Excited-State Dynamics of Isolated DNA Bases: A Case Study of Adenine

ChemPhysChem ◽  
2009 ◽  
Vol 10 (1) ◽  
pp. 101-110 ◽  
Author(s):  
Christer Z. Bisgaard ◽  
Helmut Satzger ◽  
Susanne Ullrich ◽  
Albert Stolow
Keyword(s):  
Excited State ◽  
Dna Bases ◽  
Excited State Dynamics

Excited state dynamics of DNA bases

2013 ◽  
Vol 32 (2) ◽  
pp. 308-342 ◽  
Author(s):  
Karl Kleinermanns ◽  
Dana Nachtigallová ◽  
Mattanjah S. de Vries
Keyword(s):  
Excited State ◽  
Dna Bases ◽  
Excited State Dynamics

scholarly journals Effect of substituents on the excited-state dynamics of the modified DNA bases 2,4-diaminopyrimidine and 2,6-diaminopurine

2010 ◽  
Vol 12 (20) ◽  
pp. 5375 ◽  
Author(s):  
Zsolt Gengeliczki ◽  
Michael P. Callahan ◽  
Nathan Svadlenak ◽  
Csaba István Pongor ◽  
Bálint Sztáray ◽  
...  
Keyword(s):  
Excited State ◽  
Dna Bases ◽  
Excited State Dynamics ◽  
Effect Of Substituents ◽  
Modified Dna

Excited-State Dynamics in the RNA Nucleotide Uridine 5’-Monophosphate Investigated by Femtosecond Broadband Transient Absorption Spectroscopy

2019 ◽  
Author(s):  
Matthew M. Brister ◽  
Carlos Crespo-Hernández
Keyword(s):  
Excited State ◽  
Excited States ◽  
Ground State ◽  
Transient Absorption ◽  
Electronic Energy ◽  
Transient Absorption Spectroscopy ◽  
Electronic Relaxation ◽  
Vibrationally Excited ◽  
Excited State Dynamics ◽  
Π State

<p></p><p> Damage to RNA from ultraviolet radiation induce chemical modifications to the nucleobases. Unraveling the excited states involved in these reactions is essential, but investigations aimed at understanding the electronic-energy relaxation pathways of the RNA nucleotide uridine 5’-monophosphate (UMP) have not received enough attention. In this Letter, the excited-state dynamics of UMP is investigated in aqueous solution. Excitation at 267 nm results in a trifurcation event that leads to the simultaneous population of the vibrationally-excited ground state, a longlived <sup>1</sup>n<sub>O</sub>π* state, and a receiver triplet state within 200 fs. The receiver state internally convert to the long-lived <sup>3</sup>ππ* state in an ultrafast time scale. The results elucidate the electronic relaxation pathways and clarify earlier transient absorption experiments performed for uracil derivatives in solution. This mechanistic information is important because long-lived nπ* and ππ* excited states of both singlet and triplet multiplicities are thought to lead to the formation of harmful photoproducts.</p><p></p>

Modulation of Excited State Dynamics in Lead Halide Perovskite Films with Electrical Bias

2019 ◽  
Author(s):  
Gergely Samu ◽  
R.A. Scheidt ◽  
A. Balog ◽  
C. Janáky ◽  
P.V. Kamat
Keyword(s):  
Excited State ◽  
Excited State Dynamics ◽  
Halide Perovskite ◽  
Electrical Bias ◽  
Lead Halide
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