PAA-g-PVAc Amphiphilic Graft Copolymer Synthesized by Atom Transfer Radical Polymerization

2009 ◽  
Vol 27 (11) ◽  
pp. 2273-2278 ◽  
Author(s):  
Xiaohuan Zhang ◽  
Beidi Wang ◽  
Dong Yang ◽  
Xiaohong Zhang ◽  
Li Yuan ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Graft Copolymer ◽  
Atom Transfer ◽  
Amphiphilic Graft Copolymer

Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer

RSC Advances ◽  
2015 ◽  
Vol 5 (91) ◽  
pp. 74947-74952 ◽  
Author(s):  
Guolin Lu ◽  
Xiaojun Jiang ◽  
Yongjun Li ◽  
Xuliang Lv ◽  
Xiaoyu Huang
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Graft Copolymer ◽  
Self Assembly ◽  
Side Chains ◽  
Atom Transfer ◽  
Aryl Ether ◽  
Amphiphilic Graft Copolymer ◽  
Step Growth

This article reports the synthesis of an amphiphilic graft copolymer containing a perfluorocyclobutyl (PFCB) aryl ether-based backbone and poly(N-isopropylacrylamide) side chains by a combination of thermal step-growth cycloaddition polymerization and atom transfer radical polymerization (ATRP).

Synthesis and characterization of biodegradable copolymer derived from dextrin and poly(vinyl acetate) via atom transfer radical polymerization

RSC Advances ◽  
2016 ◽  
Vol 6 (11) ◽  
pp. 9352-9359 ◽  
Author(s):  
Dipankar Das ◽  
Sudipta Mukherjee ◽  
Aniruddha Pal ◽  
Raghunath Das ◽  
Santi Gopal Sahu ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Graft Copolymer ◽  
Synthesis And Characterization ◽  
Atom Transfer ◽  
Biodegradable Copolymer

This article reports the development of a dextrin-based amphiphilic biodegradable graft copolymer (Dxt-g-pVAc) via atom transfer radical polymerization (ATRP).

Synthesis of Amylopectin Macro-Initiator for Graft Copolymerization of Amylopectin-g-Poly(Methyl Methacrylate) by ATRP (Atom Transfer Radical Polymerization)

2015 ◽  
Vol 827 ◽  
pp. 306-310 ◽  
Author(s):  
Aniek S. Handayani ◽  
Is Sulistyati Purwaningsih ◽  
Muhamad Chalid ◽  
Emil Budianto ◽  
Dedi Priadi
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Graft Copolymer ◽  
Graft Copolymerization ◽  
Homogeneous System ◽  
Hydroxyl Groups ◽  
Atom Transfer ◽  
Tert Butyl ◽  
Product Characterization

Graft copolymer of Amylopectin and PMMA was synthesized by atom transfer radical polymerization (ATRP) method. The hydroxyl groups of amylopectin partially substituted with tert-butyl a-bromoisobutyrate to form tert-butyl a-bromoisobutyrate (TBBiB ) groups. This compound is known as an efficient macro-initiator for ATRP process. This research, aimed to obtain a bio based polymer of Amylopectin, in which the amylopectin was used as macro-initiator in the ATRP of MMA. The experiment was carried out in the homogeneous system under temperature range of 40 – 70°C in DMSO solution using TEA as catalyst. The modified amylopectin-TBBiB then was grafted to methyl methacrylate trough ATRP. Product characterization indicates that the graft copolymer Amylopectin-g-PMMA is efficient and the obtained product owns well defined structures

Graft polymer growth using tandem photoinduced photoinitiator-free CuAAC/ATRP

2015 ◽  
Vol 6 (6) ◽  
pp. 946-952 ◽  
Author(s):  
Sean Doran ◽  
Yusuf Yagci
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Graft Copolymer ◽  
Atom Transfer ◽  
Graft Polymer ◽  
One Pot ◽  
Poly Methyl Methacrylate

In this work, we describe the use of a one-pot, photoinduced but photoinitiator-free combined copper-catalyzed azide–alkyne cycloaddition (CuAAC) and atom-transfer radical polymerization (ATRP) protocol to provide a graft copolymer of polystyrene-g-poly(methyl methacrylate) (PS-g-PMMA) in good conversion and polydispersity.

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