In Situ Discrimination between Axially Complexed and Ligand-Free Co Porphyrin on Au(111) with Tip-Enhanced Raman Spectroscopy

ChemPhysChem ◽  
2009 ◽  
Vol 10 (11) ◽  
pp. 1794-1798 ◽  
Author(s):  
Katrin F. Domke ◽  
Bruno Pettinger
Keyword(s):  
Raman Spectroscopy ◽  
Ligand Free ◽  
Tip Enhanced Raman Spectroscopy

Electrochemical Tip-Enhanced Raman Spectroscopy for the In Situ Characterization of Functional Materials

2021 ◽  
Vol MA2021-02 (50) ◽  
pp. 1485-1485
Author(s):  
Alice Fiocco ◽  
Aja Ana Pavlic ◽  
Laure Fillaud ◽  
Emmanuel Maisonhaute ◽  
Jean-Marc Noel ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Functional Materials ◽  
In Situ Characterization ◽  
Tip Enhanced Raman Spectroscopy

Near-field Raman spectroscopy of biological nanomaterials by in situ laser-induced synthesis of tip-enhanced Raman spectroscopy tips

2012 ◽  
Vol 37 (12) ◽  
pp. 2256 ◽  
Author(s):  
Faris Sinjab ◽  
Banyat Lekprasert ◽  
Richard A. J. Woolley ◽  
Clive J. Roberts ◽  
Saul J. B. Tendler ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Near Field ◽  
Tip Enhanced Raman Spectroscopy

In Situ Nanoscale Redox Mapping Using Tip-Enhanced Raman Spectroscopy

Nano Letters ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 2106-2113 ◽  
Author(s):  
Gyeongwon Kang ◽  
Muwen Yang ◽  
Michael S. Mattei ◽  
George C. Schatz ◽  
Richard P. Van Duyne
Keyword(s):  
Raman Spectroscopy ◽  
Tip Enhanced Raman Spectroscopy

Electrochemical Tip-Enhanced Raman Spectroscopy: An In Situ Nanospectroscopy for Electrochemistry

2021 ◽  
Vol 72 (1) ◽  
Author(s):  
Sheng-Chao Huang ◽  
Yi-Fan Bao ◽  
Si-Si Wu ◽  
Teng-Xiang Huang ◽  
Matthew M. Sartin ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Surface Science ◽  
Spatial Resolution ◽  
Rational Design ◽  
Annual Review ◽  
Chemical Information ◽  
Publication Date ◽  
Molecular Fingerprint ◽  
Tip Enhanced Raman Spectroscopy

Revealing the intrinsic relationships between the structure, properties, and performance of the electrochemical interface is a long-term goal in the electrochemistry and surface science communities because they could facilitate the rational design of electrochemical devices. Achieving this goal requires in situ characterization techniques that provide rich chemical information and high spatial resolution. Electrochemical tip-enhanced Raman spectroscopy (EC-TERS), which provides molecular fingerprint information with nanometer-scale spatial resolution, is a promising technique for achieving this goal. Since the first demonstration of this technique in 2015, EC-TERS has been developed for characterizing various electrochemical processes at the nanoscale and molecular level. Here, we review the development of EC-TERS over the past 5 years. We discuss progress in addressing the technical challenges, including optimizing the EC-TERS setup and solving tip-related issues, and provide experimental guidelines. We also survey the important applications of EC-TERS for probing molecular protonation, molecular adsorption, electrochemical reactions, and photoelectrochemical reactions. Finally, we discuss the opportunities and challenges in the future development of this young technique. Expected final online publication date for the Annual Review of Physical Chemistry, Volume 72 is April 2021. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.

Probing the Plasmon-Driven Suzuki-Miyaura Coupling Reactions with Cargo-TERS towards Tailored Catalyzation

Nanoscale ◽  
2021 ◽  
Author(s):  
Zhandong Li ◽  
Dmitry Kurouski
Keyword(s):  
Raman Spectroscopy ◽  
Analytical Approach ◽  
Coupling Reactions ◽  
Label Free ◽  
In Situ Assessment ◽  
Molecular Reactivity ◽  
Tip Enhanced Raman Spectroscopy

We present a label-free approach that is based on tip-enhanced Raman spectroscopy (TERS) for a direct in-situ assessment of molecular reactivity in plasmon-driven reactions. Using this analytical approach, named cargo-TERS,...

In Situ Electrochemical Tip-Enhanced Raman Spectroscopy with a Chemically Modified Tip

2018 ◽  
Vol 9 (14) ◽  
pp. 3825-3828 ◽  
Author(s):  
Guillaume Goubert ◽  
Xu Chen ◽  
Song Jiang ◽  
Richard P. Van Duyne
Keyword(s):  
Raman Spectroscopy ◽  
Chemically Modified ◽  
Tip Enhanced Raman Spectroscopy
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