza Crown Ethers: Complexation with Alkali, Alkaline Earth Metal Ions and Ammonium

2011 ◽  
Vol 3 (1) ◽  
Author(s):  
Nelly Mateeva ◽  
Shihab Deiab ◽  
Edikan Archibong ◽  
Donka Tasheva ◽  
Bereket Mochona ◽  
...  
Keyword(s):  
Metal Ions ◽  
Crown Ethers ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Alkaline Earth Metal Ions ◽  
Aza Crown Ethers

scholarly journals Changes in Stereoselectivity in the Triose Aldol Condensation with Increased Concentration of Alkaline-Earth Metal Ions.

1988 ◽  
Vol 42b ◽  
pp. 546-549 ◽  
Author(s):  
Svein Morgenlie ◽  
Anja Oasmaa ◽  
Curt R. Enzell ◽  
Jan-Eric Berg ◽  
W. Michael Moore ◽  
...  
Keyword(s):  
Metal Ions ◽  
Alkaline Earth ◽  
Aldol Condensation ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Alkaline Earth Metal Ions
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