COSY spectra of paramagnetic macromolecules: Observability, scalar effects, cross-correlation effects, relaxation-allowed coherence transfer

1994 ◽  
Vol 6 (4) ◽  
pp. 307-335 ◽  
Author(s):  
Ivano Bertini ◽  
Mario Piccioli ◽  
Dario Tarchi ◽  
Claudio Luchinat
Keyword(s):  
Cross Correlation ◽  
Correlation Effects ◽  
Coherence Transfer ◽  
Cosy Spectra

scholarly journals MAX-DOAS formaldehyde slant column measurements during CINDI: intercomparison and analysis improvement

2013 ◽  
Vol 6 (1) ◽  
pp. 167-185 ◽  
Author(s):  
G. Pinardi ◽  
M. Van Roozendael ◽  
N. Abuhassan ◽  
C. Adams ◽  
A. Cede ◽  
...  
Keyword(s):  
Cross Sections ◽  
Cross Correlation ◽  
Optical Absorption Spectroscopy ◽  
Integration Time ◽  
Measuring Instruments ◽  
Absorption Cross ◽  
Correlation Effects ◽  
Data Set ◽  
Random Uncertainties ◽  
Ring Effect

Abstract. We present intercomparison results for formaldehyde (HCHO) slant column measurements performed during the Cabauw Intercomparison campaign of Nitrogen Dioxide measuring Instruments (CINDI) that took place in Cabauw, the Netherlands, in summer 2009. During two months, nine atmospheric research groups simultaneously operated MAX-DOAS (MultiAXis Differential Optical Absorption Spectroscopy) instruments of various designs to record UV-visible spectra of scattered sunlight at different elevation angles that were analysed using common retrieval settings. The resulting HCHO data set was found to be highly consistent, the mean difference between instruments generally not exceeding 15% or 7.5 × 1015 molec cm−2, for all viewing elevation angles. Furthermore, a sensitivity analysis was performed to investigate the uncertainties in the HCHO slant column retrieval when varying key input parameters such as the molecular absorption cross sections, correction terms for the Ring effect or the width and position of the fitting interval. This study led to the identification of potentially important sources of errors associated with cross-correlation effects involving the Ring effect, O4, HCHO and BrO cross sections and the DOAS closure polynomial. As a result, a set of updated recommendations was formulated for HCHO slant column retrieval in the 336.5–359 nm wavelength range. To conclude, an error budget is proposed which distinguishes between systematic and random uncertainties. The total systematic error is estimated to be of the order of 20% and is dominated by uncertainties in absorption cross sections and related spectral cross-correlation effects. For a typical integration time of one minute, random uncertainties range between 5 and 30%, depending on the noise level of individual instruments.

scholarly journals Influence of cross-correlation effects on the optical quantities of rough films

2008 ◽  
Vol 16 (11) ◽  
pp. 7789 ◽  
Author(s):  
Daniel Franta ◽  
Ivan Ohlídal ◽  
David Necas
Keyword(s):  
Cross Correlation ◽  
Correlation Effects

Cross-Correlation Effects on NMR Lineshapes and Peptide Conformation

1996 ◽  
Vol 110 (1) ◽  
pp. 26-38 ◽  
Author(s):  
Miroslava Čuperlović ◽  
William E. Palke ◽  
J.T. Gerig ◽  
G.A. Gray
Keyword(s):  
Cross Correlation ◽  
Peptide Conformation ◽  
Correlation Effects

Calculation of pulse-wave velocity using cross correlation—Effects of reflexes in the arterial tree

1991 ◽  
Vol 17 (5) ◽  
pp. 461-469 ◽  
Author(s):  
Morten Benthin ◽  
Philip Dahl ◽  
Robert Ruzicka ◽  
Kjell Lindström
Keyword(s):  
Pulse Wave Velocity ◽  
Wave Velocity ◽  
Cross Correlation ◽  
Pulse Wave ◽  
Correlation Effects ◽  
Arterial Tree
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