Tuning of Photocatalytic Hydrogen Production and Photoinduced Intramolecular Electron Transfer Rates by Regioselective Bridging Ligand Substitution

ChemPhysChem ◽  
2011 ◽  
Vol 12 (11) ◽  
pp. 2101-2109 ◽  
Author(s):  
Michael Karnahl ◽  
Christian Kuhnt ◽  
Fei Ma ◽  
Arkady Yartsev ◽  
Michael Schmitt ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Hydrogen Production ◽  
Ligand Substitution ◽  
Intramolecular Electron Transfer ◽  
Photocatalytic Hydrogen Production ◽  
Transfer Rates ◽  
Bridging Ligand

Balancing electron transfer rate and driving force for efficient photocatalytic hydrogen production in CdSe/CdS nanorod–[NiFe] hydrogenase assemblies

2017 ◽  
Vol 10 (10) ◽  
pp. 2245-2255 ◽  
Author(s):  
Bryant Chica ◽  
Chang-Hao Wu ◽  
Yuhgene Liu ◽  
Michael W. W. Adams ◽  
Tianquan Lian ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Hydrogen Production ◽  
Driving Force ◽  
Transfer Rate ◽  
Pyrococcus Furiosus ◽  
Electron Transfer Rate ◽  
Photocatalytic Hydrogen Production ◽  
Photocatalytic System

We describe a hybrid photocatalytic system for hydrogen production consisting of nanocrystalline CdSe/CdS dot-in-rod (DIR) structures coupled to [NiFe] soluble hydrogenase I (SHI) fromPyrococcus furiosus.

Intramolecular electron-transfer rates in ferrocene-derivatized glucose oxidase

1993 ◽  
Vol 115 (16) ◽  
pp. 7053-7060 ◽  
Author(s):  
Antonella Badia ◽  
Rina Carlini ◽  
Arthur Fernandez ◽  
Fernando Battaglini ◽  
Susan R. Mikkelsen ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Glucose Oxidase ◽  
Intramolecular Electron Transfer ◽  
Transfer Rates

scholarly journals Photo-catalytic hydrogen production over Au/g-C3N4: effect of gold particle dispersion and morphology

2019 ◽  
Vol 21 (29) ◽  
pp. 15974-15987 ◽  
Author(s):  
M. Caux ◽  
H. Menard ◽  
Y. M. AlSalik ◽  
J. T. S. Irvine ◽  
H. Idriss
Keyword(s):  
Electron Transfer ◽  
Hydrogen Production ◽  
Gold Particle ◽  
Particle Dispersion ◽  
Hydrogen Ion ◽  
Transfer Rates ◽  
Catalytic Hydrogen

Metal/semiconductor interactions affect electron transfer rates and this is central to photocatalytic hydrogen ion reduction.

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