X-ray Absorption Spectroscopic Study of LiCoO2 as the Negative Electrode of Lithium-Ion Batteries

ChemPhysChem ◽  
2006 ◽  
Vol 7 (5) ◽  
pp. 1086-1091 ◽  
Author(s):  
Alan V. Chadwick ◽  
Shelley L. P. Savin ◽  
Ricardo Alcántara ◽  
Diego Fernández Lisbona ◽  
Pedro Lavela ◽  
...  
Keyword(s):  
Spectroscopic Study ◽  
Lithium Ion Batteries ◽  
Negative Electrode ◽  
Lithium Ion ◽  
X Ray ◽  
X Ray Absorption

X-ray Absorption Spectroscopic Study on the Electronic Structure of Li1-xCoPO4Electrodes as 4.8 V Positive Electrodes for Rechargeable Lithium Ion Batteries

2005 ◽  
Vol 109 (22) ◽  
pp. 11197-11203 ◽  
Author(s):  
Masanobu Nakayama ◽  
Satoshi Goto ◽  
Yoshiharu Uchimoto ◽  
Masataka Wakihara ◽  
Yoshinori Kitajima ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Spectroscopic Study ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Positive Electrodes ◽  
X Ray ◽  
X Ray Absorption

scholarly journals Electrochemical study on nickel aluminum layered double hydroxides as high-performance electrode material for lithium-ion batteries based on sodium alginate binder

2021 ◽  
Author(s):  
Xinyue Li ◽  
Marco Fortunato ◽  
Anna Maria Cardinale ◽  
Angelina Sarapulova ◽  
Christian Njel ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Material ◽  
Photoelectron Spectroscopy ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Electrochemical Study ◽  
Ex Situ ◽  
Potential Range ◽  
X Ray ◽  
Storage Mechanism

AbstractNickel aluminum layered double hydroxide (NiAl LDH) with nitrate in its interlayer is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the performance of the material is investigated in 1 M LiPF6 in EC/DMC vs. Li. The NiAl LDH electrode based on sodium alginate (SA) binder shows a high initial discharge specific capacity of 2586 mAh g−1 at 0.05 A g−1 and good stability in the potential range of 0.01–3.0 V vs. Li+/Li, which is better than what obtained with a polyvinylidene difluoride (PVDF)-based electrode. The NiAl LDH electrode with SA binder shows, after 400 cycles at 0.5 A g−1, a cycling retention of 42.2% with a capacity of 697 mAh g−1 and at a high current density of 1.0 A g−1 shows a retention of 27.6% with a capacity of 388 mAh g−1 over 1400 cycles. In the same conditions, the PVDF-based electrode retains only 15.6% with a capacity of 182 mAh g−1 and 8.5% with a capacity of 121 mAh g−1, respectively. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. Graphical abstract The as-prepared NiAl-NO3−-LDH with the rhombohedral R-3 m space group is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the material’s performance is investigated in 1 M LiPF6 in EC/DMC vs. Li. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. This work highlights the possibility of the direct application of NiAl LDH materials as negative electrodes for LIBs.

Investigation of a porous NiSi 2 /Si composite anode material used for lithium-ion batteries by X-ray absorption spectroscopy

2016 ◽  
Vol 324 ◽  
pp. 830-835 ◽  
Author(s):  
Dong Zhou ◽  
Haiping Jia ◽  
Jatinkumar Rana ◽  
Tobias Placke ◽  
Richard Klöpsch ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Absorption Spectroscopy ◽  
Lithium Ion ◽  
Composite Anode ◽  
X Ray ◽  
X Ray Absorption

X-ray absorption study on LiNi0.8Co0.15Al0.05O2 cathode material for lithium-ion batteries

2008 ◽  
Vol 34 (4) ◽  
pp. 859-862 ◽  
Author(s):  
Takamasa Nonaka ◽  
Chikaaki Okuda ◽  
Yoshiki Seno ◽  
Kunihito Koumoto ◽  
Yoshio Ukyo
Keyword(s):  
Cathode Material ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Absorption Study ◽  
X Ray ◽  
X Ray Absorption

scholarly journals In situ time-resolved dispersive X-ray absorption fine structure analysis of BaTiO3–LiCoO2 composites for lithium ion batteries

2016 ◽  
Vol 124 (6) ◽  
pp. 659-663 ◽  
Author(s):  
Takashi TERANISHI ◽  
Yumi YOSHIKAWA ◽  
Ryota MIYAHARA ◽  
Hidetaka HAYASHI ◽  
Akira KISHIMOTO ◽  
...  
Keyword(s):  
Fine Structure ◽  
Lithium Ion Batteries ◽  
Structure Analysis ◽  
Lithium Ion ◽  
Time Resolved ◽  
X Ray ◽  
Absorption Fine ◽  
Fine Structure Analysis ◽  
X Ray Absorption
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