Preparation of P4VP-g-PSt Copolymer Microspheres with Controllable Size by Atom Transfer Radical Polymerization Synthesized Poly(4-vinylpyridine) Macromonomer

2009 ◽  
Vol 27 (11) ◽  
pp. 2249-2254 ◽  
Author(s):  
Na Hu ◽  
Zhongbin Ni ◽  
Hong Chu ◽  
Xiaoya Liu ◽  
Mingqing Chen
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Controllable Size

Functionalization of Carbon Particles by Atom Transfer Radical Polymerization

MRS Advances ◽  
2017 ◽  
Vol 2 (47) ◽  
pp. 2537-2544
Author(s):  
Nurettin Sahiner ◽  
Sultan B Sengel
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Trimethylammonium Chloride ◽  
Carbon Particles ◽  
Temperature Responsive ◽  
Spherical Carbon ◽  
The Stability ◽  
Post Modification ◽  
Controllable Size

ABSTRACTSpherical carbon particles (CPs) with controllable size and surface functionalities were prepared via hydrothermal treatment using sucrose as a precursor and then post modification methods. The CPs were prepared in two steps; firstly, dewatering of sucrose molecules at relatively low temperatures and secondly, carbonization at high temperatures. The micro/nano-sized CPs were functionalized by 2-Acrylamido-2-methylpropane sulfonic acid (AMPS), (3-Acrylamidopropyl)-trimethylammonium chloride (APTMACI), and N-isopropylacrylamide (NIPAM) in order to have the corresponding polymers on the surface of CPs. The monomers were polymerized via atom transfer radical polymerization (ATRP) by means of grafted initiator onto the CPs surface. Additionally, copolymer of these monomers was synthesized to introduce additional properties. The stability of the functionalized CPs in different solutions, and pH, temperature responsive behaviors of the newly prepared CP-polymers composite were evaluated.

Redox Responsive Behavior of Thiol/Disulfide-Functionalized Star Polymers Synthesized via Atom Transfer Radical Polymerization

2010 ◽  
Vol 43 (9) ◽  
pp. 4133-4139 ◽  
Author(s):  
Jun Kamada ◽  
Kaloian Koynov ◽  
Cathrin Corten ◽  
Azhar Juhari ◽  
Jeong Ae Yoon ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Star Polymers ◽  
Atom Transfer ◽  
Redox Responsive ◽  
Responsive Behavior

Simplified Electrochemically Mediated Atom Transfer Radical Polymerization using a Sacrificial Anode

2015 ◽  
Vol 54 (8) ◽  
pp. 2388-2392 ◽  
Author(s):  
Sangwoo Park ◽  
Paweł Chmielarz ◽  
Armando Gennaro ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Sacrificial Anode

scholarly journals Plug-and-play aqueous electrochemical atom transfer radical polymerization

2021 ◽  
Vol 57 (32) ◽  
pp. 3897-3900
Author(s):  
Boyu Zhao ◽  
Mahir Mohammed ◽  
Bryn A. Jones ◽  
Paul Wilson
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Good Control ◽  
Atom Transfer ◽  
Plug And Play ◽  
Radical Polymerisation ◽  
Galvanostatic Conditions

‘Plug-and-play’ simplified electrochemical atom transfer radical polymerisation of PEGA480 under potentiostatic and galvanostatic conditions proceeds with very good control to conversions up to 83%.

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